Electronic‐to‐vibrational energy transfer has been studied by solving numerically the close‐coupling equations, in the T‐shape configuration, on the two lowest electronic states of the Na–N2 system. The diabatic potential surfaces were taken from Archirel and Habitz while the interelectronic coupling was modeled by different Gaussian‐type functions. Different sets of parameters for the coupling were used in order to study the final vibrational distributions of N2. Finally, partial quenching probabilities are presented and compared with previous theoretical and experimental works.

1.
(a) I. V. Hertel, in Dynamics of the Excited State, edited by K. Lawley (Wiley New York, 1982), p. 475;
(b) W. H. Breckenridge and H. Umemoto, ibid., p. 325;
(c)
A. W.
Kleyn
,
J.
Los
, and
E. A.
Gislason
,
Phys. Rep.
90
,
1
(
1982
).
2.
A.
Bjerre
and
E. E.
Nikitin
,
Chem. Phys. Lett.
1
,
179
(
1967
).
3.
E.
Bauer
,
E. R.
Fisher
, and
F. R.
Gilmore
,
J. Chem. Phys.
51
,
4173
(
1969
).
4.
(a)
P.
Botschwina
,
W.
Meyer
,
I. V.
Hertel
, and
W.
Reiland
,
J. Chem. Phys.
75
,
5438
(
1981
);
(b)
W.
Reiland
,
H.‐U.
Tittes
,
I. V.
Hertel
,
V.
Bonačić‐Koutecký
, and
M.
Persico
,
J. Chem. Phys.
77
,
1908
(
1982
).,
J. Chem. Phys.
5.
(a)
D. G.
Truhlar
,
J. W.
Duff
,
N. C.
Blails
,
J. C.
Tully
, and
B. C.
Garrett
,
J. Chem. Phys.
77
,
764
(
1982
);
(b)
N. C.
Blais
,
D. G.
Truhlar
, and
B. C.
Garrett
,
J. Chem. Phys.
78
,
2956
(
1983
).,
J. Chem. Phys.
6.
(a)
P.
Habitz
,
Chem. Phys.
54
,
131
(
1980
).
(b)
P.
Archirel
and
P.
Habitz
,
78
,
213
(
1983
).,
Chem. Phys.
7.
M. Persico, in Spectral Line Shapes (De Grunter, Berlin, 1985), Vol. III.
8.
D.
Poppe
,
D.
Papierowska‐Kaminski
, and
V.
Bonačić‐Koutecký
,
J. Chem. Phys.
86
,
822
(
1987
).
9.
J. C. Tully, in Dynamics of Molecular Collisions, Part B, edited by W. H. Miller (Plenum, New York, 1976), p. 217.
10.
(a)
E. A.
Gislason
,
A. W.
Kleyn
, and
J.
Los
,
Chem. Phys.
59
,
91
(
1981
);
(b)
N. C.
Blais
and
D. G.
Truhlar
,
J. Chem. Phys.
79
,
1334
(
1983
).
11.
G.
Delgado‐Barrio
and
J. A.
Beswick
,
Chem. Phys. Lett.
48
,
358
(
1977
).
12.
P.
McGuire
and
J. C.
Bellum
,
J. Chem. Phys.
71
,
1975
(
1979
).
13.
C. H.
Becker
and
R. P.
Saxon
,
J. Chem. Phys.
75
,
4899
(
1981
).
14.
J. Campos‐Martinez, O. Roncero, S. Miret‐Artés, P. Viliarreal, and G. Delgado‐Barrio, Atomic and Molecular Processes with Short Intense Laser Pulses, NATO ASI Series, edited by A. D. Bandrauk (Plenum, New York, 1987).
15.
J. R.
Barker
and
R. E.
Weston
, Jr.
,
J. Chem. Phys.
65
,
1427
(
1976
).
16.
J. A.
Silver
,
N. C.
Blails
, and
G. H.
Kwei
,
J. Chem. Phys.
71
,
3412
(
1979
).
17.
W.
Reiland
,
C. P.
Schulz
,
H.‐U.
Tittes
, and
I. V.
Hertel
,
Chem. Phys. Lett.
91
,
329
(
1982
).
18.
I.
Tanarro
,
F.
Arqueros
, and
J.
Campos
,
J. Chem. Phys.
77
,
1826
(
1982
).
19.
W.
Kamke
,
B.
Kamke
,
I. V.
Hertel
, and
A.
Gallagher
,
J. Chem. Phys.
80
,
4879
(
1984
).
20.
G.
Jamieson
,
W.
Reiland
,
C. P.
Schulz
,
H.‐U.
Tittes
, and
I. V.
Hertel
,
J. Chem. Phys.
81
,
5805
(
1984
).
21.
D.
Poppe
,
Chem. Phys.
111
,
17
(
1987
).
22.
M. S. Child, in Atom‐Molecule Collision Theory, edited by R. B. Bernstein (Plenum, New York, 1979), p. 427.
23.
G. Herzberg, Spectra of Diatomic Molecules (Van Nostrand Reinhold, New York, 1979).
24.
(a)
R.
Grice
and
D. R.
Hersschbach
,
Mol. Phys.
27
,
159
(
1974
);
(b)
M. B.
Faist
,
B. R.
Johnson
, and
R. D.
Levine
,
Chem. Phys. Lett.
32
,
1
(
1975
);
(c)
M. B.
Faist
, and
R. D.
Levine
,
J. Chem. Phys.
64
,
2953
(
1976
);
(d)
A. W.
Kleyn
,
M. M.
Hubers
, and
J.
Los
,
Chem. Phys.
34
,
55
(
1978
);
(e)
A. W.
Kleyn
,
V. N.
Khromov
, and
J.
Los
,
Chem. Phys.
52
,
65
(
1980
).,
Chem. Phys.
25.
C.
Galloy
and
J. C.
Lorquet
,
J. Chem. Phys.
67
,
4672
(
1977
).
26.
P. Hering, S. L. Cunha, and K. L. Kompa in Methods Laser Spectroscopy, edited by Y. Prior, Reuven A. Ben, and M. Rosenbenh (Plenum, New York, 1985).
27.
P.
Viliarreal
,
G.
Delgado‐Barrio
,
O.
Roncero
,
F. A.
Gianturco
, and
A.
Palma
,
Phys. Rev. A
336
,
617
(
1987
).
28.
J. Campos‐Martinez, P. Viliarreal, G. Delgado‐Barrio, and S. Miret‐Artés, Int. J. Quantum Chem. (in press).
This content is only available via PDF.
You do not currently have access to this content.