Recent experiments have shown that colloidal suspensions can spontaneously self-assemble into dense clusters of various internal structures, sizes, and dynamical properties when doped with active Janus particles. Characteristically, these clusters move ballistically during their formation but dynamically revert their velocity and temporarily move opposite to the self-propulsion direction of the Janus particles they contain. Here, we explore a simple effective model of colloidal mixtures that allows reproducing most aspects seen in experiments, including the morphology and the velocity-reversal of the clusters. We attribute the latter to the nonreciprocal phoretic attractions of the passive particles to the active colloids’ caps, taking place even at close contact and pushing the active particles backwards. When the phoretic interactions are repulsive, in turn, they cause dynamical aggregation of passive colloids in the chemical density minima produced by the active particles, as recently seen in experiments; in other parameter regimes, they induce traveling fronts of active particles pursued by passive ones coexisting with an active gas.
REFERENCES
The recently developed AAA model46 could be used as an alternative to the present model, after extending it to account for the anisotropy in the chemical production as necessary to model the velocity-reversals; however, it does not admit to explore delay-effects due to the noninstantaneous chemical relaxation, which can be important for the case of repulsive phoretic interactions38,39 and which we study here for active-passive mixtures.
We alternatingly iterate the particle positions and the chemical field by one step, using time step size ranging from Δt = 2.5 × 10−7 to Δt = 2 × 10−6 depending on the specific simulation. For the finite difference grid, we chose a spacing of .