In Paper I [O. Coquand and M. Sperl, J. Chem. Phys. 152, 124112 (2020)], we derived analytical expressions for the structure factor of the square-shoulder potential in a perturbative way around the high- and low-temperature regimes. Here, various physical properties of these solutions are derived. In particular, we investigate the large wave number sector and relate it to the contact values of the pair-correlation function. Then, the thermoelastic properties of the square-shoulder fluids are discussed.
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In this last reference, the computation is done for a square-well potential. However, the expressions are exactly identical in the case of a square-shoulder potential, except for the sign of the potential in the region [R; d].
© 2020 Author(s).
2020
Author(s)
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