We consider a binary mixture of chemically active particles that produce or consume solute molecules and that interact with each other through the long-range concentration fields they generate. We analytically calculate the effective phoretic mobility of these particles when the mixture is submitted to a constant, external concentration gradient, at leading order in the overall concentration. Relying on an analogy with the modeling of strong electrolytes, we show that the effective phoretic mobility decays with the square root of the concentration: our result is, therefore, a nonequilibrium counterpart to the celebrated Kohlrausch and Debye–Hückel–Onsager conductivity laws for electrolytes, which are extended here to particles with long-range nonreciprocal interactions. The effective mobility law we derive reveals the existence of a regime of maximal mobility and could find applications in the description of nanoscale transport phenomena in living cells.
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21 April 2024
Research Article|
April 16 2024
Chemotactic particles as strong electrolytes: Debye–Hückel approximation and effective mobility law
Pierre Illien
;
Pierre Illien
a)
(Conceptualization, Investigation, Methodology, Writing – original draft, Writing – review & editing)
1
Laboratoire PHENIX (Physico-Chimie des Électrolytes et Nanosystèmes Interfaciaux), CNRS, Sorbonne Université
, 4 Place Jussieu, 75005 Paris, France
a)Author to whom correspondence should be addressed: [email protected]
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Ramin Golestanian
Ramin Golestanian
(Conceptualization, Investigation, Methodology, Writing – review & editing)
2
Department of Living Matter Physics, Max Planck Institute for Dynamics and Self-Organization
, D-37077 Göttingen, Germany
3
Rudolf Peierls Centre for Theoretical Physics, University of Oxford
, OX1 3PU Oxford, United Kingdom
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a)Author to whom correspondence should be addressed: [email protected]
J. Chem. Phys. 160, 154901 (2024)
Article history
Received:
February 15 2024
Accepted:
March 28 2024
Citation
Pierre Illien, Ramin Golestanian; Chemotactic particles as strong electrolytes: Debye–Hückel approximation and effective mobility law. J. Chem. Phys. 21 April 2024; 160 (15): 154901. https://doi.org/10.1063/5.0203593
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