Detonation fronts in solid high explosives have been examined through measurements of particle velocity histories resulting from the interaction of a detonation wave with a thin metal foil backed by a water window. Using a high time resolution velocity‐interferometer system, experiments were conducted on three explosives—a TATB (1,3,5‐triamino‐trinitrobenzene)‐based explosive called PBX‐9502, TNT (2,4,6‐Trinitrotoluene), and CP (2‐{5‐cyanotetrazolato} pentaamminecobalt {III} perchlorate). In all cases, detonation‐front rise times were found to be less than the 300 ps resolution of the interferometer system. The thermodynamic state in the front of the detonation wave was estimated to be near the unreacted state determined from an extrapolation of low‐pressure unreacted Hugoniot data for both TNT and PBX‐9502 explosives. Computer calculations based on an ignition and growth model of a Zeldovich–von Neumann–Doering (ZND) detonation wave show good agreement with the measurements. By using the unreacted Hugoniot and a JWL equation of state for the reaction products, we estimated the initial reaction rate in the high explosive after the detonation wave front interacted with the foil to be 40 μs−1 for CP, 60 μs−1 for TNT, and 80 μs−1 for PBX‐9502. The shape of the profiles indicates the reaction rate decreases as reaction proceeds.

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