Theoretical prediction of interfacial capacitance in graphene-based supercapacitors is crucial to accelerating materials’ design and development cycles. However, there is currently a significant gap between ab initio predictions and experimental reports, particularly in the case of nitrogen-doped graphene. Analyses based on changes to the density of states of freestanding graphene upon doping do not account for the electronic interactions between the electrode, dopants, and substrates. The result is an overestimation of the doping-induced capacitance increase by up to two orders of magnitude. Moreover, it is unclear whether electrolyte and solvent interactions can further complicate matters by inducing changes to the band structure and, therefore, the capacitive properties of the electrode. A third complication lies in the fixed-band approximation, where materials are simulated without accounting for the influence of an external electrical field. In this work, we present an interfacial modeling and characterization procedure that leverages the combined strengths of ab-initio molecular dynamics, density functional theory, and microscopic polarization theory to produce reliable predictions of interfacial capacitance. The procedure is applied to two case studies of interest in supercapacitor design: (1) nitrogen-doped graphene on a Cu(111) substrate and (2) an interface between bulk water and Cu(111)-supported graphene at room temperature. Results show that water alters graphene’s band structure from a semi-metallic to an n-doped-semiconducting character and that metallic substrates dominate the band structure of the electrode interface even in the presence of dopants. The water interface also shows an asymmetric capacitive response relative to the polarity of the applied field.
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