We demonstrate theoretically that laser-induced coherent quantum interference control of asymptotic states of dissociating molecules is possible – even in the (one-photon) weak-field limit starting from a single vibrational eigenstate – when resonances are in play. This is illustrated for the NaI molecule, where it is shown that the probability of observing atomic fragments as well as the distribution of their relative momenta can be changed by a phase modulated pulse with a fixed bandwidth. This type of control is restricted to finite times during the indirect fragmentation.
REFERENCES
1.
S. A.
Rice
and M.
Zhao
, Optical Control of Molecular Dynamics
(Wiley
, New York
, 2000
).2.
M.
Shapiro
and P.
Brumer
, Principles of Quantum Control of Molecular Processes
(Wiley
, New York
, 2003
).3.
C.
Brif
, R.
Chakrabarti
, and H.
Rabitz
, New J. Phys.
12
, 075008
(2010
).4.
N. E.
Henriksen
and F. Y.
Hansen
, Theories of Molecular Reaction Dynamics
(Oxford University Press
, Oxford
, 2008
).5.
A.
Assion
, T.
Baumert
, M.
Bergt
, T.
Brixner
, B.
Kiefer
, V.
Seyfried
, M.
Strehle
, and G.
Gerber
, Science
282
, 919
(1998
).6.
T. C.
Weinacht
, J.
Ahn
, and P. H.
Bucksbaum
, Nature
397
, 233
(1999
).7.
T.
Brixner
, N. H.
Damrauer
, P.
Niklaus
, and G.
Gerber
, Nature
414
, 57
(2001
).8.
R. J.
Levis
, G. M.
Mekir
, and H.
Rabitz
, Science
292
, 709
(2001
).9.
G.
Vogt
, G.
Krampert
, P.
Niklaus
, P.
Nuernberger
, and G.
Gerber
, Phys. Rev. Lett.
94
, 068305
(2005
).10.
P.
Brumer
and M.
Shapiro
, Chem. Phys. Lett.
126
, 541
(1986
).11.
P.
Brumer
and M.
Shapiro
, Chem. Phys.
139
, 221
(1989
).12.
M.
Shapiro
and P.
Brumer
, J. Phys. Chem. A
105
, 2897
(2001
).13.
N. E.
Henriksen
, Adv. Chem. Phys.
91
, 433
(1995
).14.
J. L.
Krause
, R. M.
Whitnell
, K. R.
Wilson
, Y.-J.
Yan
, and S.
Mukamel
, J. Chem. Phys.
99
, 6562
(1993
).15.
A. K.
Tiwari
, K. B.
Møller
, and N. E.
Henriksen
, Chem. Phys. Lett.
450
, 6
(2007
).16.
D. J.
Tannor
and S. A.
Rice
, J. Chem. Phys.
83
, 5013
(1985
).17.
A. K.
Tiwari
, K. B.
Møller
, and N. E.
Henriksen
, Phys. Rev. A
78
, 065402
(2008
).18.
V. I.
Prokhorenko
, A. M.
Nagy
, L. S.
Brown
, and R. J.
Dwayne Miller
, Chem. Phys.
341
, 296
(2007
).19.
G.
Katz
, M. A.
Ratner
, and R.
Kosloff
, New J. Phys.
12
, 015003
(2010
).20.
N. E.
Henriksen
and K. B.
Møller
, J. Chem. Phys.
119
, 2569
(2003
).21.
N. E.
Henriksen
, J. Chem. Phys.
132
, 234311
(2010
).22.
R.
Schinke
, Photodissociation Dynamics
(Cambridge University Press
, Cambridge
, 1993
).23.
V.
Engel
and H.
Metiu
, J. Chem. Phys.
92
, 2317
(1990
).24.
C.
Meier
, V.
Engel
, and J. S.
Briggs
, J. Chem. Phys.
95
, 7337
(1991
).25.
K. B.
Møller
, N. E.
Henriksen
, and A. H.
Zewail
, J. Chem. Phys.
113
, 10477
(2000
).26.
M.
Bixon
and J.
Jortner
, J. Chem. Phys.
107
, 1470
(1997
).27.
H.
Tang
and S. A.
Rice
, J. Phys. Chem. A
101
, 9587
(1997
).28.
K.
Hoki
, Y.
Ohtsuki
, H.
Kono
, and Y.
Fujimura
, J. Phys. Chem. A
103
, 6301
(1999
).29.
K.
Nakagami
, Y.
Ohtsuki
, and Y.
Fujimura
, J. Chem. Phys.
117
, 6429
(2002
).30.
K.
Mishima
and K.
Yamashita
, J. Chem. Phys.
109
, 1801
(1998
).31.
T. S.
Rose
, M. J.
Rosker
, and A. H.
Zewail
, J. Chem. Phys.
91
, 7415
(1989
).32.
A.
Monmayrant
, S.
Weber
, and B.
Chatel
, J. Phys. B
43
, 103001
(2010
).33.
C. C.
Marston
and G. G.
Balint-Kurti
, J. Chem. Phys.
91
, 3571
(1989
).34.
R.
Kosloff
, J. Phys. Chem.
92
, 2087
(1988
).35.
J.
Degert
, C.
Meier
, B.
Girard
, and M. J. J.
Vrakking
, Eur. Phys. J. D
14
, 257
(2001
).36.
C.-C.
Shu
, J.
Yu
, K.-J.
Yuan
, W.-H.
Hu
, J.
Yang
, and S.-L.
Cong
, Phys. Rev. A
79
, 023418
(2009
).37.
Y.-C.
Han
, K.-J.
Yuan
, W.-H.
Hu
, and S.-L.
Cong
, J. Chem. Phys.
130
, 044308
(2009
).38.
A. V.
Baklanov
, L. M. C.
Janssen
, D. H.
Parker
, L.
Poisson
, B.
Soep
, J. M.
Mestdagh
, and O.
Gobert
, J. Chem. Phys.
129
, 214306
(2008
).39.
S.
Chapman
and M. S.
Child
, J. Phys. Chem.
95
, 578
(1991
).40.
P. S.
Christopher
, M.
Shapiro
, and P.
Brumer
, J. Chem. Phys.
123
, 064313
(2005
).© 2011 American Institute of Physics.
2011
American Institute of Physics
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