Spatial displacements of spins between radio frequency pulses in a Double-Quantum (DQ) nuclear magnetic resonance pulse sequence generate additional terms in the effective DQ Hamiltonian. We derive a simple expression that allows the estimation and control of these contributions to the initial rise of the DQ build up function by variation of experimental parameters in systems performing anomalous diffusion. The application of polymers is discussed.
REFERENCES
1.
J.
Baum
and A.
Pines
, J. Am. Chem. Soc.
108
, 7447
(1986
).2.
R.
Graf
, A.
Heuer
, and H. W.
Spiess
, Phys. Rev. Lett.
80
, 5738
(1998
).3.
T.
Dollase
, R.
Graf
, A.
Heuer
, and H. W.
Spiess
, Macromolecules
34
, 298
(2001
).4.
K.
Saalwächter
, Macromol. Rapid Commun.
23
, 286
(2002
).5.
K.
Saalwächter
, Chem. Phys. Lett.
362
, 331
(2002
).6.
R.
Fechete
, D. E.
Demco
, and B.
Blümich
, Macromolecules
35
, 6083
(2002
).7.
K.
Saalwächter
, P.
Zeigler
, O.
Spyckerelle
, B.
Haidar
, A.
Vidal
, and J.-U.
Sommer
, Macromolecules
119
, 3468
(2003
).8.
K.
Saalwächter
and A.
Heuer
, Macromolecules
39
, 3291
(2006
).9.
A.
Mordvinkin
and K.
Saalwächter
, J. Chem. Phys.
146
, 094902
(2017
).10.
K.
Saalwächter
, Prog. Nucl. Magn. Reson. Spectrosc.
51
, 1
(2007
).11.
F.
Vaca Chávez
and K.
Saalwächter
, Macromolecules
44
, 1549
(2011
).12.
A.
Mordvinkin
, D.
Döhler
, W. H.
Binder
, R. H.
Colby
, and K.
Saalwächter
, Phys. Rev. Lett.
125
, 127801
(2020
).13.
F.
Shahsavan
, M.
Beiner
, and K.
Saalwächter
, J. Polym. Sci.
60
, 1266
–1276
(2022
).14.
S.
Stapf
and S.
Kariyo
, Acta Phys. Pol., A
108
, 247
–259
(2005
).15.
N.
Fatkullin
, C.
Mattea
, and S.
Stapf
, J. Chem. Phys.
139
, 194905
(2013
).16.
M.
Mehring
, Principles of High Resolution NMR in Solids
, 2nd ed. (Springer-Verlag
, Berlin, Heidelberg, New York
, 1983
).17.
18.
K.
Saalwächter
, J. Chem. Phys.
141
, 064201
(2014
).19.
R.
Kimmich
and N.
Fatkullin
, Prog. Nucl. Magn. Reson. Spectrosc.
101
, 18
(2017
).20.
E. A.
Rössler
, S.
Stapf
, and N.
Fatkullin
, Curr. Opin. Colloid Interface Sci.
18
, 173
(2013
).21.
N.
Fatkullin
, S.
Stapf
, M.
Hofmann
, R.
Meier
, and E. A.
Rössler
, J. Non-Cryst. Solids
407
, 309
(2015
).22.
N.
Fatkullin
, A.
Gubaidullin
, C.
Mattea
, and S.
Stapf
, J. Chem. Phys.
137
, 224907
(2012
).© 2022 Author(s). Published under an exclusive license by AIP Publishing.
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