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Volume 37, Issue 4

15 August 1962

All Issues

ISSN 0021-9606

EISSN 1089-7690

In this Issue

LETTERS TO THE EDITOR

Mössbauer Effect in Iron (III) Acetylacetonate and Chemical Consequences of K Capture in Cobalt (III) Acetylacetonate

G. K. Wertheim; W. R. Kingston; R. H. Herber

J. Chem. Phys. 37, 687–690 (1962) https://doi.org/10.1063/1.1733147

Abstract

View articletitled, Mössbauer Effect in Iron (III) Acetylacetonate and Chemical Consequences of K Capture in Cobalt (III) Acetylacetonate

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Derivation of Physically Significant Nonbonded Interaction Constants in Hydrides by a Modified Urey—Bradley Analysis

L. S. Bartell; Kozo Kuchitsu

J. Chem. Phys. 37, 691–696 (1962) https://doi.org/10.1063/1.1733148

Abstract

View articletitled, Derivation of Physically Significant Nonbonded Interaction Constants in Hydrides by a Modified Urey—Bradley Analysis

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Crystal Structure of CsMnF₃

Allan Zalkin; Kenneth Lee; David H. Templeton

J. Chem. Phys. 37, 697–699 (1962) https://doi.org/10.1063/1.1733149

Abstract

View articletitled, Crystal Structure of CsMnF3

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Theoretical Interpretation of Reactions Occurring in Photochlorination

Harold S. Johnston; Paul Goldfinger

J. Chem. Phys. 37, 700–709 (1962) https://doi.org/10.1063/1.1733150

Abstract

View articletitled, Theoretical Interpretation of Reactions Occurring in Photochlorination

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Polarization of the Electret

Bernhard Gross; R. J. de Moraes

J. Chem. Phys. 37, 710–713 (1962) https://doi.org/10.1063/1.1733151

Abstract

View articletitled, Polarization of the Electret

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Work Function Changes Produced by Chemisorption on Surfaces with Different Types of Adsorption Sites

A. D. Crowell; A. L. Norberg, Jr.

J. Chem. Phys. 37, 714–717 (1962) https://doi.org/10.1063/1.1733152

Abstract

View articletitled, Work Function Changes Produced by Chemisorption on Surfaces with Different Types of Adsorption Sites

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Effect of Inert Salts on Equilibrium and Rate Constants for Ionic Reactions

J. W. Gryder

J. Chem. Phys. 37, 718–722 (1962) https://doi.org/10.1063/1.1733153

Abstract

View articletitled, Effect of Inert Salts on Equilibrium and Rate Constants for Ionic Reactions

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Sequential Filling of a Line by Intervals Placed at Random and Its Application to Linear Adsorption

J. K. Mackenzie

J. Chem. Phys. 37, 723–728 (1962) https://doi.org/10.1063/1.1733154

Abstract

View articletitled, Sequential Filling of a Line by Intervals Placed at Random and Its Application to Linear Adsorption

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Low‐Energy Electron Diffraction Study of Silicon Surface Structures

J. J. Lander; J. Morrison

J. Chem. Phys. 37, 729–746 (1962) https://doi.org/10.1063/1.1733155

Abstract

View articletitled, Low‐Energy Electron Diffraction Study of Silicon Surface Structures

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Second‐Order Splittings in the ESR Spectra of Organic Radicals

Richard W. Fessenden

J. Chem. Phys. 37, 747–750 (1962) https://doi.org/10.1063/1.1733156

Abstract

View articletitled, Second‐Order Splittings in the ESR Spectra of Organic Radicals

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Bond Character in XY_M‐Type Molecules: Chlorine—Oxygen Compounds

E. L. Wagner

J. Chem. Phys. 37, 751–759 (1962) https://doi.org/10.1063/1.1733157

Abstract

View articletitled, Bond Character in XYM‐Type Molecules: Chlorine—Oxygen Compounds

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Some Theoretical Aspects of Bonding in N–F Compounds

Joyce J. Kaufman

J. Chem. Phys. 37, 759–764 (1962) https://doi.org/10.1063/1.1733158

Abstract

View articletitled, Some Theoretical Aspects of Bonding in N–F Compounds

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Effect of Molecular Shape on Nuclear Magnetic Relaxation

Hiroshi Shimizu

J. Chem. Phys. 37, 765–778 (1962) https://doi.org/10.1063/1.1733159

Abstract

View articletitled, Effect of Molecular Shape on Nuclear Magnetic Relaxation

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Microwave Spectrum of Chlorine Dioxide. III. Interpretation of the Hyperfine Coupling Constants Obtained in Terms of the Electronic Structure

R. F. Curl, Jr.

J. Chem. Phys. 37, 779–784 (1962) https://doi.org/10.1063/1.1733160

Abstract

View articletitled, Microwave Spectrum of Chlorine Dioxide. III. Interpretation of the Hyperfine Coupling Constants Obtained in Terms of the Electronic Structure

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Diffusional Contribution to the Total Flow from a Knudsen Cell

W. L. Winterbottom; J. P. Hirth

J. Chem. Phys. 37, 784–793 (1962) https://doi.org/10.1063/1.1733161

Abstract

View articletitled, Diffusional Contribution to the Total Flow from a Knudsen Cell

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Theory of Paramagnetic Excitons in Solid Free Radicals

Ruth M. Lynden‐Bell; Harden M. McConnell

J. Chem. Phys. 37, 794–798 (1962) https://doi.org/10.1063/1.1733162

Abstract

View articletitled, Theory of Paramagnetic Excitons in Solid Free Radicals

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Equation of State of Classical Hard Spheres at High Density

Z. W. Salsburg; W. W. Wood

J. Chem. Phys. 37, 798–804 (1962) https://doi.org/10.1063/1.1733163

Abstract

View articletitled, Equation of State of Classical Hard Spheres at High Density

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Note on the ⁵Σ⁺_g State of N₂

P. K. Carroll

J. Chem. Phys. 37, 805–809 (1962) https://doi.org/10.1063/1.1733164

Abstract

View articletitled, Note on the 5Σ+g State of N2

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Low‐Energy ⁵Σ⁺_g States of the Nitrogen Molecule

Robert S. Mulliken

J. Chem. Phys. 37, 809–813 (1962) https://doi.org/10.1063/1.1733165

Abstract

View articletitled, Low‐Energy 5Σ+g States of the Nitrogen Molecule

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Relationship between Absorption Intensity and Fluorescence Lifetime of Molecules

S. J. Strickler; Robert A. Berg

J. Chem. Phys. 37, 814–822 (1962) https://doi.org/10.1063/1.1733166

Abstract

View articletitled, Relationship between Absorption Intensity and Fluorescence Lifetime of Molecules

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Melting Curves of Five Metals under High Pressure

Marvin L. McDaniel; Stanley E. Babb, Jr.; Gene J. Scott

J. Chem. Phys. 37, 822–828 (1962) https://doi.org/10.1063/1.1733167

Abstract

View articletitled, Melting Curves of Five Metals under High Pressure

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Exchange Interaction with Electrolytically Generated Benzonitrile Negative Ion

Peter Ludwig; Ralph N. Adams

J. Chem. Phys. 37, 828–830 (1962) https://doi.org/10.1063/1.1733168

Abstract

View articletitled, Exchange Interaction with Electrolytically Generated Benzonitrile Negative Ion

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Power‐Series Solutions for Energy Eigenvalues

Don Secrest; K. Cashion; Joseph O. Hirschfelder

J. Chem. Phys. 37, 830–835 (1962) https://doi.org/10.1063/1.1733169

Abstract

View articletitled, Power‐Series Solutions for Energy Eigenvalues

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Color Centers in a Cerium‐Containing Silicate Glass

Jackson S. Stroud

J. Chem. Phys. 37, 836–841 (1962) https://doi.org/10.1063/1.1733170

Abstract

View articletitled, Color Centers in a Cerium‐Containing Silicate Glass

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Determination of the Atomic Kinetics of the Freezing Process. I. Theory

J. J. Kramer; W. A. Tiller

J. Chem. Phys. 37, 841–848 (1962) https://doi.org/10.1063/1.1733171

Abstract

View articletitled, Determination of the Atomic Kinetics of the Freezing Process. I. Theory

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Pressure Dependence of Fluorescence Spectra. IV. Effects of Vibrational Energy Transfer between Fluorescing Molecules

Robert C. Davis; David J. Wilson

J. Chem. Phys. 37, 848–853 (1962) https://doi.org/10.1063/1.1733172

Abstract

View articletitled, Pressure Dependence of Fluorescence Spectra. IV. Effects of Vibrational Energy Transfer between Fluorescing Molecules

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Luminescence of Solids Excited by Surface Recombination of Atoms. I. Luminescence Spectra

Kenneth M. Sancier; William J. Fredericks; Henry Wise

J. Chem. Phys. 37, 854–860 (1962) https://doi.org/10.1063/1.1733173

Abstract

View articletitled, Luminescence of Solids Excited by Surface Recombination of Atoms. I. Luminescence Spectra

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Luminescence of Solids Excited by Surface Recombination of Atoms. II. Recombination Coefficients

Kenneth M. Sancier; William J. Fredericks; James L. Hatchett; Henry Wise

J. Chem. Phys. 37, 860–864 (1962) https://doi.org/10.1063/1.1733174

Abstract

View articletitled, Luminescence of Solids Excited by Surface Recombination of Atoms. II. Recombination Coefficients

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Luminescence of Solids Excited by Surface Recombination of Atoms. III. Measurement of Absolute Energies Released as Luminescence and Heat

Kenneth M. Sancier; William J. Fredericks; Henry Wise

J. Chem. Phys. 37, 865–867 (1962) https://doi.org/10.1063/1.1733175

Abstract

View articletitled, Luminescence of Solids Excited by Surface Recombination of Atoms. III. Measurement of Absolute Energies Released as Luminescence and Heat

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4‐Fluorotoluene: Chemical Thermodynamic Properties, Vibrational Assignment, and Internal Rotation

D. W. Scott; J. F. Messerly; S. S. Todd; I. A. Hossenlopp; D. R. Douslin; J. P. McCullough

J. Chem. Phys. 37, 867–873 (1962) https://doi.org/10.1063/1.1733176

Abstract

View articletitled, 4‐Fluorotoluene: Chemical Thermodynamic Properties, Vibrational Assignment, and Internal Rotation

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Effect of an Electric Field on Silicon Oxidation

Paul J. Jorgensen

J. Chem. Phys. 37, 874–877 (1962) https://doi.org/10.1063/1.1733177

Abstract

View articletitled, Effect of an Electric Field on Silicon Oxidation

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Vapor‐Phase Radiolysis of Propane‐d₈ in the Presence of Other Hydrocarbons

Sharon G. Lias; P. Ausloos

J. Chem. Phys. 37, 877–883 (1962) https://doi.org/10.1063/1.1733178

Abstract

View articletitled, Vapor‐Phase Radiolysis of Propane‐d8 in the Presence of Other Hydrocarbons

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X‐Ray Study of Pyrolytic Graphites

O. J. Guentert

J. Chem. Phys. 37, 884–891 (1962) https://doi.org/10.1063/1.1733179

Abstract

View articletitled, X‐Ray Study of Pyrolytic Graphites

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Self‐Diffusion Coefficients of Carbon Dioxide at 1180°—1680°K

G. Ember; J. R. Ferron; K. Wohl

J. Chem. Phys. 37, 891–897 (1962) https://doi.org/10.1063/1.1733180

Abstract

View articletitled, Self‐Diffusion Coefficients of Carbon Dioxide at 1180°—1680°K

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Reflection and Dissociation of H₂ on Tungsten

Joe N. Smith, Jr.; Wade L. Fite

J. Chem. Phys. 37, 898–904 (1962) https://doi.org/10.1063/1.1733181

Abstract

View articletitled, Reflection and Dissociation of H2 on Tungsten

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Flash‐Photolysis Studies of α‐ and γ‐(2,4‐Dinitrobenzyl)pyridine

Harry S. Mosher; E. R. Hardwick; David Ben Hur

J. Chem. Phys. 37, 904–909 (1962) https://doi.org/10.1063/1.1733182

Abstract

View articletitled, Flash‐Photolysis Studies of α‐ and γ‐(2,4‐Dinitrobenzyl)pyridine

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LETTERS TO THE EDITOR

COMMUNICATIONS

One‐Center Expansion Self‐Consistent Field Molecular Orbital Electronic Wave Functions for XH_n Molecules

Roberto Moccia

J. Chem. Phys. 37, 910–911 (1962) https://doi.org/10.1063/1.1733183

View articletitled, One‐Center Expansion Self‐Consistent Field Molecular Orbital Electronic Wave Functions for XHn Molecules

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Two Synthesizer Nuclear Spin Decoupling; INDOR Spectra of C¹³F₃COOH and CF₃C¹³OOH, N¹⁴H₄⁺, and (CH₃)₄Si²⁹

Edward B. Baker

J. Chem. Phys. 37, 911–912 (1962) https://doi.org/10.1063/1.1733184

View articletitled, Two Synthesizer Nuclear Spin Decoupling; INDOR Spectra of C13F3COOH and CF3C13OOH, N14H4+, and (CH3)4Si29

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Polarization of Triplet→Singlet Transitions in Polyacenes

V. G. Krishna; Lionel Goodman

J. Chem. Phys. 37, 912–914 (1962) https://doi.org/10.1063/1.1733185

View articletitled, Polarization of Triplet→Singlet Transitions in Polyacenes

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COMMENTS AND ERRATA

Electronic Energy of HF as a Power Series in the Internuclear Distance

Charles E. Reid

J. Chem. Phys. 37, 914 (1962) https://doi.org/10.1063/1.1733186

View articletitled, Electronic Energy of HF as a Power Series in the Internuclear Distance

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Erratum: Electrostatic Energy Matrices of the f⁷ Configuration

W. A. Runciman

J. Chem. Phys. 37, 914 (1962) https://doi.org/10.1063/1.1733187

View articletitled, Erratum: Electrostatic Energy Matrices of the f7 Configuration

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NOTES

Molten Salt Solutions of Electropositive Metals: Electronic Conductance and Metal Halide Stoichiometry

M. A. Bredig

J. Chem. Phys. 37, 914–915 (1962) https://doi.org/10.1063/1.1733188

View articletitled, Molten Salt Solutions of Electropositive Metals: Electronic Conductance and Metal Halide Stoichiometry

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Adsorption Isotherms of Neon, Argon, Krypton, Xenon, Hydrogen, Deuterium, Methane, and Tetradeuteromethane on the Highly Graphitized Carbon Black P33 (2700°)

G. Constabaris; J. R. Sams, Jr.; G. D. Halsey, Jr.

J. Chem. Phys. 37, 915 (1962) https://doi.org/10.1063/1.1733189

View articletitled, Adsorption Isotherms of Neon, Argon, Krypton, Xenon, Hydrogen, Deuterium, Methane, and Tetradeuteromethane on the Highly Graphitized Carbon Black P33 (2700°)

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Electronic Transport in Crystalline and Liquid Pyrene

Oliver H. LeBlanc, Jr.

J. Chem. Phys. 37, 916–917 (1962) https://doi.org/10.1063/1.1733190

View articletitled, Electronic Transport in Crystalline and Liquid Pyrene

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Autodetachment of Electrons in Sulfur Hexafluoride

D. Edelson; J. E. Griffiths; K. B. McAfee, Jr.

J. Chem. Phys. 37, 917–918 (1962) https://doi.org/10.1063/1.1733191

View articletitled, Autodetachment of Electrons in Sulfur Hexafluoride

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High‐Temperature Gas Viscosities. III. NO–N₂O Mixtures

W. A. Hawksworth; H. H. E. Nourse; C. J. G. Raw

J. Chem. Phys. 37, 918–919 (1962) https://doi.org/10.1063/1.1733192

View articletitled, High‐Temperature Gas Viscosities. III. NO–N2O Mixtures

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Heats of Combustion and Formation of Seven Organic Compounds Containing Oxygen

George S. Parks; Helene P. Mosher

J. Chem. Phys. 37, 919–920 (1962) https://doi.org/10.1063/1.1733193

View articletitled, Heats of Combustion and Formation of Seven Organic Compounds Containing Oxygen

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Miscibility of Liquid Ozone with Fluorine and Oxygen

C. S. Stokes; A. G. Streng

J. Chem. Phys. 37, 920–921 (1962) https://doi.org/10.1063/1.1733194

View articletitled, Miscibility of Liquid Ozone with Fluorine and Oxygen

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Useful Integral for One‐Center Calculations

Antony F. Saturno

J. Chem. Phys. 37, 921–922 (1962) https://doi.org/10.1063/1.1733195

View articletitled, Useful Integral for One‐Center Calculations

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Melting Curves of Tin and Selenium to 10 000 Bar

Stanley E. Babb, Jr.

J. Chem. Phys. 37, 922–923 (1962) https://doi.org/10.1063/1.1733196

View articletitled, Melting Curves of Tin and Selenium to 10 000 Bar

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Location of the Lowest Triplet Level in Azulene

William R. Ware

J. Chem. Phys. 37, 923–924 (1962) https://doi.org/10.1063/1.1733197

View articletitled, Location of the Lowest Triplet Level in Azulene

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Vibrationally Excited O₂ Molecules from the Reactions of O Atoms with NO₂ and with O₃

L. F. Phillips; H. I. Schiff

J. Chem. Phys. 37, 924–925 (1962) https://doi.org/10.1063/1.1733198

View articletitled, Vibrationally Excited O2 Molecules from the Reactions of O Atoms with NO2 and with O3

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Charge Transfer Cross Section for Electronically Excited N₂⁺ with O Atoms at Low Energy

Walter Roth

J. Chem. Phys. 37, 925–926 (1962) https://doi.org/10.1063/1.1733199

View articletitled, Charge Transfer Cross Section for Electronically Excited N2+ with O Atoms at Low Energy

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