The dynamics of many-body fermionic systems are important in problems ranging from catalytic reactions at electrochemical surfaces to transport through nanojunctions and offer a prime target for quantum computing applications. Here, we derive the set of conditions under which fermionic operators can be exactly replaced by bosonic operators that render the problem amenable to a large toolbox of dynamical methods while still capturing the correct dynamics of n-body operators. Importantly, our analysis offers a simple guide on how one can exploit these simple maps to calculate nonequilibrium and equilibrium single- and multi-time correlation functions essential in describing transport and spectroscopy. We use this to rigorously analyze and delineate the applicability of simple yet effective Cartesian maps that have been shown to correctly capture the correct fermionic dynamics in select models of nanoscopic transport. We illustrate our analytical results with exact simulations of the resonant level model. Our work provides new insights as to when one can leverage the simplicity of bosonic maps to simulate the dynamics of many-electron systems, especially those where an atomistic representation of nuclear interactions becomes essential.
Skip Nav Destination
Article navigation
7 March 2023
Research Article|
March 07 2023
A derivation of the conditions under which bosonic operators exactly capture fermionic structure and dynamics
Andrés Montoya-Castillo
;
Andrés Montoya-Castillo
a)
(Conceptualization, Formal analysis, Investigation, Methodology, Software, Writing – original draft, Writing – review & editing)
1
Department of Chemistry, University of Colorado Boulder
, Boulder, Colorado 80309, USA
Search for other works by this author on:
Thomas E. Markland
Thomas E. Markland
b)
(Conceptualization, Formal analysis, Funding acquisition, Methodology, Writing – original draft, Writing – review & editing)
2
Department of Chemistry, Stanford University
, Stanford, California 94305, USA
b)Author to whom correspondence should be addressed: tmarkland@stanford.edu
Search for other works by this author on:
a)
Electronic mail: Andres.MontoyaCastillo@colorado.edu
b)Author to whom correspondence should be addressed: tmarkland@stanford.edu
J. Chem. Phys. 158, 094112 (2023)
Article history
Received:
December 13 2022
Accepted:
February 13 2023
Citation
Andrés Montoya-Castillo, Thomas E. Markland; A derivation of the conditions under which bosonic operators exactly capture fermionic structure and dynamics. J. Chem. Phys. 7 March 2023; 158 (9): 094112. https://doi.org/10.1063/5.0138664
Download citation file:
Sign in
Don't already have an account? Register
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Sign in via your Institution
Sign in via your InstitutionPay-Per-View Access
$40.00
Citing articles via
Related Content
An Exactly Soluble Model of a Many‐Fermion System
J. Math. Phys. (December 2004)
An exactly soluble relativistic quantum two‐fermion problem
J. Math. Phys. (December 1986)
Boson Expansions for an Exactly Soluble Model of Interacting Fermions with SU(3) Symmetry
J. Math. Phys. (October 2003)
Relations between parameters of density functional theories through exactly solvable many-fermion models
J. Chem. Phys. (June 2001)
Exactly Solvable Models Based on the Pairing Interaction
AIP Conference Proceedings (November 2002)