We numerically study different forms of nanoscale gaseous domains on a model for rough surfaces. Our calculations based on the constrained lattice density functional theory show that the inter-connectivity of pores surrounded by neighboring nanoposts, which model the surface roughness, leads to the formation of stable microscopic Cassie states. We investigate the dependence of the stability of the micro-Cassie states on substrate roughness, fluid-solid interaction, and chemical potential and then address the differences between the origin of the micro-Cassie states and that of surface nanobubbles within similar models. Finally, we show that the micro-Cassie states share some features with experimentally observed micropancakes at solid-water interfaces.
Skip Nav Destination
Article navigation
28 June 2015
Research Article|
June 24 2015
Stability of micro-Cassie states on rough substrates
Zhenjiang Guo;
Zhenjiang Guo
1State Key Laboratory of Organic-Inorganic Composites,
Beijing University of Chemical Technology
, Beijing 100029, China
Search for other works by this author on:
Yawei Liu;
Yawei Liu
1State Key Laboratory of Organic-Inorganic Composites,
Beijing University of Chemical Technology
, Beijing 100029, China
Search for other works by this author on:
Detlef Lohse;
Detlef Lohse
2Physics of Fluids group, Department of Science and Technology,
Mesa+ Institute
, and J. M. Burgers Centre for Fluid Dynamics, University of Twente
, P.O. Box 217, 7500 AE Enschede, The Netherlands
Search for other works by this author on:
Xuehua Zhang;
Xuehua Zhang
2Physics of Fluids group, Department of Science and Technology,
Mesa+ Institute
, and J. M. Burgers Centre for Fluid Dynamics, University of Twente
, P.O. Box 217, 7500 AE Enschede, The Netherlands
3School of Civil, Environmental and Chemical Engineering,
RMIT University
, Melbourne, VIC 3001, Australia
Search for other works by this author on:
Xianren Zhang
Xianren Zhang
1State Key Laboratory of Organic-Inorganic Composites,
Beijing University of Chemical Technology
, Beijing 100029, China
Search for other works by this author on:
J. Chem. Phys. 142, 244704 (2015)
Article history
Received:
April 03 2015
Accepted:
June 12 2015
Citation
Zhenjiang Guo, Yawei Liu, Detlef Lohse, Xuehua Zhang, Xianren Zhang; Stability of micro-Cassie states on rough substrates. J. Chem. Phys. 28 June 2015; 142 (24): 244704. https://doi.org/10.1063/1.4922905
Download citation file:
Sign in
Don't already have an account? Register
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Sign in via your Institution
Sign in via your InstitutionPay-Per-View Access
$40.00