Emission from and is observed from photolysis of ozone–oxygen mixtures at 2537 Å. The is formed by energy transfer from and the relative rates of removal of by O2, N2, and O3 are found to be 1:0.7:9.7, respectively. The is formed directly by photolysis. Photolysis and the reaction of and with O3 are discussed as sources of both O2 singlet states.
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