The time‐independent scattering theory associated with the non‐self‐adjoint matrix Hamiltonians H of arrangement channel quantum mechanics is presented in detail first using the 3‐particle case as an example. A key feature is the biorthogonality of a suitably constructed set of scattering eigenvectors and duals. Channel space Möller operators, S‐ and T‐matrices are defined and a variety of properties investigated including the way multichannel unitarity is embedded into the theory. Some remarks on the time‐dependent theory are also made. A detailed discussion of channel space density matrix scattering theory (of interest, e.g., in reactive kinetic theory) is presented using the Liouville representation. We describe some special cases including the exclusion of breakup and 2×2 choices of three particle H.
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March 1983
Research Article|
March 01 1983
Scattering theory in arrangement channel quantum mechanics
J. W. Evans;
J. W. Evans
Ames Laboratory and Department of Chemistry, Iowa State University, Ames, Iowa 50011
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D. K. Hoffman;
D. K. Hoffman
Ames Laboratory and Department of Chemistry, Iowa State University, Ames, Iowa 50011
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D. J. Kouri
D. J. Kouri
Department of Chemistry, University of Houston—Central Campus, Houston, Texas 77004
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J. Math. Phys. 24, 576–587 (1983)
Article history
Received:
June 01 1982
Accepted:
September 17 1982
Citation
J. W. Evans, D. K. Hoffman, D. J. Kouri; Scattering theory in arrangement channel quantum mechanics. J. Math. Phys. 1 March 1983; 24 (3): 576–587. https://doi.org/10.1063/1.525730
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