To overcome the traditional paradigm of filtration, where separation is essentially performed upon steric sieving principles, we explore the concept of dynamic osmosis through active membranes. A partially permeable membrane presents a time-tuneable feature that changes the effective pore interaction with the solute and thus actively changes permeability with time. In general, we find that slow flickering frequencies effectively decrease the osmotic pressure and large flickering frequencies do not change it. In the presence of an asymmetric membrane, we find a resonant frequency where pumping of the solute is performed and can be analyzed in terms of ratchet transport. We discuss and highlight the properties of this resonant osmotic transport. Furthermore, we show that dynamic osmosis allows us to pump the solute at the nanoscale using less energy than reverse osmosis. This opens new possibilities to build advanced filtration devices and design artificial ionic machinery.
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7 February 2020
Research Article|
February 03 2020
Resonant osmosis across active switchable membranes
Sophie Marbach
;
Laboratoire de Physique de l’Ecole normale supérieure, ENS, Université PSL, CNRS, Sorbonne Université, Université de Paris
, F-75005 Paris, France
b)Author to whom correspondence should be addressed: lyderic.bocquet@ens.fr
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Nikita Kavokine
;
Nikita Kavokine
Laboratoire de Physique de l’Ecole normale supérieure, ENS, Université PSL, CNRS, Sorbonne Université, Université de Paris
, F-75005 Paris, France
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Lydéric Bocquet
Lydéric Bocquet
b)
Laboratoire de Physique de l’Ecole normale supérieure, ENS, Université PSL, CNRS, Sorbonne Université, Université de Paris
, F-75005 Paris, France
b)Author to whom correspondence should be addressed: lyderic.bocquet@ens.fr
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a)
Present address: Courant Institute of Mathematical Sciences, New York University, New York, New York, USA.
b)Author to whom correspondence should be addressed: lyderic.bocquet@ens.fr
J. Chem. Phys. 152, 054704 (2020)
Article history
Received:
November 16 2019
Accepted:
January 08 2020
Connected Content
A companion article has been published:
Dynamic osmosis is demonstrated as an alternative water filtration system
Citation
Sophie Marbach, Nikita Kavokine, Lydéric Bocquet; Resonant osmosis across active switchable membranes. J. Chem. Phys. 7 February 2020; 152 (5): 054704. https://doi.org/10.1063/1.5138987
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