The chemical thermodynamic properties of alkanethiol (RSH where R is an alkyl group) isomer groups from CH4S to C4H10S in the ideal gas phase have been calculated from 298.15 to 1000 K from tables of Stull, Westrum, and Sinke. In the absence of literature data on all isomers of higher isomer groups, the properties of isomers of C5H12S to C8H18S have been estimated using Benson group values. Equilibrium mole fractions within isomer groups have been calculated for the ideal gas state from 298.15 to 1000 K. For isomer group properties, increments per carbon atom have been calculated to show the extent to which thermodynamic properties of higher isomer groups may be obtained by linear extrapolation. Values of C○P, S°, ΔfH°, and ΔfG° are given for all species of alkanethiols from CH4S to C8H18S in SI units for a standard state pressure of 1 bar.
Skip Nav Destination
Article navigation
April 1987
Research Article|
April 01 1987
Standard Chemical Thermodynamic Properties of Alkanethiol Isomer Groups
Robert A. Alberty;
Robert A. Alberty
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Search for other works by this author on:
Ellen Burmenko;
Ellen Burmenko
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Search for other works by this author on:
Tae H. Kang;
Tae H. Kang
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Search for other works by this author on:
Michael B. Chung
Michael B. Chung
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Search for other works by this author on:
J. Phys. Chem. Ref. Data 16, 193–208 (1987)
Article history
Received:
August 25 1986
Received:
November 04 1986
Citation
Robert A. Alberty, Ellen Burmenko, Tae H. Kang, Michael B. Chung; Standard Chemical Thermodynamic Properties of Alkanethiol Isomer Groups. J. Phys. Chem. Ref. Data 1 April 1987; 16 (2): 193–208. https://doi.org/10.1063/1.555779
Download citation file:
Pay-Per-View Access
$40.00
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Citing articles via
Ab Initio Calculation of Fluid Properties for Precision Metrology
Giovanni Garberoglio, Christof Gaiser, et al.
Equation of State for Solid Argon Valid for Temperatures up to 300 K and Pressures up to 16 GPa
Tage W. Maltby, Morten Hammer, et al.
Survey of Hyperfine Structure Measurements in Alkali Atoms
Maria Allegrini, Ennio Arimondo, et al.
Related Content
Standard Chemical Thermodynamic Properties of Alkanol Isomer Groups
J. Phys. Chem. Ref. Data (July 1987)
Standard Chemical Thermodynamic Properties of Alkyne Isomer Groups
J. Phys. Chem. Ref. Data (October 1986)
Standard Chemical Thermodynamic Properties of Alkylcyclopentane Isomer Groups, Alkylcyclohexane Isomer Groups, and Combined Isomer Groups
J. Phys. Chem. Ref. Data (October 1985)
Standard Chemical Thermodynamic Properties of Alkylbenzene Isomer Groups
J. Phys. Chem. Ref. Data (January 1985)
Standard Chemical Thermodynamic Properties of Alkylnaphthalene Isomer Groups
J. Phys. Chem. Ref. Data (July 1985)