We investigate the efficiency of a quantum Carnot engine based on open quantum dynamics theory. The model includes time-dependent external fields for the subsystems controlling the isothermal and isentropic processes and for the system–bath (SB) interactions controlling the transition between these processes. Numerical simulations are conducted in a nonperturbative and non-Markovian SB coupling regime by using the hierarchical equations of motion under these fields at different cycle frequencies. The work applied to the total system and the heat exchanged with the baths are rigorously evaluated. In addition, by regarding quasi-static work as free energy, we compute the quantum thermodynamic variables and analyze the simulation results by using thermodynamic work diagrams for the first time. Analysis of these diagrams indicates that, in the strong SB coupling region, the fields for the SB interactions are major sources of work, while in other regions, the field for the subsystem is a source of work. We find that the maximum efficiency is achieved in the quasi-static case and is determined solely by the bath temperatures, regardless of the SB coupling strength, which is a numerical manifestation of Carnot’s theorem.
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28 August 2022
Research Article|
August 23 2022
Numerically “exact” simulations of a quantum Carnot cycle: Analysis using thermodynamic work diagrams
Shoki Koyanagi
;
Shoki Koyanagi
(Conceptualization, Data curation, Formal analysis, Investigation, Software, Writing – original draft)
Department of Chemistry, Graduate School of Science, Kyoto University
, Kyoto 606-8502, Japan
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Yoshitaka Tanimura
Yoshitaka Tanimura
a)
(Conceptualization, Data curation, Formal analysis, Investigation, Writing – review & editing)
Department of Chemistry, Graduate School of Science, Kyoto University
, Kyoto 606-8502, Japan
a)Author to whom correspondence should be addressed: tanimura.yoshitaka.5w@kyoto-u.jp
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a)Author to whom correspondence should be addressed: tanimura.yoshitaka.5w@kyoto-u.jp
J. Chem. Phys. 157, 084110 (2022)
Article history
Received:
July 04 2022
Accepted:
July 28 2022
Citation
Shoki Koyanagi, Yoshitaka Tanimura; Numerically “exact” simulations of a quantum Carnot cycle: Analysis using thermodynamic work diagrams. J. Chem. Phys. 28 August 2022; 157 (8): 084110. https://doi.org/10.1063/5.0107305
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