The Mpemba effect is a fingerprint of the anomalous relaxation phenomenon wherein an initially hotter system equilibrates faster than an initially colder system when both are quenched to the same low temperature. Experiments on a single colloidal particle trapped in a carefully shaped double well potential have demonstrated this effect recently [A. Kumar and J. Bechhoefer, Nature 584, 64 (2020)]. In a similar vein, here, we consider a piece-wise linear double well potential that allows us to demonstrate the Mpemba effect using an exact analysis based on the spectral decomposition of the corresponding Fokker–Planck equation. We elucidate the role of the metastable states in the energy landscape as well as the initial population statistics of the particles in showcasing the Mpemba effect. Crucially, our findings indicate that neither the metastability nor the asymmetry in the potential is a necessary or a sufficient condition for the Mpemba effect to be observed.
Skip Nav Destination
Article navigation
28 July 2023
Research Article|
July 31 2023
Mpemba effect in a Langevin system: Population statistics, metastability, and other exact results
Special Collection:
2023 JCP Emerging Investigators Special Collection
Apurba Biswas
;
Apurba Biswas
a)
(Conceptualization, Formal analysis, Investigation, Methodology, Validation, Writing – original draft, Writing – review & editing)
1
The Institute of Mathematical Sciences, C.I.T. Campus
, Taramani, Chennai 600113, India
2
Homi Bhabha National Institute, Training School Complex
, Anushakti Nagar, Mumbai 400094, India
Search for other works by this author on:
R. Rajesh
;
R. Rajesh
b)
(Investigation, Methodology, Supervision, Validation, Writing – review & editing)
1
The Institute of Mathematical Sciences, C.I.T. Campus
, Taramani, Chennai 600113, India
2
Homi Bhabha National Institute, Training School Complex
, Anushakti Nagar, Mumbai 400094, India
Search for other works by this author on:
Arnab Pal
Arnab Pal
c)
(Conceptualization, Investigation, Methodology, Supervision, Validation, Writing – review & editing)
1
The Institute of Mathematical Sciences, C.I.T. Campus
, Taramani, Chennai 600113, India
2
Homi Bhabha National Institute, Training School Complex
, Anushakti Nagar, Mumbai 400094, India
c)Author to whom correspondence should be addressed: arnabpal@imsc.res.in
Search for other works by this author on:
c)Author to whom correspondence should be addressed: arnabpal@imsc.res.in
a)
Electronic mail: apurbab@imsc.res.in
b)
Electronic mail: rrajesh@imsc.res.in
J. Chem. Phys. 159, 044120 (2023)
Article history
Received:
April 24 2023
Accepted:
July 06 2023
Citation
Apurba Biswas, R. Rajesh, Arnab Pal; Mpemba effect in a Langevin system: Population statistics, metastability, and other exact results. J. Chem. Phys. 28 July 2023; 159 (4): 044120. https://doi.org/10.1063/5.0155855
Download citation file:
Sign in
Don't already have an account? Register
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Sign in via your Institution
Sign in via your InstitutionPay-Per-View Access
$40.00