This work is a collection of initial calculations and formal considerations within the Salpeter–Sucher exact equal-time relativistic quantum electrodynamics framework. The calculations are carried out as preparation for the computation of pair, retardation, and radiative corrections to the relativistic energy of correlated two-spin-1/2-fermion systems. In this work, particular attention is paid to the retardation and the “one-loop” self-energy corrections, which are known to be among the largest corrections to the correlated relativistic energy. The theoretical development is supplemented with identifying formal connections to the non-relativistic quantum electrodynamics framework, which is based on a correlated but non-relativistic reference, as well as to the “1/Z approach,” which is built on a relativistic but independent-particle zeroth order. The two complementary directions currently provide the theoretical framework for light atomic–molecular precision spectroscopy and heavy-atom phenomena. The present theoretical efforts pave the way for relativistic QED corrections to (explicitly) correlated relativistic computations.

1.
M.
Beyer
,
N.
Hölsch
,
J.
Hussels
,
C.-F.
Cheng
,
E. J.
Salumbides
,
K. S. E.
Eikema
,
W.
Ubachs
,
C.
Jungen
, and
F.
Merkt
,
Phys. Rev. Lett.
123
,
163002
(
2019
).
2.
L.
Semeria
,
P.
Jansen
,
G.-M.
Camenisch
,
F.
Mellini
,
H.
Schmutz
, and
F.
Merkt
,
Phys. Rev. Lett.
124
,
213001
(
2020
).
3.
G.
Clausen
,
P.
Jansen
,
S.
Scheidegger
,
J. A.
Agner
,
H.
Schmutz
, and
F.
Merkt
,
Phys. Rev. Lett.
127
,
093001
(
2021
).
4.
L.
Gurung
,
T. J.
Babij
,
J.
Pérez-Ríos
,
S. D.
Hogan
, and
D. B.
Cassidy
,
Phys. Rev. A
103
,
042805
(
2021
).
5.
R. E.
Sheldon
,
T. J.
Babij
,
S. H.
Reeder
,
S. D.
Hogan
, and
D. B.
Cassidy
,
Phys. Rev. Lett.
131
,
043001
(
2023
).
6.
G.
Clausen
,
S.
Scheidegger
,
J. A.
Agner
,
H.
Schmutz
, and
F.
Merkt
,
Phys. Rev. Lett.
131
,
103001
(
2023
).
7.
A.
Rischka
,
H.
Cakir
,
M.
Door
,
P.
Filianin
,
Z.
Harman
,
W. J.
Huang
,
P.
Indelicato
,
C. H.
Keitel
,
C. M.
König
,
K.
Kromer
,
M.
Müller
,
Y. N.
Novikov
,
R. X.
Schüssler
,
C.
Schweiger
,
S.
Eliseev
, and
K.
Blaum
,
Phys. Rev. Lett.
124
,
113001
(
2020
).
9.
M.
I Eides
,
H.
Grotch
, and
V. A.
Shelyuto
,
Phys. Rep.
342
,
63
(
2001
).
10.
U. D.
Jentschura
and
G. S.
Adkins
,
Quantum Electrodynamics: Atoms, Lasers and Gravity
(
World Scientific
,
Singapore
,
2022
).
11.
12.
V.
Korobov
and
A.
Yelkhovsky
,
Phys. Rev. Lett.
87
,
193003
(
2001
).
13.
14.
V. A.
Yerokhin
,
V.
Patkóš
, and
K.
Pachucki
,
Symmetry
13
,
1246
(
2021
).
15.
G.
Adkins
,
D.
Cassidy
, and
J.
Pérez-Ríos
,
Phys. Rep.
975
,
1
(
2022
).
16.
P.
Mohr
,
G.
Plunien
, and
G.
Soff
,
Phys. Rep.
293
,
227
(
1998
).
18.
I.
Lindgren
,
Relativistic Many-Body Theory
,
Springer Series on Atomic, Optical, and Plasma Physics
(
Springer
,
New York
,
2011
), Vol.
63
.
19.
V. A.
Yerokhin
and
A. V.
Maiorova
,
Symmetry
12
,
800
(
2020
).
20.
A. N.
Artemyev
,
V. M.
Shabaev
,
V. A.
Yerokhin
,
G.
Plunien
, and
G.
Soff
,
Phys. Rev. A
71
,
062104
(
2005
).
21.
Y. S.
Kozhedub
,
A. V.
Malyshev
,
D. A.
Glazov
,
V. M.
Shabaev
, and
I. I.
Tupitsyn
,
Phys. Rev. A
100
,
062506
(
2019
).
22.
A. V.
Malyshev
,
Y. S.
Kozhedub
,
D. A.
Glazov
,
I. I.
Tupitsyn
, and
V. M.
Shabaev
,
Phys. Rev. A
99
,
010501
(
2019
).
23.
O.
Gorceix
,
P.
Indelicato
, and
J. P.
Desclaux
,
J. Phys. B: At. Mol. Phys.
20
,
639
(
1987
).
24.
S. A.
Blundell
,
W. R.
Johnson
,
Z. W.
Liu
, and
J.
Sapirstein
,
Phys. Rev. A
39
,
3768
(
1989
).
25.
F. A.
Parpia
and
I. P.
Grant
,
J. Phys. B: At., Mol. Opt. Phys.
23
,
211
(
1990
).
26.
K. G.
Dyall
and
K.
Faegri
, Jr.
,
Introduction to Relativistic Quantum Chemistry
(
Oxford University Press
,
New York
,
2007
).
27.
M.
Reiher
and
A.
Wolf
,
Relativistic Quantum Chemistry: The Fundamental Theory of Molecular Science
, 2nd ed. (
Wiley VCH
,
Weinheim
,
2015
).
30.
O.
Smits
,
P.
Indelicato
,
W.
Nazarewicz
,
M.
Piibeleht
, and
P.
Schwerdtfeger
,
Phys. Rep.
1035
,
1
(
2023
).
31.
E. E.
Salpeter
and
H. A.
Bethe
,
Phys. Rev.
84
,
1232
(
1951
).
32.
33.
J.
Sucher
,
Energy Levels of the Two-Electron Atom, to Order α3Rydberg
(
Columbia University
,
1958
).
34.
M.
Douglas
and
N. M.
Kroll
,
Ann. Phys.
82
,
89
(
1974
).
36.
P.
Jeszenszki
,
D.
Ferenc
, and
E.
Mátyus
,
J. Chem. Phys.
154
,
224110
(
2021
).
37.
D.
Ferenc
,
P.
Jeszenszki
, and
E.
Mátyus
,
J. Chem. Phys.
156
,
084111
(
2022
).
38.
D.
Ferenc
,
P.
Jeszenszki
, and
E.
Mátyus
,
J. Chem. Phys.
156
,
084110
(
2022
).
39.
D.
Ferenc
,
P.
Jeszenszki
, and
E.
Matyus
,
J. Chem. Phys.
157
,
094113
(
2022
).
40.
P.
Jeszenszki
and
E.
Mátyus
,
J. Chem. Phys.
158
,
054104
(
2023
).
41.
D.
Ferenc
and
E.
Mátyus
,
Phys. Rev. A
107
,
052803
(
2023
).
42.
I.
Lindgren
,
H.
Persson
,
S.
Salomonson
, and
L.
Labzowsky
,
Phys. Rev. A
51
,
1167
(
1995
).
43.
H.
Araki
,
Prog. Theor. Phys.
17
,
619
(
1957
).
44.
G. W.
Drake
,
Can. J. Phys.
66
,
586
(
1988
).
45.
V. A.
Yerokhin
,
V.
Patkóš
,
M.
Puchalski
, and
K.
Pachucki
,
Phys. Rev. A
102
,
012807
(
2020
).
46.
V. A.
Yerokhin
,
V. c. v.
Patkóš
, and
K.
Pachucki
,
Phys. Rev. A
106
,
022815
(
2022
).
47.
P. T.
Matthews
and
A.
Salam
,
Phys. Rev.
94
,
185
(
1954
).
49.
J. M.
Jauch
and
F.
Rohrlich
,
The Theory of Photons and Electrons
, 2nd ed. (
Springer Berlin
,
Heidelberg
,
1976
).
52.
W.
Greiner
and
J.
Reinhardt
,
Quantum Electrodynamics
(
Springer-Verlag
,
Berlin Heidelberg
,
2009
).
53.
F.
Gross
,
Relativistic Quantum Mechanics and Field Theory
(
John Wiley & Sons, Inc.
,
New York
,
1999
).
54.
P.
Jeszenszki
and
E.
Mátyus
(to be published) (
2024
).
55.
I.
Lindgren
and
J.
Morrison
,
Atomic Many-Body Theory
,
Springer Series on Atomic, Optical, and Plasma Physics
(
Springer
,
New York
,
1986
), Vol.
3
.
56.
E.
Mátyus
,
D.
Ferenc
,
P.
Jeszenszki
, and
A.
Margócsy
,
ACS Phys. Chem. Au
3
,
222
(
2023
).
57.
I. P.
Grant
,
Relativistic Quantum Theory of Atoms and Molecules: Theory and Computation
,
Springer Series on Atomic, Optical, and Plasma Physics
(
Springer
,
New York
,
2007
), Vol.
40
.
59.
I.
Lindgren
,
H.
Persson
,
S.
Salomonson
, and
A.
Ynnerman
,
Phys. Rev. A
47
,
R4555
(
1993
).
60.
H.
Persson
,
I.
Lindgren
, and
S.
Salomonson
,
Phys. Scr.
T46
,
125
(
1993
).
61.
I.
Grant
and
H.
Quiney
,
Atoms
10
,
108
(
2022
).
63.
P.
Kabir
and
E.
Salpeter
,
Phys. Rev.
108
,
1256
(
1957
).
65.
66.
67.
68.
D.
Ferenc
and
E.
Mátyus
,
J. Phys. Chem. A
127
,
627
(
2023
).
69.
V. I.
Korobov
and
S. V.
Korobov
,
Phys. Rev. A
59
,
3394
(
1999
).
70.
E.
Tiesinga
,
P. J.
Mohr
,
D. B.
Newell
, and
B. N.
Taylor
,
Rev. Mod. Phys.
93
,
025010
(
2021
).
71.
V. I.
Korobov
and et al,
Phys. Rev. A
87
,
062506
(
2013
).
72.
J.
Seke
and
W.
Mödritsch
,
Lett. Math. Phys.
24
,
115
(
1992
).
73.
H.
Persson
,
S.
Salomonson
, and
P.
Sunnergren
,
Adv. Quantum Chem.
30
,
379
(
1998
).
74.
H. M.
Quiney
and
I. P.
Grant
,
J. Phys. B: At., Mol. Opt. Phys.
49
,
L299
(
1994
).
75.
V. A.
Yerokhin
,
Phys. Rev. A
62
,
012508
(
2000
).
76.
I.
Goidenko
,
G.
Plunien
,
S.
Zschocke
,
L.
Labzowsky
, and
G.
Soff
,
Phys. Rev. A
65
,
042110
(
2002
).
77.
78.
Y.
Suzuki
and
K.
Varga
,
Stochastic Variational Approach to Quantum-Mechanical Few-Body Problems
(
Springer-Verlag
,
Berlin, Heidelberg
,
1998
).
79.
E.
Mátyus
and
M.
Reiher
,
J. Chem. Phys.
137
,
024104
(
2012
).
You do not currently have access to this content.