We report on measurements of differential cross sections (DCSs) for electron impact excitation of a series of Rydberg electronic-states in α-tetrahydrofurfuryl alcohol (THFA). The energy range of these experiments was 20–50 eV, while the scattered electron was detected in the 10°–90° angular range. There are currently no other experimental data or theoretical computations against which we can directly compare the present measured results. Nonetheless, we are able to compare our THFA DCSs with earlier cross section measurements for Rydberg-state electronic excitation for tetrahydrofuran, a similar cyclic ether, from Do et al. [J. Chem. Phys. 134, 144302 (2011)]. In addition, “rotationally averaged” elastic DCSs, calculated using our independent atom model with screened additivity rule correction approach are also reported. Those latter results give integral cross sections consistent with the optical theorem, and supercede those from the only previous study of Milosavljević et al. [Eur. Phys. J. D 40, 107 (2006)].
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14 July 2014
Research Article|
July 08 2014
Differential cross sections for intermediate-energy electron scattering from α-tetrahydrofurfuryl alcohol: Excitation of electronic-states
L. Chiari;
L. Chiari
1School of Chemical and Physical Sciences,
Flinders University
, GPO Box 2100, Adelaide, SA 5001, Australia
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H. V. Duque;
H. V. Duque
1School of Chemical and Physical Sciences,
Flinders University
, GPO Box 2100, Adelaide, SA 5001, Australia
2Departamento de Física,
Universidade Federal de Juiz de Fora
, Juiz de Fora, MG, Brazil
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D. B. Jones;
D. B. Jones
1School of Chemical and Physical Sciences,
Flinders University
, GPO Box 2100, Adelaide, SA 5001, Australia
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P. A. Thorn;
P. A. Thorn
1School of Chemical and Physical Sciences,
Flinders University
, GPO Box 2100, Adelaide, SA 5001, Australia
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Z. Pettifer;
Z. Pettifer
1School of Chemical and Physical Sciences,
Flinders University
, GPO Box 2100, Adelaide, SA 5001, Australia
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G. B. da Silva;
G. B. da Silva
1School of Chemical and Physical Sciences,
Flinders University
, GPO Box 2100, Adelaide, SA 5001, Australia
3
Universidade Federal de Mato Grosso
, Barra do Garças, Mato Grosso, Brazil
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P. Limão-Vieira;
P. Limão-Vieira
4Laboratório de Colisões Atómicas e Moleculares, CEFITEC, Departamento de Física, Faculdade de Ciências e Tecnologia,
Universidade Nova de Lisboa
, 2829-516 Caparica, Portugal
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D. Duflot;
D. Duflot
5Laboratoire de Physique des Lasers, Atomes et Molécules, UMR CNRS 8523,
Université Lille
, F-59655 Villeneuve d’Ascq Cedex, France
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M.-J. Hubin-Franskin;
M.-J. Hubin-Franskin
6Départment de Chimie,
Université de Liège
, Institut de Chimie-Bât. B6C, B-4000 Liège 1, Belgium
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J. Delwiche;
J. Delwiche
6Départment de Chimie,
Université de Liège
, Institut de Chimie-Bât. B6C, B-4000 Liège 1, Belgium
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F. Blanco;
F. Blanco
7Departamento de Física Atómica, Molecular y Nuclear,
Universidad Complutense de Madrid
, Madrid E-28040, Spain
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G. García;
G. García
8Instituto de Física Fundamental,
CSIC
, Madrid E-28006, Spain
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M. C. A. Lopes;
M. C. A. Lopes
2Departamento de Física,
Universidade Federal de Juiz de Fora
, Juiz de Fora, MG, Brazil
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K. Ratnavelu;
K. Ratnavelu
9Institute of Mathematical Sciences,
University of Malaya
, Kuala Lumpur, Malaysia
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R. D. White;
R. D. White
10School of Engineering and Physical Sciences,
James Cook University
, Townsville, 4810 Queensland, Australia
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M. J. Brunger
M. J. Brunger
a)
1School of Chemical and Physical Sciences,
Flinders University
, GPO Box 2100, Adelaide, SA 5001, Australia
9Institute of Mathematical Sciences,
University of Malaya
, Kuala Lumpur, Malaysia
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L. Chiari
1
H. V. Duque
1,2
D. B. Jones
1
P. A. Thorn
1
Z. Pettifer
1
G. B. da Silva
1,3
P. Limão-Vieira
4
D. Duflot
5
M.-J. Hubin-Franskin
6
J. Delwiche
6
F. Blanco
7
G. García
8
M. C. A. Lopes
2
K. Ratnavelu
9
R. D. White
10
M. J. Brunger
1,9,a)
1School of Chemical and Physical Sciences,
Flinders University
, GPO Box 2100, Adelaide, SA 5001, Australia
2Departamento de Física,
Universidade Federal de Juiz de Fora
, Juiz de Fora, MG, Brazil
3
Universidade Federal de Mato Grosso
, Barra do Garças, Mato Grosso, Brazil
4Laboratório de Colisões Atómicas e Moleculares, CEFITEC, Departamento de Física, Faculdade de Ciências e Tecnologia,
Universidade Nova de Lisboa
, 2829-516 Caparica, Portugal
5Laboratoire de Physique des Lasers, Atomes et Molécules, UMR CNRS 8523,
Université Lille
, F-59655 Villeneuve d’Ascq Cedex, France
6Départment de Chimie,
Université de Liège
, Institut de Chimie-Bât. B6C, B-4000 Liège 1, Belgium
7Departamento de Física Atómica, Molecular y Nuclear,
Universidad Complutense de Madrid
, Madrid E-28040, Spain
8Instituto de Física Fundamental,
CSIC
, Madrid E-28006, Spain
9Institute of Mathematical Sciences,
University of Malaya
, Kuala Lumpur, Malaysia
10School of Engineering and Physical Sciences,
James Cook University
, Townsville, 4810 Queensland, Australia
a)
Electronic mail: [email protected]
J. Chem. Phys. 141, 024301 (2014)
Article history
Received:
May 11 2014
Accepted:
June 18 2014
Citation
L. Chiari, H. V. Duque, D. B. Jones, P. A. Thorn, Z. Pettifer, G. B. da Silva, P. Limão-Vieira, D. Duflot, M.-J. Hubin-Franskin, J. Delwiche, F. Blanco, G. García, M. C. A. Lopes, K. Ratnavelu, R. D. White, M. J. Brunger; Differential cross sections for intermediate-energy electron scattering from α-tetrahydrofurfuryl alcohol: Excitation of electronic-states. J. Chem. Phys. 14 July 2014; 141 (2): 024301. https://doi.org/10.1063/1.4885856
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