Recently, results for the CO2 R(12) line strength parameter have been reported, which differ significantly and are inconsistent with respect to quoted uncertainties. We investigate to what extent this inconsistency might be caused by the chosen data analysis methods. To this end, we assess and compare a parametric fitting procedure and a non-parametric approach. We apply the methods to simulated and measured line spectra, and we specify the conditions required for the safe application of the two procedures. For our present data, the corresponding conditions are satisfied for both methods, and consistent results are obtained. However, the simulations reveal that the fitting procedure can show shortcomings when the uncertainty in the wavenumber is large.
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28 November 2011
Research Article|
November 28 2011
Comparison and assessment of procedures for calculating the R(12) line strength of the ν1+ 2 ν2 + ν3 band of CO2
Gerd Wübbeler;
Gerd Wübbeler
a)
1
Physikalisch-Technische Bundesanstalt
, Abbestr. 2-12, D-10587 Berlin, Germany
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Gerardo J. Padilla Víquez;
Gerardo J. Padilla Víquez
1
Physikalisch-Technische Bundesanstalt
, Abbestr. 2-12, D-10587 Berlin, Germany
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Karl Jousten;
Karl Jousten
1
Physikalisch-Technische Bundesanstalt
, Abbestr. 2-12, D-10587 Berlin, Germany
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Olav Werhahn;
Olav Werhahn
2
Physikalisch-Technische Bundesanstalt
, Bundesallee 100, D-38116 Braunschweig, Germany
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Clemens Elster
Clemens Elster
1
Physikalisch-Technische Bundesanstalt
, Abbestr. 2-12, D-10587 Berlin, Germany
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Gerd Wübbeler
1,a)
Gerardo J. Padilla Víquez
1
Karl Jousten
1
Olav Werhahn
2
Clemens Elster
1
1
Physikalisch-Technische Bundesanstalt
, Abbestr. 2-12, D-10587 Berlin, Germany
2
Physikalisch-Technische Bundesanstalt
, Bundesallee 100, D-38116 Braunschweig, Germany
a)
Author to whom correspondence should be addressed. Electronic mail: [email protected].
J. Chem. Phys. 135, 204304 (2011)
Article history
Received:
March 01 2011
Accepted:
October 27 2011
Citation
Gerd Wübbeler, Gerardo J. Padilla Víquez, Karl Jousten, Olav Werhahn, Clemens Elster; Comparison and assessment of procedures for calculating the R(12) line strength of the ν1+ 2 ν2 + ν3 band of CO2. J. Chem. Phys. 28 November 2011; 135 (20): 204304. https://doi.org/10.1063/1.3662134
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