A calculation of symmetric resonant charge exchange cross sections has been made for a selection of atoms in the velocity range where the impact parameter method is applicable. Cross sections for other atoms can be estimated by interpolating in terms of their ionization potentials. The results are in fair agreement with experiment. A similar calculation has been attempted for asymmetric nonresonant charge exchange processes. The approximations used are more restrictive in this calculation, the calculations being only semiquantitative in nature. The cross section of an asymmetric charge exchange process is determined in terms of the ΔE of the reaction and the ``average'' ionization potential of the two atoms. The results are qualitatively in agreement with experiment. A very brief discussion of approaches for extrapolating data to lower velocities, where the rectilinear orbit impact parameter method is not applicable, is given.
Skip Nav Destination
Article navigation
1 December 1962
Research Article|
July 20 2004
Charge Exchange between Gaseous Ions and Atoms
Donald Rapp;
Donald Rapp
Lockheed Missiles and Space Company, Palo Alto, California
Search for other works by this author on:
W. E. Francis
W. E. Francis
Lockheed Missiles and Space Company, Palo Alto, California
Search for other works by this author on:
J. Chem. Phys. 37, 2631–2645 (1962)
Article history
Received:
March 28 1962
Citation
Donald Rapp, W. E. Francis; Charge Exchange between Gaseous Ions and Atoms. J. Chem. Phys. 1 December 1962; 37 (11): 2631–2645. https://doi.org/10.1063/1.1733066
Download citation file:
Sign in
Don't already have an account? Register
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Sign in via your Institution
Sign in via your InstitutionPay-Per-View Access
$40.00
Citing articles via
Related Content
A Semiconductor‐Based Positron Emission Tomography System
AIP Conference Proceedings (December 2009)
Ultrasonic Absorption Theory of Gierer and Wirtz
J. Chem. Phys. (October 2004)
Structure and Properties of Liquid Water
J. Chem. Phys. (May 2004)
Photoluminescence, Photocurrent, and Phase‐Transition Correlations in SrTiO3
Journal of Applied Physics (June 2004)
Classical Isotope Effect in Vibrational Relaxation: The Relaxation of H2 and D2
J. Chem. Phys. (September 2003)