We consider the many-body time evolution of weakly interacting bosons in the mean field regime for initial coherent states. We show that bounded k-particle operators, corresponding to dependent random variables, satisfy both a law of large numbers and a central limit theorem.

We consider N weakly interacting bosons in the mean-field regime described on Ls2(R3N), the symmetric subspace of L2(R3N), by the Hamilton operator

(1.1)

with the two-body interaction potential v satisfying

(1.2)

for a positive constant C > 0. The mean-field regime is characterized through weak and long-range interactions of particles. Trapped Bose gases at extremely low temperatures, as prepared in the experiments, are known to relax to the ground state. The ground state ψNgs of (1.1), if it exists, exhibits Bose–Einstein condensation,17 i.e., the associated -particle reduced density

(1.3)

converges in the trace norm to

(1.4)

for all N, where φL2(R3) denotes the condensate wave function, known to be the Hartree minimizer. However, we remark that the factorized state φN does not approximate the ground state due to correlations of particles.11 

Turning to the probabilistic picture, the property of Bose–Einstein condensation (1.4) implies a law of large numbers for bounded one-particle operators.3 To be more precise, for kN, we denote with O(k) a bounded, self-adjoint k-particle operator on L2(R3k) and with i̲k the multi-index

(1.5)

Then, we define for fixed kN the N-particle operator

(1.6)

acting as O(k) on particles i1, …, ik and as identity elsewhere. We consider the operator Oi̲k(k) as a random variable with probability distribution determined through ψN by

(1.7)

where χA denotes the characteristic function of the set AR.

For one-particle operators, factorized states correspond to i.i.d. random variables as for any subsets A1,A2R and i,jIN(1) with ij,

(1.8)

In particular, for factorized states, Chebychef’s inequality implies a law of large numbers for the centered averaged sum,

(1.9)

In contrast to one-particle operators for k-particle operators with k ≥ 2, factorized states do not correspond to i.i.d. random variables. In fact, for k ≥ 2, we have

(1.10)

for all i̲kj̲k for which i̲k contains at least one element of j̲k. We conclude that in this case, the random variables are correlated and, thus, dependent. In contrast, whenever i̲k does not intersect with j̲k, the random variables Oi̲k(k), Oj̲k(k) are independent [following from arguments similarly to (1.8)]. Consequently, for factorized states, the random variables {Oi̲k(k)}i̲kIN(k) denote a sequence of  m-dependent random variables with mR. Still, as in Theorem 1.1, the centered averaged sum

(1.11)

satisfies a law of large numbers.

Theorem 1.1
(law of large numbers). ForkN, letO(k)denote a self-adjoint boundedk-particle operator,φL2(R3), andψNLs2R3Nbe a bosonic wave function satisfying
(1.12)
for allN. Then, for any fixedkNandδ > 0, the averaged sumON(k)defined in(1.11)satisfies
(1.13)

For factorized states, we have γφN()=|φφ|, and a law of large numbers follows from Theorem 1.1.

In particular, Theorem 1.1 shows that the property of condensation (1.12) implies a law of large numbers for bounded k-particle operators for fixed kN. Thus, Theorem 1.1 generalizes known results from Ref. 3 for bounded one-particle operators to k-particle operators with fixed kN. We recall that the ground state ψNgs of (1.1) cannot be approximated by a factorized state; nonetheless, the condensation property (1.4) ensures that bounded k-particle operators satisfy a law of large numbers for ψNgs, too.

1. Generalization to the Fock space

In order to generalize Theorem 1.1 to any Fock space vector ψF of the bosonic Fock space F=n0L2(R3)sn, we introduce some more notation.

For any vector ψF, we have the following identity for the operator Õ(k)=O(k)φk|O(k)|φk on the N-particle sector:

(1.14)

where we introduced the second quantization for any integral operator O(k) on L2(R3k),

(1.15)

Note that we can generalize the definition of the probability distribution (1.7) to the Fock space: For any ψF, integral operator O(k) on L2(R3k), and AR, we have

(1.16)

On the Fock space, the k-particle reduced density γψ(k) associated with ψF is given by the integral operator with kernel

(1.17)

It follows from a generalization of Theorem 1.1’s proof in Sec. II that for ψF satisfying (1.12), we have for any δ > 0,

(1.18)

2. Dynamics

We are interested in the dynamics of initially trapped Bose gases. Removing the trap, the bosons evolve with respect to the Schrödinger equation,

(1.19)

with HN being the mean-field Hamiltonian given in (1.1). In the following, we consider coherent initial data, i.e., initial data of the form

(1.20)

where Ω denotes the vacuum of the bosonic Fock space F=n0L2(R3)sn equipped with creation and annihilation operators a*(f), a(f) for fL2(R3), W(f)=ea*(f)a(f) denotes the Weyl operator, and fH1(R3) denotes the condensate wave function. Coherent states of the form (1.20) exhibit Bose–Einstein condensation in the quantum state φ, i.e., they satisfy (1.4).

Thus, it follows from Theorem 1.1 that initially a law of large numbers holds true. The property of condensation is preserved along the many-body time evolution (Ref. 4, Theorem 3.1), i.e., the -particle reduced density γN,t() associated with ψN,t satisfies

(1.21)

where φtH1(R3) denotes the solution to the Hartree equation,

(1.22)

with initial data φ0=φH1(R3) (for further references, see, e.g., Refs. 1, 2, 7, 9, 10, 15, 22, and 23). Theorem 1.1 and (1.21) show that

(1.23)

satisfies a law of large numbers for positive times t > 0 too, i.e., for any δ > 0,

(1.24)

While the law of large numbers characterizes the mean of the probability distribution, fluctuations around the mean are governed through the central limit theorem. Before stating our result on a central limit theorem for fluctuations of order O(Nk−1/2), we introduce some notations. For a bounded k-particle integral operator O(k) and φL2(R3), we define

(1.25)

and furthermore, for tR, 0 ≤ st, and j ∈ {1, …, k}, the function fs;t(j) is given by

(1.26)

with the anti-linear operator Jf=f̄ for any fL2(R3), qt = 1 − |φt⟩⟨φt|, the Hartree Hamiltonian hH defined in (1.22), and the operators

(1.27)

Theorem 1.2

(central limit theorem). Fork,NNwithkN, letO(k)be a self-adjoint, boundedk-particle integral operator andφtbe the solution to the Hartree equation(1.22)with initial datumφ0=φH1(R3). LetψN,tLs2(R3N)denote the solution to the Schrödinger equation(1.19)with the initial datum of the formψN,0=W(Nφ)Ω.

Leta,bRwitha < b; then, there exists a constantCa,b,k > 0 such that the centered averaged sumdΓ(Ot(k))defined in(1.23)satisfies
(1.28)
whereGtdenotes the centered Gaussian random variable with variance given by
(1.29)

We remark that for a factorized state, we can explicitly compute the variance

(1.30)

where we introduced the centered k-particle operator

(1.31)

The last sum of the rhs of (1.30) vanishes. Furthermore, the first sum vanishes whenever j̲k does not intersect with i̲k, and for the remaining terms, we find

(1.32)

using the definition

(1.33)

with q = 1 − |φ⟩⟨φ| and (1.25). In particular, we observe that the variance scales as σN2=O(N2k1), and thus, we expect fluctuations to be O(Nk−1/2).

We observe that Theorem 1.2 shows that the fluctuations of the many-body dynamics scale similarly to the fluctuations of a factorized state. Moreover, for t = 0, the variance σ02 of the many-body dynamics defined in (1.29) agrees with the covariance matrix MφN(i,j) in (1.33) of a factorized state.

We remark that for k = 1, i.e., considering bounded one-particle observables, Theorem 1.2 generalizes known results3,6 to more general one-particle observables. This generalization is due to a different strategy of the Proof of Theorem 1.3 than in Refs. 3 and 6. We follow the ideas of Ref. 6; however, we directly use as a first step in Lemma 4.1 the norm approximation (4.1) of the many-body time evolution (for more details, see Sec. IV B). Furthermore, the authors of Ref. 6 proved a multivariate central limit theorem: it is shown that the expectation value of products of functions f1, …, fk of bounded, self-adjoint, and centered one-particle operators O1, …, Ok [i.e., operators of the special form (1.9)] can be approximated with the integral of f1, …, fk against a complex-valued Gaussian density.

Recently, for one-particle operators, the probability distribution’s tails were characterized through large deviation estimates,14,21 showing that

(1.34)

for sufficiently small xCeeC|t|, where f̃t,0(1) is defined similarly to (1.26), but using the projected kernels K̃j,s(x,y)=qsKj,s(x,y)qs.

Furthermore, for one-particle operators, a central limit theorem is proven for stronger particles’ interactions in the intermediate regime,19 interpolating between the mean-field and the Gross–Pitaevski regime. In the Gross–Pitaevski regime of singular particles’ interaction, a central limit theorem is proven for quantum fluctuations in the ground state,20 too.

Theorem 1.2 follows from an approximation of the random variable’s characteristic function given in the following.

Theorem 1.3.
Under the same assumptions as in Theorem 1.2, we have
(1.35)

In the following, we will now first turn to the Proof of Theorem 1.1 in Sec. II, then prove Theorem 1.2 from Theorem 1.3 in Sec. III, and finally prove Theorem 1.3 in Sec. IV.

We generalize ideas from Ref. 3 on a law of large numbers for bounded one-particle observables to the case of k-particle operators.

Proof.
By Chebycheff’s inequality, we have
(2.1)
where we used the notation Õ(k) defined in (1.31). Furthermore, we denote with {i̲k,j̲k} the number of elements of i̲k agreeing with j̲k. Then, we can write
(2.2)
We can express the rhs of (2.1) in terms of j-particle reduced density matrices defined in (1.3) and find
(2.3)
Plugging (2.3) into the rhs of (2.1), we find
(2.4)
For = 0, the term of the sum of the rhs of (2.4) is given by
(2.5)
Since ψN exhibits Bose–Einstein condensation, it follows by assumption (1.12),
(2.6)
and by definition (1.31) of Õ(k), we arrive at
(2.7)
For ≥ 1, the terms of the sum of the rhs of (2.4) consist of (2k)-particle operators whose expectation values are computed with (2k)-particle operators. In particular, we find
(2.8)
as N.
We conclude with (2.4), (2.7), and (2.8) by
(2.9)

We use standard arguments from probability theory to prove Theorem 1.2 from Theorem 1.3. We follow the arguments from Ref. 6, Corollary 1.2.

Proof.
We consider the difference
(3.1)
where χ[a,b] denotes the characteristic function of the set [a, b]. We observe that for gL1(R) with Fourier transform ĝL1R,(1+s2k)ds, we have, on the one hand,
(3.2)
and, on the other hand,
(3.3)
and, in particular, by Theorem 1.3,
(3.4)
Thus, in order to find an estimate for (3.1), we shall find an approximation from above f+,ɛ and from below f−,ɛ of the characteristic function χ[a,b], which satisfy f,ε,f+,εL1(R3) and f̂,ε,f̂+,εL1(R,(1+s2k)ds). For this, let ηC0(R) with η ≥ 0, η(s) = 0 for all |s| ≥ 1 and ∫ds η(s) = 1. Furthermore, for ɛ > 0, let ηɛ(s) = ɛ−1η(s/ɛ). Then, for any ɛ > 0, we define
(3.5)
which satisfy
(3.6)
Moreover, the Fourier transform is given by
(3.7)
Thus, it follows from (3.1) and (3.6) that
(3.8)
and with (3.4) and (3.7), we arrive at
(3.9)
Similarly, using f+,ɛ, we have
(3.10)
Now, we optimize with respect to ɛ > 0 and arrive at (1.28).□

In the following, we consider the bosonic N-particle wave function ψN,t as an element of the bosonic Fock space F=n0L2(R3)sn with creation and annihilation operators a*(f), a(f) for fL2(R3). Theorem 1.3 characterizes the fluctuations around the Hartree dynamics, which are well described by the approximation of the many-body time evolution (Ref. 4, Theorem 4.1, and Ref. 6, Proposition 3.3) in the L2(R3N)-norm,

(4.1)

where the limiting dynamics U(t;0) is given by

(4.2)

with the generator

(4.3)

Here, dΓ(A)=dxdyA(x;y)ax*ay denotes the second quantization of an operator A on L2(R3), hH(t) denotes the Hartree Hamiltonian defined in (1.22), and Kj,t denote the operators defined in (1.27). For further references, see also Refs. 8, 12, 13, 16, and 18. The generator L(t) is quadratic in creation and annihilation operators and thus (Ref. 3, Theorem 2.2) (see also Refs. 5 and 19) gives rise to a Bogoliubov dynamics, i.e., there exist bounded operators U(t; 0), V(t; 0) on L2(R3) such that for f,gL2(R3) and the operator A(f,g)=a(f)+a*(ḡ), we have

(4.4)

where Jf=f̄ for any fL2(R3). In particular, for the operator

(4.5)

from (4.4), we have

(4.6)

and it follows from Ref. 3, Theorem 2.2, and the subsequent remark that

(4.7)

Compared with (1.26), we note that the variance σt defined in (1.29) is determined by the limiting Bogoliubov dynamics (4.2), i.e., the fluctuations’ quasi-free approximation.

Proof 1.3 is split into three steps covered by Lemmas 4.1–4.3.

For the first step, Lemma 4.1, we use a strategy similar to the strategy in Refs. 19 and 20, directly the norm approximation (4.1). This allows us to consider more general k (respectively, one) particle operators than in Refs. 3 and 6 where the difference of the limiting fluctuation dynamics U(t;0) defined in (4.2) to the full many-body dynamics was estimated in (4.10) by Duhamel’s formula and a Gronwall estimate. The remaining steps use the same ideas as in Refs. 3 and 6.

Lemma 4.1.
Under the same assumptions as in Theorem 1.2, let
(4.8)
Then, there existsC > 0 such that
(4.9)

Proof.
We have
(4.10)
The operator O(k) is a self-adjoint operator; thus, eiNk+1/2ONkop1, and we find with (4.1) and (4.8),
(4.11)

Lemma 4.2.
Under the same assumptions as in Theorem 1.2, letϕ(f) be defined as in(4.5)andht=j=1khj,tL2(R3)be defined with(1.25)by
(4.12)
Then, there existsC > 0 such that
(4.13)

Proof.
Recalling (4.8), we shall estimate the expectation value
(4.14)
In order to compute the operator
(4.15)
we use the Weyl operators’ shifting properties on creation and annihilation operators, i.e.,
(4.16)
With Ot(k)O(k)φtk|O(k)|φtk, we find
(4.17)
We observe that the leading order term O(Nk) vanishes by the definition of Õ(k) in (1.31). Thus, the first non-vanishing leading order term is O(Nk−1/2), and in particular, we have with (4.5) and (4.12),
(4.18)
The remainder
(4.19)
is the sum of (2k − 2k) terms. The estimates
(4.20)
for any fL2(R3) and any Fock space vector ξF together with (4.17) yield the upper bound
(4.21)
for any ξF. We use the fundamental theorem of calculus to write
(4.22)
Then, it follows from (4.21) that
(4.23)
With Ref. 6, Proposition 3.4 and ht22O(k)op2 by definition (1.25), we have
(4.24)
and furthermore, with Ref. 6, Lemma 3.2,
(4.25)
We use now estimate (4.25) for (4.23) and arrive at
(4.26)
which proves the lemma.□

Lemma 4.3.
Under the same assumptions as in Theorem 1.2, letft;s=i=1kft;s(i)L2(R3)be given by(1.26). Then, we have
(4.27)

Proof.
We need to compute the expectation value
(4.28)
We recall that the limiting dynamics U(t;0) defined in (4.2) acts as a Bogoliubov transform. In particular, in follows from (4.4) and (4.7) and the notations introduced therein that
(4.29)
with f0;t defined in (1.26). Hence, we have
(4.30)
With the Baker–Campbell–Hausdorff formulas, we split the sum in the exponential and arrive at
(4.31)

Proof of Theorem 1.3.

Combining now Lemmas 4.1–4.3, we arrive at Theorem 1.3.□

S.R. would like to thank Robert Seiringer and Benedikt Stufler for helpful discussions. Funding from the European Union’s Horizon 2020 Research and Innovation Program under the ERC grant (Grant Agreement No. 694227) and under the Marie Skłodowska-Curie grant (Agreement No. 754411) is acknowledged.

The author has no conflicts to disclose.

The data that support the findings of this study are available within the article.

1.
Adami
,
R.
,
Golse
,
F.
, and
Teta
,
A.
, “
Rigorous derivation of the cubic NLS in dimension one
,”
J. Stat. Phys.
127
(
6
),
1193
1220
(
2007
).
2.
Ammari
,
Z.
,
Falconi
,
M.
, and
Pawilowski
,
B.
, “
On the rate of convergence for the mean field approximation of bosonic many-body quantum dynamics
,”
Commun. Math. Sci.
14
(
5
),
1417
1442
(
2016
).
3.
Arous
,
G. B.
,
Kirkpatrick
,
K.
, and
Schlein
,
B.
, “
A central limit theorem in many-body quantum dynamics
,”
Commun. Math. Phys.
321
(
2
),
371
417
(
2013
).
4.
Benedikter
,
N.
,
Porta
,
M.
, and
Schlein
,
B.
,
Effective Evolution Equations from Quantum Dynamics
, Springer Briefs in Mathematical Physics Vol. 7 (
Springer
,
Cham
,
2016
).
5.
Bossmann
,
L.
,
Petrat
,
S.
,
Pickl
,
P.
, and
Soffer
,
A.
, “
Beyong Bogoliubov dynamics
,” arXiv:1912.11004 (
2019
).
6.
Buchholz
,
S.
,
Saffirio
,
C.
, and
Schlein
,
B.
, “
Multivariate central limit theorem in quantum dynamics
,”
J. Stat. Phys.
154
(
1–2
),
113
152
(
2014
).
7.
Chen
,
L.
,
Lee
,
J. O.
, and
Schlein
,
B.
, “
Rate of convergence towards Hartree dynamics
,”
J. Stat. Phys.
144
(
4
),
872
903
(
2011
).
8.
Chen
,
X.
, “
Second order corrections to mean field evolution for weakly interacting bosons in the case of three-body interactions
,”
Arch. Ration. Mech. Anal.
203
,
455
497
(
2012
).
9.
Fröhlich
,
J.
,
Knowles
,
A.
, and
Schwarz
,
S.
, “
On the mean-field limit of bosons with Coulomb two-body interaction
,”
Commun. Math. Phys.
288
(
3
),
1023
1059
(
2009
).
10.
Ginibre
,
J.
and
Velo
,
G.
, “
The classical field limit of scattering theory for non-relativistic many-boson systems. I
,”
Commun. Math. Phys.
66
,
37
76
(
1979
).
11.
Grech
,
P. D.
and
Seiringer
,
R.
, “
The excitation spectrum for weakly interacting bosons in a trap
,”
Commun. Math. Phys.
322
,
559
591
(
2012
).
12.
Grillakis
,
M.
and
Machedon
,
M.
, “
Pair excitations and the mean field approximation of interacting Bosons, II
,”
Commun. Partial Differ. Equations
42
(
1
),
24
67
(
2017
).
13.
Hepp
,
K.
, “
The classical limit for quantum mechanics correlation functions
,”
Commun. Math. Phys.
35
,
265
277
(
1974
).
14.
Kirkpatrick
,
K.
,
Rademacher
,
S.
, and
Schlein
,
B.
, “
A large deviation principle for many–body quantum dynamics
,”
Ann. Henri Poincaré
22
,
2595
2618
(
2021
).
15.
Knowles
,
A.
and
Pickl
,
P.
, “
Mean-field dynamics: Singular potentials and rate of convergence
,”
Commun. Math. Phys.
298
(
1
),
101
138
(
2010
).
16.
Lewin
,
M.
,
Nam
,
P. T.
, and
Schlein
,
B.
, “
Fluctuations around Hartree states in the mean-field regime
,”
Am. J. Math.
137
,
1613
1650
(
2013
).
17.
Lieb
,
E. H.
and
Seiringer
,
R.
, “
Proof of Bose-Einstein condensation for dilute trapped gases
,”
Phys. Rev. Lett.
88
(
17
),
170409
(
2002
).
18.
Mitrouskas
,
D.
,
Petrat
,
S.
, and
Pickl
,
P.
, “
Bogoliubov corrections and trace norm convergence for the Hartree dynamics
,”
Rev. Math. Phys.
31
(
08
),
1950024
(
2019
).
19.
Rademacher
,
S.
, “
Central limit theorem for Bose gases interacting through singular potentials
,”
Lett. Math. Phys.
110
,
2143
(
2019
).
20.
Rademacher
,
S.
and
Schlein
,
B.
, “
Central limit theorem for Bose-Einstein condensates
,”
J. Math. Phys.
60
,
071902
(
2019
).
21.
Rademacher
,
S.
and
Seiringer
,
R.
, “
Large deviation estimates for weakly interacting bosons
,” arXiv:2112.01999.
22.
Rodnianski
,
I.
and
Schlein
,
B.
, “
Quantum fluctuations and rate of convergence towards mean filed dynamics
,”
Commun. Math. Phys.
291
(
1
),
31
61
(
2009
).
23.
Spohn
,
H.
, “
Kinetic equations from Hamiltonian dynamics
,”
Rev. Mod. Phys.
52
(
3
),
569
615
(
1980
).