Simulating mixed-state evolution in open quantum systems is crucial for various chemical physics, quantum optics, and computer science applications. These simulations typically follow the Lindblad master equation dynamics. An alternative approach known as quantum state diffusion unraveling is based on the trajectories of pure states generated by random wave functions, which evolve according to a nonlinear Itô–Schrödinger equation (ISE). This study introduces weak first-order and second-order solvers for the ISE based on directly applying the Itô–Taylor expansion with exact derivatives in the interaction picture. We tested the method on free and driven Morse oscillators coupled to a thermal environment and found that both orders allowed practical estimation with a few dozen iterations. The variance was relatively small compared to the linear unraveling and did not grow with time. The second-order solver delivers a much higher accuracy and stability with bigger time steps than the first-order scheme, with a small additional workload. However, the second-order algorithm has quadratic complexity with the number of Lindblad operators as opposed to the linear complexity of the first-order algorithm.
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14 February 2024
Research Article|
February 09 2024
Weak second-order quantum state diffusion unraveling of the Lindblad master equation Available to Purchase
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Sayak Adhikari
;
Sayak Adhikari
(Conceptualization, Data curation, Formal analysis, Investigation, Methodology, Validation, Visualization, Writing – original draft, Writing – review & editing)
Fritz Haber Center for Molecular Dynamics and Institute of Chemistry, The Hebrew University of Jerusalem
, Jerusalem 9190401, Israel
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Roi Baer
Roi Baer
a)
(Conceptualization, Data curation, Formal analysis, Funding acquisition, Investigation, Methodology, Project administration, Software, Supervision, Validation, Visualization, Writing – original draft, Writing – review & editing)
Fritz Haber Center for Molecular Dynamics and Institute of Chemistry, The Hebrew University of Jerusalem
, Jerusalem 9190401, Israel
a)Author to whom correspondence should be addressed: [email protected]
Search for other works by this author on:
Sayak Adhikari
Conceptualization, Data curation, Formal analysis, Investigation, Methodology, Validation, Visualization, Writing – original draft, Writing – review & editing
Fritz Haber Center for Molecular Dynamics and Institute of Chemistry, The Hebrew University of Jerusalem
, Jerusalem 9190401, Israel
Roi Baer
Conceptualization, Data curation, Formal analysis, Funding acquisition, Investigation, Methodology, Project administration, Software, Supervision, Validation, Visualization, Writing – original draft, Writing – review & editing
a)
Fritz Haber Center for Molecular Dynamics and Institute of Chemistry, The Hebrew University of Jerusalem
, Jerusalem 9190401, Israel
a)Author to whom correspondence should be addressed: [email protected]
J. Chem. Phys. 160, 064107 (2024)
Article history
Received:
December 17 2023
Accepted:
January 18 2024
Citation
Sayak Adhikari, Roi Baer; Weak second-order quantum state diffusion unraveling of the Lindblad master equation. J. Chem. Phys. 14 February 2024; 160 (6): 064107. https://doi.org/10.1063/5.0191947
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