This work is a collection of initial calculations and formal considerations within the Salpeter–Sucher exact equal-time relativistic quantum electrodynamics framework. The calculations are carried out as preparation for the computation of pair, retardation, and radiative corrections to the relativistic energy of correlated two-spin-1/2-fermion systems. In this work, particular attention is paid to the retardation and the “one-loop” self-energy corrections, which are known to be among the largest corrections to the correlated relativistic energy. The theoretical development is supplemented with identifying formal connections to the non-relativistic quantum electrodynamics framework, which is based on a correlated but non-relativistic reference, as well as to the “1/Z approach,” which is built on a relativistic but independent-particle zeroth order. The two complementary directions currently provide the theoretical framework for light atomic–molecular precision spectroscopy and heavy-atom phenomena. The present theoretical efforts pave the way for relativistic QED corrections to (explicitly) correlated relativistic computations.
Skip Nav Destination
,
Article navigation
28 May 2024
Research Article|
May 22 2024
QED corrections to the correlated relativistic energy: One-photon processes
Ádám Margócsy
;
Ádám Margócsy
(Formal analysis, Investigation, Methodology, Writing – original draft, Writing – review & editing)
ELTE, Eötvös Loránd University, Institute of Chemistry
, Pázmány Péter Sétány 1/A, Budapest H-1117, Hungary
Search for other works by this author on:
Edit Mátyus
Edit Mátyus
a)
(Formal analysis, Investigation, Methodology, Writing – original draft, Writing – review & editing)
ELTE, Eötvös Loránd University, Institute of Chemistry
, Pázmány Péter Sétány 1/A, Budapest H-1117, Hungary
a)Author to whom correspondence should be addressed: [email protected]
Search for other works by this author on:
Ádám Margócsy
Edit Mátyus
a)
ELTE, Eötvös Loránd University, Institute of Chemistry
, Pázmány Péter Sétány 1/A, Budapest H-1117, Hungary
a)Author to whom correspondence should be addressed: [email protected]
J. Chem. Phys. 160, 204103 (2024)
Article history
Received:
December 21 2023
Accepted:
May 02 2024
Citation
Ádám Margócsy, Edit Mátyus; QED corrections to the correlated relativistic energy: One-photon processes. J. Chem. Phys. 28 May 2024; 160 (20): 204103. https://doi.org/10.1063/5.0193250
Download citation file:
Pay-Per-View Access
$40.00
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Citing articles via
DeePMD-kit v2: A software package for deep potential models
Jinzhe Zeng, Duo Zhang, et al.
CREST—A program for the exploration of low-energy molecular chemical space
Philipp Pracht, Stefan Grimme, et al.
Related Content
Exact integral constraint requiring only the ground-state electron density as input on the exchange-correlation force − ∂ V xc ( r ) / ∂ r for spherical atoms
J. Chem. Phys. (November 2008)
Effects of adiabatic, relativistic, and quantum electrodynamics interactions on the pair potential and thermophysical properties of helium
J. Chem. Phys. (June 2012)
Analysis of QED and non-adiabaticity effects on the rovibrational spectrum of H 3 + using geometry-dependent effective nuclear masses
J. Chem. Phys. (March 2020)
Breit corrections to individual atomic and molecular orbital energies
J. Chem. Phys. (January 2018)
Variational vs perturbative relativistic energies for small and light atomic and molecular systems
J. Chem. Phys. (September 2022)