Swollen cubic lyotropic ternary phases with Pn3m symmetry and reduced hardness were obtained from a specific binary mixture of cubic phase-forming (phytantriol) and lamellar phase-forming (decaglycerol monooleate) compounds. The microstructures were determined by using a small-angle x-ray scattering technique. The softness and temperature-induced phase transitions were investigated by means of rheology. The incorporation of a surface-active fragrance compound (linalool) at concentrations up to 6 wt. % induced a structural transition toward a softer Im3m bulk cubic phase with longer water channels. Higher linalool concentrations allowed for the spontaneous dispersion of the bulk cubic phase into microscopic particles with a cubic structure (cubosomes).
REFERENCES
1.
R.
Mezzenga
, J. M.
Seddon
, C. J.
Drummond
, B. J.
Boyd
, G. E.
Schröder‐Turk
, and L.
Sagalowicz
, Adv. Mater.
31
, 1900818
(2019
).2.
B. J.
Boyd
, in Bicontinuous Liquid Crystals
, edited by M. L.
Lynch
and P.
Spicer
(CRC Press
, Boca Raton, FL
, 2005
), p. 289
.3.
C.
Fong
, T.
Le
, and C. J.
Drummond
, Chem. Soc. Rev.
41
, 1297
(2012
).4.
S.
Milak
and A.
Zimmer
, Int. J. Pharm.
478
, 569
(2015
).5.
G.
Garg
, S.
Saraf
, and S.
Saraf
, Biol. Pharm. Bull.
30
, 350
(2007
).6.
V.
Tchakalova
, F.
Testard
, K.
Wong
, A.
Parker
, D.
Benczédi
, and T.
Zemb
, Colloids Surf., A
331
, 31
(2008
).7.
V.
Tchakalova
, F.
Testard
, K.
Wong
, A.
Parker
, D.
Benczédi
, and T.
Zemb
, Colloids Surf., A
331
, 40
(2008
).8.
V.
Tchakalova
and W.
Fieber
, J. Surfactants Deterg.
15
, 167
(2012
).9.
10.
T.
Lukowicz
, R.
Company Maldonado
, V.
Molinier
, J.-M.
Aubry
, and V.
Nardello-Rataj
, Colloids Surf., A
458
, 85
(2014
).11.
N.
Kanei
, K.-i.
Watanabe
, and H.
Kunieda
, J. Oleo Sci.
52
, 607
(2003
).12.
M. H.
Uddin
, N.
Kanei
, and H.
Kunieda
, Langmuir
16
, 6891
(2000
).13.
M.
Kumbhakar
, T.
Goel
, T.
Mukherjee
, and H.
Pal
, J. Phys. Chem. B
109
, 14168
(2005
).14.
A.
Tidu
, F.
Méducin
, A.-M.
Faugère
, and S.
Guillot
, Langmuir
34
, 13283
(2018
).15.
N.
Amar-Zrihen
, A.
Aserin
, and N.
Garti
, J. Agric. Food Chem.
59
, 5554
(2011
).16.
A.
Yaghmur
, L.
de Campo
, L.
Sagalowicz
, M. E.
Leser
, and O.
Glatter
, Langmuir
21
, 569
(2005
).17.
J.
Borné
, T.
Nylander
, and A.
Khan
, Langmuir
16
, 10044
(2000
).18.
J.
Borné
, T.
Nylander
, and A.
Khan
, Langmuir
17
, 7742
(2001
).19.
P. J.
Maddaford
and C.
Toprakcioglu
, Langmuir
9
, 2868
(1993
).20.
A.
Zabara
, J. T. Y.
Chong
, I.
Martiel
, L.
Stark
, B. A.
Cromer
, C.
Speziale
, C. J.
Drummond
, and R.
Mezzenga
, Nat. Commun.
9
, 544
(2018
).21.
C. V.
Kulkarni
, W.
Wachter
, G.
Iglesias-Salto
, S.
Engelskirchen
, and S.
Ahualli
, Phys. Chem. Chem. Phys.
13
, 3004
(2011
).22.
S.
Richert
, A.
Schrader
, and K.
Schrader
, Int. J. Cosmet. Sci.
25
, 5
(2003
).23.
T.
Zemb
, O.
Tache
, F.
Né
, and O.
Spalla
, J. Appl. Crystallogr.
36
, 800
(2003
).24.
T.
Zemb
, O.
Taché
, F.
Né
, and O.
Spalla
, Rev. Sci. Instrum.
74
, 2456
(2003
).25.
J.
Barauskas
and T.
Landh
, Langmuir
19
, 9562
(2003
).26.
J. F.
Dufrêche
and Th.
Zemb
, Curr. Opin. Colloid Interface Sci.
49
, 133
(2020
).27.
S. T.
Hyde
, in Handbook of Applied Surface and Colloid Chemistry
, edited by K.
Holmberg
(John Willey & Sons, Ltd.
, 2001), Ch. 16.28.
M.
Kanduč
, A.
Schlaich
, A. H.
de Vries
, J.
Jouhet
, E.
Maréchal
, B.
Demé
, R. R.
Netz
, and E.
Schneck
, Nat. Commun.
8
, 14899
(2017
).29.
R.
Guo
, J.
Yang
, S. E.
Friberg
, V.
Landeryou
, and L.
Hall
, J. Dispersion Sci. Technol.
21
, 1
–18
(2000
).30.
J.
Briggs
, H.
Chung
, and M.
Caffrey
, J. Phys. II France
6
, 723
(1996
).31.
T. N.
Zemb
, S. T.
Hyde
, P. J.
Derian
, I. S.
Barnes
, and B. W.
Ninham
, J. Phys. Chem.
91
, 3814
(1987
).32.
D. C.
Turner
, Z.-G.
Wang
, S. M.
Gruner
, D. A.
Mannock
, and R. N.
McElhaney
, J. Phys. II
2
, 2039
(1992
).33.
A.
Gulik
, V.
Luzzati
, M.
De Rosa
, and A.
Gambacorta
, J. Mol. Biol.
182
, 131
(1985
).34.
C.
Speziale
, R.
Ghanbari
, and R.
Mezzenga
, Langmuir
34
, 5052
(2018
).35.
H.
Chung
and M.
Caffrey
, Biophys. J.
66
, 377
(1994
).36.
S. T.
Hyde
, J. Phys. Chem.
93
, 1458
(1989
).37.
R.
Mezzenga
, C.
Meyer
, C.
Servais
, A. I.
Romoscanu
, L.
Sagalowicz
, and R. C.
Hayward
, Langmuir
21
, 3322
(2005
).38.
Y.
Yao
, S.
Catalini
, B.
Kutus
, J.
Hunger
, P.
Foggi
, and R.
Mezzenga
, Angew. Chem., Int. Ed.
60
, 25274
(2021
).39.
M.
Gradzielski
, M.
Duvail
, P. M.
de Molina
, M.
Simon
, Y.
Talmon
, and T.
Zemb
, Chem. Rev.
121
, 5671
(2021
).40.
A. M.
Squires
, R. H.
Templer
, J. M.
Seddon
, J.
Woenkhaus
, R.
Winter
, T.
Narayanan
, and S.
Finet
, Phys. Rev. E
72
, 011502
(2005
).41.
T.
Oka
, Langmuir
31
, 3180
(2015
).42.
R.
Negrini
and R.
Mezzenga
, Langmuir
28
, 16455
(2012
).43.
Y.
Aota-Nakano
, S. J.
Li
, and M.
Yamazaki
, Biochim. Biophys. Acta, Biomembr.
1461
, 96
(1999
).44.
G. C.
Shearman
, B. J.
Khoo
, M.-L.
Motherwell
, K. A.
Brakke
, O.
Ces
, C. E.
Conn
, J. M.
Seddon
, and R. H.
Templer
, Langmuir
23
, 7276
(2007
).45.
Bicontinuous Liquid Crystals
, edited by M. L.
Lynch
and P. T.
Spicer
(CRC Press
, Boca Raton, FL
, 2005
).© 2022 Author(s). Published under an exclusive license by AIP Publishing.
2022
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