Bohr proposed in 1913 a model for atoms and molecules by synthesizing Planck’s quantum hypothesis with classical mechanics. When the atom number is small, his model provides good accuracy for the ground-state energy. When is large, his model is not as accurate in comparison with the experimental data but still provides a good trend agreeing with the experimental values of the ground-state energy of atoms. The main objective of this paper is to provide a rigorous mathematical analysis for the Bohr atom model. We have established the following: (1) An existence proof of the global minimizer of the ground-state energy through scaling. (2) A careful study of the critical points of the energy function. Such critical points include both the stable steady-state electron configurations as well as unstable saddle-type configurations. (3) Coplanarity of certain electron configurations. Numerical examples and graphics are also illustrated.
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February 2006
Research Article|
February 28 2006
Mathematical analysis of a Bohr atom model
Goong Chen;
Goong Chen
Department of Mathematics,
Texas A&M University
, College Station, Texas 77843 and Institute for Quantum Studies, Texas A&M University
, College Station, Texas 77843
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Zhonghai Ding;
Zhonghai Ding
Department of Mathematical Sciences,
University of Nevada
, Las Vegas, Nevada 89154
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Sze-Bi Hsu;
Sze-Bi Hsu
a)
Department of Mathematics,
Texas A&M University
, College Station, Texas 77843 and Department of Mathematics, National Tsing Hua University
, Hsinchu, Taiwan, Republic of China
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Moochan Kim;
Moochan Kim
Institute for Quantum Studies and Department of Physics,
Texas A&M University
, College Station, Texas 77843
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Jianxin Zhou
Jianxin Zhou
Department of Mathematics,
Texas A&M University
, College Station, Texas 77843
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a)
Work completed while on sabbatical leave from National Tsing Hua University. Supported in part by an NSC grant of Republic of China.
J. Math. Phys. 47, 022107 (2006)
Article history
Received:
November 02 2005
Accepted:
December 26 2005
Citation
Goong Chen, Zhonghai Ding, Sze-Bi Hsu, Moochan Kim, Jianxin Zhou; Mathematical analysis of a Bohr atom model. J. Math. Phys. 1 February 2006; 47 (2): 022107. https://doi.org/10.1063/1.2168396
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