A quantum‐mechanical counterpart to the classical mechanical variation of constants method is derived, with initial values of coordinates and momenta as “constants.” Use is made of a formal operator solution for nonautonomous or autonomous systems in classical mechanics, which we published earlier, and of the correspondence between Poisson brackets and commutators. An alternative unified Lie‐algebraic derivation is also given. It is shown that the Schrödinger, Heisenberg, and interaction pictures in quantum mechanics do not correspond directly to the method of classical mechanical variation of these “constants.” A fourth picture, termed “mixed interaction,” is introduced and shown to so correspond. It complements the previous three in a symmetrical manner, bearing the same relation to the Heisenberg picture that the Schrödinger picture bears to the interaction one. The group‐theoretic relationship to the interaction picture is noted, as is the relation to the usual variation‐of‐constants method in wave mechanics. For completeness, the classical counterparts of the Heisenberg and interaction pictures are also given. The present results arose from a comparison of quantum and classical treatments of collisions.

1.
For example, J. M. Jauch, Foundations of Quantum Mechanics (Addison‐Wesley, Reading, Mass., 1968), pp. 156–157.
2.
For example, E. W. Brown and C. A. Shook, Planetary Theory (Cambridge U.P., London, 1933), p. 125;
W. M. Smart, Celestial Mechanics (Longmans Green, New York, 1953), p. 159.
3.
P. A. M. Dirac, The Principles of Quantum Mechanics (Oxford U.P., New York, 1958), 4th ed., p. 174;
L. Pauling and E. B. Wilson, Jr., Introduction to Quantum Mechanics (McGraw‐Hill, New York, 1935), p. 294.
4.
R. A.
Marcus
,
J. Chem. Phys.
52
,
4803
(
1970
). [In Eq. (4) the i = x̄i should read i = x̄i0.] Several notational differences occur; e.g., subscripted M quantities here were denoted by barred quantities there. The ad B notation, given later in the present (3.7)–(3.12), replaces {B, }, etc. A notational difference in writing the equations is described in the present Appendix C.
5.
Reference 3, p. 87. An example of application of the correspondence to the unintegrated equations of motion is given in W. H. Louisell, Radiation and Noise in Quantum Electrons (McGraw‐Hill, New York, 1964), p. 60.
6.
A. Messiah, Quantum Mechanics (North‐Holland, Amsterdam, 1961), p. 322.
7.
A. Messiah, Ref. 6, p. 723.
8.
R. G. Newton, Scattering of Waves and Particles (McGraw‐Hill, New York, 1966), Sec. 6.5, p. 176.
9.
This function arose by converting Eqs. (3.4) and (3.5) to operator equations,4 and applying a solution to the latter due to
W.
Magnus
,
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7
,
649
(
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).
10.
J. G.
Belinfante
,
B.
Kolman
, and
H. A.
Smith
,
SIAM Rev.
8
,
1
(
1966
). In the present instance of Eq. (4) the Poisson bracket is the Lie bracket.
11.
The solution of W. Magnus9 is applied to (4.11), using the definition of B in the present Eq. (4.4).
12.
(exp ad A)C = (exp A)C exp(−A); cf. W. H. Louisell, Ref. 5, p. 101;
J.
Wei
and
E.
Norman
,
J. Math. Phys.
4
,
575
(
1963
).
13.
Reference 9, p. 661. Also see,
E.
Wichmann
,
J. Math. Phys.
6
,
875
(
1961
).
14.
W. Magnus, Ref. 9.
15.
N. Jacobson, Lie Algebras (Interscience, New York, 1962), p. 7, where the definition is given in terms of multiplication on the right.
16.
Reference 15, pp. 3, 10.
17.
Reference 15, p. 9.
18.
If the equation solved in Ref. 9 is denoted by dY/dt = A(t)Y, then differentiation of YY−1 = 1 yields dY−1/dt = −Y−1A(t).
19.
One Lie Algebra is generated by ad H1I(t) [cf. Eq. (4.3), with H1(q,p,t) written as H1I(qM,pM,t), and the other is generated by H1I(t) (Eqs. 4.10 and 4.12)]. “Adjoint representation” is defined in Ref. 10, p. 23.
20.
R. Hermann, Differential Geometry and the Calculus of Variations (Academic, New York, 1968), p. 88 for definition of adjoint group.
21.
(a)
K. T.
Chen
,
Bull. Am. Math. Soc.
68
,
341
(
1962
);
see also, R. Hermann, Ref. 20, Chap. 6;
(b)
K. T.
Chen
,
Arch. Ratl. Mech. Anal.
13
,
348
(
1963
).
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