We propose a novel approach to cavity-ring-down-spectroscopy (CRDS) in which spectra acquired with a frequency-agile rapid-scanning (FARS) scheme, i.e., with a laser sideband stepped across the modes of a high-finesse cavity, are interleaved with one another by a sub-millisecond readjustment of the cavity length. This brings to time acquisitions below 20 s for few-GHz-wide spectra composed of a very high number of spectral points, typically 3200. Thanks to the signal-to-noise ratio easily in excess of 10 000, each FARS-CRDS spectrum is shown to be sufficient to determine the line-centre frequency of a Doppler broadened line with a precision of 2 parts over 1011, thus very close to that of sub-Doppler regimes and in a few-seconds time scale. The referencing of the probe laser to a frequency comb provides absolute accuracy and long-term reproducibility to the spectrometer and makes it a powerful tool for precision spectroscopy and line-shape analysis. The experimental approach is discussed in detail together with experimental precision and accuracy tests on the (30 012) (00 001) P12e line of CO2 at ∼1.57 μm.
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Conjugating precision and acquisition time in a Doppler broadening regime by interleaved frequency-agile rapid-scanning cavity ring-down spectroscopy
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7 October 2017
Research Article|
October 05 2017
Conjugating precision and acquisition time in a Doppler broadening regime by interleaved frequency-agile rapid-scanning cavity ring-down spectroscopy
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Riccardo Gotti
;
Riccardo Gotti
1
Dipartimento di Fisica–Politecnico di Milano and IFN-CNR
, Via Gaetano Previati 1/C, 23900 Lecco, Italy
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Davide Gatti
;
Davide Gatti
1
Dipartimento di Fisica–Politecnico di Milano and IFN-CNR
, Via Gaetano Previati 1/C, 23900 Lecco, Italy
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Piotr Masłowski;
Piotr Masłowski
2
Institute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University
, Grudziadzka 5, 87-100 Torun, Poland
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Marco Lamperti
;
Marco Lamperti
1
Dipartimento di Fisica–Politecnico di Milano and IFN-CNR
, Via Gaetano Previati 1/C, 23900 Lecco, Italy
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Michele Belmonte;
Michele Belmonte
3
Oclaro, Inc.
, Via F. Fellini, 4, 20097 San Donato Milanese, Italy
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Paolo Laporta
;
Paolo Laporta
1
Dipartimento di Fisica–Politecnico di Milano and IFN-CNR
, Via Gaetano Previati 1/C, 23900 Lecco, Italy
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Marco Marangoni
Marco Marangoni
1
Dipartimento di Fisica–Politecnico di Milano and IFN-CNR
, Via Gaetano Previati 1/C, 23900 Lecco, Italy
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Riccardo Gotti
1
Davide Gatti
1
Piotr Masłowski
2
Marco Lamperti
1
Michele Belmonte
3
Paolo Laporta
1
Marco Marangoni
1
1
Dipartimento di Fisica–Politecnico di Milano and IFN-CNR
, Via Gaetano Previati 1/C, 23900 Lecco, Italy
2
Institute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University
, Grudziadzka 5, 87-100 Torun, Poland
3
Oclaro, Inc.
, Via F. Fellini, 4, 20097 San Donato Milanese, Italy
J. Chem. Phys. 147, 134201 (2017)
Article history
Received:
August 04 2017
Accepted:
September 19 2017
Citation
Riccardo Gotti, Davide Gatti, Piotr Masłowski, Marco Lamperti, Michele Belmonte, Paolo Laporta, Marco Marangoni; Conjugating precision and acquisition time in a Doppler broadening regime by interleaved frequency-agile rapid-scanning cavity ring-down spectroscopy. J. Chem. Phys. 7 October 2017; 147 (13): 134201. https://doi.org/10.1063/1.4999056
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