The structure profiles and physical properties of the adsorbed water film on a mica surface under conditions with different degrees of relative humidity are investigated by a surface force apparatus. The first layer of the adsorbed water film shows ice-like properties, including a lattice constant similar with ice crystal, a high bearing capacity that can support normal pressure as high as 4 MPa, a creep behavior under the action of even a small normal load, and a character of hydrogen bond. Adjacent to the first layer of the adsorbed water film, the water molecules in the outer layer are liquid-like that can flow freely under the action of external loads. Experimental results demonstrate that the adsorbed water layer makes the mica surface change from hydrophilic to weak hydrophobic. The weak hydrophobic surface may induce the latter adsorbed water molecules to form water islands on a mica sheet.
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14 September 2015
Research Article|
September 14 2015
Structure and properties of water film adsorbed on mica surfaces Available to Purchase
Gutian Zhao;
Gutian Zhao
a)
1Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments,
Southeast University
, Nanjing 211189, China
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Qiyan Tan;
Qiyan Tan
a)
1Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments,
Southeast University
, Nanjing 211189, China
3School of Mechanical Engineering,
Nanjing Institute of Technology
, Nanjing 211167, China
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Li Xiang;
Li Xiang
1Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments,
Southeast University
, Nanjing 211189, China
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Di Cai;
Di Cai
1Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments,
Southeast University
, Nanjing 211189, China
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Hongbo Zeng;
Hongbo Zeng
2Department of Chemical and Materials Engineering,
University of Alberta, Edmonton
, Alberta T6G 2V43, Canada
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Hong Yi;
Hong Yi
1Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments,
Southeast University
, Nanjing 211189, China
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Zhonghua Ni;
Zhonghua Ni
b)
1Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments,
Southeast University
, Nanjing 211189, China
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Yunfei Chen
Yunfei Chen
b)
1Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments,
Southeast University
, Nanjing 211189, China
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Gutian Zhao
1,a)
Qiyan Tan
1,3,a)
Li Xiang
1
Di Cai
1
Hongbo Zeng
2
Hong Yi
1
Zhonghua Ni
1,b)
Yunfei Chen
1,b)
1Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments,
Southeast University
, Nanjing 211189, China
3School of Mechanical Engineering,
Nanjing Institute of Technology
, Nanjing 211167, China
2Department of Chemical and Materials Engineering,
University of Alberta, Edmonton
, Alberta T6G 2V43, Canada
a)
G. Zhao and Q. Tan contributed equally to this work.
b)
Authors to whom correspondence should be addressed. Electronic addresses: [email protected]. and [email protected].
J. Chem. Phys. 143, 104705 (2015)
Article history
Received:
April 28 2015
Accepted:
August 26 2015
Citation
Gutian Zhao, Qiyan Tan, Li Xiang, Di Cai, Hongbo Zeng, Hong Yi, Zhonghua Ni, Yunfei Chen; Structure and properties of water film adsorbed on mica surfaces. J. Chem. Phys. 14 September 2015; 143 (10): 104705. https://doi.org/10.1063/1.4930274
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