A quantum‐mechanical counterpart to the classical mechanical variation of constants method is derived, with initial values of coordinates and momenta as “constants.” Use is made of a formal operator solution for nonautonomous or autonomous systems in classical mechanics, which we published earlier, and of the correspondence between Poisson brackets and commutators. An alternative unified Lie‐algebraic derivation is also given. It is shown that the Schrödinger, Heisenberg, and interaction pictures in quantum mechanics do not correspond directly to the method of classical mechanical variation of these “constants.” A fourth picture, termed “mixed interaction,” is introduced and shown to so correspond. It complements the previous three in a symmetrical manner, bearing the same relation to the Heisenberg picture that the Schrödinger picture bears to the interaction one. The group‐theoretic relationship to the interaction picture is noted, as is the relation to the usual variation‐of‐constants method in wave mechanics. For completeness, the classical counterparts of the Heisenberg and interaction pictures are also given. The present results arose from a comparison of quantum and classical treatments of collisions.
Skip Nav Destination
Article navigation
15 August 1970
Research Article|
August 15 1970
Fourth Picture in Quantum Mechanics Available to Purchase
R. A. Marcus
R. A. Marcus
Noyes Chemical Laboratory, University of Illinois, Urbana, Illinois 61801
Search for other works by this author on:
R. A. Marcus
Noyes Chemical Laboratory, University of Illinois, Urbana, Illinois 61801
J. Chem. Phys. 53, 1349–1355 (1970)
Article history
Received:
February 19 1970
Citation
R. A. Marcus; Fourth Picture in Quantum Mechanics. J. Chem. Phys. 15 August 1970; 53 (4): 1349–1355. https://doi.org/10.1063/1.1674179
Download citation file:
Pay-Per-View Access
$40.00
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Citing articles via
DeePMD-kit v2: A software package for deep potential models
Jinzhe Zeng, Duo Zhang, et al.
CREST—A program for the exploration of low-energy molecular chemical space
Philipp Pracht, Stefan Grimme, et al.
GPAW: An open Python package for electronic structure calculations
Jens Jørgen Mortensen, Ask Hjorth Larsen, et al.