The dynamics of wire frame particles in concentrated suspension are studied by means of a 2D model and compared to those of rod-like particles. The wire frames have bent or branched structures constructed from infinitely thin, rigid rods. In the model, a particle is surrounded by diffusing points that it cannot cross. We derive a formal expression for the mean squared displacement (MSD) and, by using a self-consistent approximation, we find markedly different dynamics for wire frames and rods. For wire frames, there exists a critical concentration of points above which they become frozen with the long time MSD reaching a plateau. Rods, on the other hand, always diffuse by reptation. We also study the rheology through the elastic stress, and more striking differences are found: the initial magnitude of the stress for wire frames is much larger than for rods, scaling such as the square of the point concentration, and above the critical concentration, the stress for wire frames appears to persist indefinitely while for rods it always decays.
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7 September 2023
Research Article|
September 05 2023
Dynamics of wire frame glasses in two dimensions
Special Collection:
2023 JCP Emerging Investigators Special Collection
David A. King
David A. King
a)
(Conceptualization, Formal analysis, Investigation, Methodology, Writing – original draft, Writing – review & editing)
Department of Physics and Astronomy, University of Pennsylvania
, 209 South 33rd St., Philadelphia, Pennsylvania 19104, USA
a)Author to whom correspondence should be addressed: daviking@sas.upenn.edu
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a)Author to whom correspondence should be addressed: daviking@sas.upenn.edu
J. Chem. Phys. 159, 094903 (2023)
Article history
Received:
June 22 2023
Accepted:
August 11 2023
Citation
David A. King; Dynamics of wire frame glasses in two dimensions. J. Chem. Phys. 7 September 2023; 159 (9): 094903. https://doi.org/10.1063/5.0164438
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