Dye laser excitation and fluorescence spectra have been used to provide information on rotational structure and energy linkages between several low‐lying electronic states of YbO. Configurational assignments of the observed low‐lying states have been made on the basis of vibrational frequencies. The X 1Σ+ ground state, with ΔG1/2=683 cm−1, is assigned to the Yb2+ 4f14 configuration, whereas five states with Ω=0−, 1, 2, 1, and 3 and ΔG1/2∼820–830 cm−1 are assigned to Yb2+ 4f136s. The lowest 4f136s(Ω=0−) state is found to be 910 cm−1 above the 4f14, X 1Σ+ state, thus establishing the linkage between the f14 and f13s configurations. The observed electronic states are discussed in relation to the ligand field model and the electronic state energies are fitted to determine the ligand field parameters. The configurational assignment for the YbO ground state proposed by M. Dolg and H. Stoll [Theor. Chim. Acta 75, 369 (1989)] is shown conclusively to be incorrect.
Skip Nav Destination
,
,
,
Article navigation
1 December 1990
Research Article|
December 01 1990
Laser spectroscopy of low‐lying excited states in YbO: Linkage of the Yb2+ f 13s and f 14 configurations
Stephen A. McDonald;
Stephen A. McDonald
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Search for other works by this author on:
Steven F. Rice;
Steven F. Rice
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Search for other works by this author on:
Robert W. Field;
Robert W. Field
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
Search for other works by this author on:
Colan Linton
Colan Linton
Physics Department, University of New Brunswick, P.O. Box 4400, Fredericton, N.B. E3B 5A3 Canada
Search for other works by this author on:
Stephen A. McDonald
Steven F. Rice
Robert W. Field
Colan Linton
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139
J. Chem. Phys. 93, 7676–7686 (1990)
Article history
Received:
April 18 1990
Accepted:
August 24 1990
Citation
Stephen A. McDonald, Steven F. Rice, Robert W. Field, Colan Linton; Laser spectroscopy of low‐lying excited states in YbO: Linkage of the Yb2+ f 13s and f 14 configurations. J. Chem. Phys. 1 December 1990; 93 (11): 7676–7686. https://doi.org/10.1063/1.459347
Download citation file:
Pay-Per-View Access
$40.00
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Citing articles via
DeePMD-kit v2: A software package for deep potential models
Jinzhe Zeng, Duo Zhang, et al.
CREST—A program for the exploration of low-energy molecular chemical space
Philipp Pracht, Stefan Grimme, et al.
Related Content
Basis set construction for molecular electronic structure theory: Natural orbital and Gauss–Slater basis for smooth pseudopotentials
J. Chem. Phys. (February 2011)
Linkages in general relativity
J. Math. Phys. (April 1981)
On the study of the floating linkage mechanisms
AIP Conf. Proc. (May 2023)
Optimal synthesis of a six-bar linkage
AIP Conf. Proc. (June 2023)
Glycosidic linkage conformation of methyl- α -mannopyranoside
J. Chem. Phys. (July 2008)