The structure profiles and physical properties of the adsorbed water film on a mica surface under conditions with different degrees of relative humidity are investigated by a surface force apparatus. The first layer of the adsorbed water film shows ice-like properties, including a lattice constant similar with ice crystal, a high bearing capacity that can support normal pressure as high as 4 MPa, a creep behavior under the action of even a small normal load, and a character of hydrogen bond. Adjacent to the first layer of the adsorbed water film, the water molecules in the outer layer are liquid-like that can flow freely under the action of external loads. Experimental results demonstrate that the adsorbed water layer makes the mica surface change from hydrophilic to weak hydrophobic. The weak hydrophobic surface may induce the latter adsorbed water molecules to form water islands on a mica sheet.

1.
R.
Guckenberger
,
M.
Heim
,
G.
Cevc
,
H. F.
Knapp
,
W.
Wiegrabe
, and
A.
Hillebrand
,
Science
266
,
1538
(
1994
).
2.
M.
Odelius
,
M.
Bernasconi
, and
M.
Parrinello
,
Phys. Rev. Lett.
78
,
2855
(
1997
).
3.
J.
Hu
,
X. D.
Xiao
,
D. F.
Ogletree
, and
M.
Salmeron
,
Science
268
,
267
(
1995
).
4.
A.
Verdaguer
,
G. M.
Sacha
,
H.
Bluhm
, and
M.
Salmeron
,
Chem. Rev.
106
,
1478
(
2006
).
5.
H.
Bluhm
and
M.
Salmeron
,
J. Chem. Phys.
111
,
6947
(
1999
).
6.
K.
Xu
,
P. G.
Cao
, and
J. R.
Heath
,
Science
329
,
1188
(
2010
).
7.
D.
Beaglehole
and
H. K.
Christenson
,
J. Phys. Chem.
96
,
3395
(
1992
).
8.
J. R.
Zimmerman
and
J. A.
Lasater
,
J. Phys. Chem.
62
,
1157
(
1958
).
9.
H. K.
Christenson
,
J. Phys. Chem.
97
,
12034
(
1993
).
10.
R. M.
Pashley
and
J. N.
Israelachvili
,
J. Colloid Interface Sci.
101
,
511
(
1984
).
11.
T. E.
Balmer
,
H. K.
Christenson
,
N. D.
Spencer
, and
M.
Heuberger
,
Langmuir
24
,
1566
(
2008
).
12.
D. B.
Asay
and
S. H.
Kim
,
J. Phys. Chem. B
109
,
16760
(
2005
).
13.
D. B.
Asay
and
S. H.
Kim
,
Langmuir
23
,
12174
(
2007
).
14.
W. H.
Briscoe
,
S.
Titmuss
,
F.
Tiberg
,
R. K.
Thomas
,
D. J.
McGillivray
, and
J.
Klein
,
Nature
444
,
191
(
2006
).
15.
U.
Raviv
,
S.
Giasson
,
N.
Kampf
,
J. F.
Gohy
,
R.
Jerome
, and
J.
Klein
,
Nature
425
,
163
(
2003
).
16.
U.
Raviv
,
P.
Laurat
, and
J.
Klein
,
Nature
413
,
51
(
2001
).
17.
M. P.
Goertz
,
J. E.
Houston
, and
X. Y.
Zhu
,
Langmuir
23
,
5491
(
2007
).
18.
U.
Raviv
,
S.
Perkin
,
P.
Laurat
, and
J.
Klein
,
Langmuir
20
,
5322
(
2004
).
19.
U.
Raviv
and
J.
Klein
,
Science
297
,
1540
(
2002
).
20.
Y. S.
Leng
and
P. T.
Cummings
,
J. Chem. Phys.
124
,
219907
(
2006
).
21.
H.
Sakuma
,
K.
Otsuki
, and
K.
Kurihara
,
Phys. Rev. Lett.
96
,
046104
(
2006
).
22.
S. H.
Khan
,
G.
Matei
,
S.
Patil
, and
P. M.
Hoffmann
,
Phys. Rev. Lett.
105
,
106101
(
2010
).
23.
P. J.
Feibelman
,
Phys. Today
63
(
2
),
34
(
2010
).
24.
J. N.
Israelachvili
,
Y.
Min
,
M.
Akbulut
,
A.
Alig
,
G.
Carver
,
W.
Greene
,
K.
Kristiansen
,
E.
Meyer
,
N.
Pesika
,
K.
Rosenberg
, and
H.
Zeng
,
Rep. Prog. Phys.
73
,
1
(
2010
).
25.
G. T.
Zhao
,
Q. Y.
Tan
,
L.
Xiang
,
D.
Zhang
,
Z. H.
Ni
,
H.
Yi
, and
Y. F.
Chen
,
Rev. Sci. Instrum.
85
,
013702
(
2014
).
26.
H.
Zeng
,
Y.
Tian
,
B.
Zhao
,
M.
Tirrell
, and
J.
Israelachvili
,
Macromolecules
40
,
8409
(
2007
).
27.
H. B.
Zeng
,
Y.
Tian
,
B. X.
Zhao
,
M.
Tirrell
, and
J.
Israelachvili
,
Langmuir
23
,
6126
(
2007
).
28.
H. B.
Zeng
,
Y.
Tian
,
B. X.
Zhao
,
M.
Tirrell
, and
J.
Israelachvili
,
Soft Matter
3
,
88
(
2007
).
29.
Y. S.
Leng
and
P. T.
Cummings
,
Phys. Rev. Lett.
94
,
026101
(
2005
).
30.
P. B.
Miranda
,
L.
Xu
,
Y. R.
Shen
, and
M.
Salmeron
,
Phys. Rev. Lett.
81
,
5876
(
1998
).
31.
L.
Cheng
,
P.
Fenter
,
K. L.
Nagy
,
M. L.
Schlegel
, and
N. C.
Sturchio
,
Phys. Rev. Lett.
87
,
156103
(
2001
).
32.
J. N.
Israelachvili
,
Intermolecular and Surface Forces
, 3rd ed. (
Elsevier Science
,
San Diego
,
2011
).
33.
J. N.
Israelachvili
and
R. M.
Pashley
,
Nature
306
,
249
(
1983
).
34.
L.
Xu
,
A.
Lio
,
J.
Hu
,
D. F.
Ogletree
, and
M.
Salmeron
,
J. Phys. Chem. B
102
,
540
(
1998
).
35.
N.
Maeda
and
J. N.
Israelachvili
,
J. Phys. Chem. B
106
,
3534
(
2002
).
36.
N.
Maeda
,
J. N.
Israelachvili
, and
M.
Kohonen
,
Proc. Natl. Acad. Sci. U. S. A.
100
,
803
(
2003
).
37.
N. H.
Fletcher
,
The Chemical Physics of Ice
, 1st ed. (
Cambridge University Press
,
1970
).
38.
S. H.
Park
and
G.
Sposito
,
Phys. Rev. Lett.
89
,
085501
(
2002
).
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