We report a detailed numerical investigation of the relative abundance of periodic and chaotic oscillations in phase diagrams for the Belousov–Zhabotinsky (BZ) reaction as described by a nonpolynomial, autonomous, three-variable model suggested by Györgyi and Field [Nature (London)355, 808 (1992)]. The model contains 14 parameters that may be tuned to produce rich dynamical scenarios. By computing the Lyapunov spectra, we find the structuring of periodic and chaotic phases of the BZ reaction to display unusual global patterns, very distinct from those recently found for gas and semiconductor lasers, for electric circuits, and for a few other familiar nonlinear oscillators. The unusual patterns found for the BZ reaction are surprisingly robust and independent of the parameter explored.

1.
R. J.
Field
and
L.
Györgyi
,
Chaos in Chemistry and Biochemistry
(
World Scientific
,
Singapore
,
1993
).
2.
I. R.
Epstein
and
J. A.
Pojman
,
An Introduction to Nonlinear Chemical Dynamics: Oscillations, Waves, Patterns, and Chaos
(
Oxford University Press
,
New York
,
1998
).
3.
P.
Gray
and
S. K.
Scott
,
Chemical Oscillations and Instabilities
(
Oxford Science
,
New York
,
1990
).
4.
S. K.
Scott
,
Chemical Chaos
(
Oxford Science
,
New York
,
1991
).
5.
C.
Bonatto
,
J. C.
Garreau
, and
J. A. C.
Gallas
,
Phys. Rev. Lett.
95
,
143905
(
2005
).
6.
C.
Bonatto
and
J. A.C.
Gallas
,
Phys. Rev. E
75
,
055204
(R) (
2007
).
7.
Y.
Zou
,
M.
Thiel
,
M. C.
Romano
,
J.
Kurths
, and
Q.
Bi
,
Int. J. Bifurcation Chaos Appl. Sci. Eng.
16
,
3567
(
2006
).
8.
V.
Castro
,
M.
Monti
,
W. B.
Pardo
,
J. A.
Walkenstein
, and
E.
Rosa
,
Int. J. Bifurcation Chaos Appl. Sci. Eng.
17
,
965
(
2007
).
9.
H. A.
Albuquerque
,
R. M.
Rubinger
, and
P. C.
Rech
,
Phys. Lett. A
372
,
4793
(
2008
).
10.
G. M.
Ramírez-Ávila
and
J. A. C.
Gallas
,
Revista Boliviana de Fisica
14
,
1
(
2008
).
11.
G. M.
Ramírez-Ávila
and
J. A.C.
Gallas
, “
Quantification of regular and chaotic oscillations of Chua’s circuit
,”
IEEE Trans. Circuits-I
(submitted).
12.
C.
Bonatto
and
J. A. C.
Gallas
,
Phys. Rev. Lett.
101
,
054101
(
2008
).
13.
J. G.
Freire
,
C.
Bonatto
,
C.
DaCamara
, and
J. A. C.
Gallas
,
Chaos
18
,
033121
(
2008
).
14.
C.
Bonatto
,
J. A.C.
Gallas
, and
Y.
Ueda
,
Phys. Rev. E
77
,
026217
(
2008
).
15.
C.
Bonatto
and
J. A.C.
Gallas
,
Philos. Trans. R. Soc. London, Ser. A
366
,
505
(
2008
).
16.
J. A. C.
Gallas
, “
Infinite networks of periodicity hubs in phase diagrams of simple autonomous flows
,”
Int. J. Bifurcation Chaos Appl. Sci. Eng.
(to be published).
17.
J. A. C.
Gallas
,
Phys. Rev. Lett.
70
,
2714
(
1993
);
[PubMed]
J. A. C.
Gallas
,
Appl. Phys. B: Lasers Opt.
60
,
S203
(
1995
);
B. R.
Hunt
,
J. A. C.
Gallas
,
C.
Grebogi
,
J. A.
Yorke
, and
H.
Koçak
,
Physica D
129
,
35
(
1999
).
18.
19.
A phase diagram including the inner structuring of chaotic phases for a nonautonomous chemical flow was reported in Ref. 15.
20.
L.
Györgyi
and
R. J.
Field
,
Nature (London)
355
,
808
(
1992
).
21.
A. P.
Nazarea
and
S. A.
Rice
,
Proc. Natl. Acad. Sci. U.S.A.
68
,
2502
(
1971
).
22.
B. P.
Belousov
, in
Oscillations and Traveling Waves in Chemical Systems
, edited by
R. J.
Field
and
M.
Burger
(
Wiley
,
New York
,
1985
).
23.
A. M.
Zhabotinsky
,
Scholarpedia J.
2
,
1435
(
2007
).
24.
R. J.
Field
,
E.
Kőrös
, and
R. M.
Noyes
,
J. Am. Chem. Soc.
94
,
8649
(
1972
).
25.
R. A.
Schmitz
,
K. R.
Graziani
, and
J. L.
Hudson
,
J. Chem. Phys.
67
,
3040
(
1977
).
26.
J. L.
Hudson
and
J. C.
Mankin
,
J. Chem. Phys.
74
,
6171
(
1981
).
27.
J. S.
Turner
,
J. -C.
Roux
,
W. D.
McCormick
, and
H. L.
Swinney
,
Phys. Lett. A
85
,
9
(
1981
).
28.
C.
Vidal
,
S.
Bachelart
, and
A.
Rossi
,
J. Phys. (Paris)
43
,
7
(
1982
).
30.
L.
Györgyi
,
R. J.
Field
,
Z.
Noszticzius
,
W. D.
McCormick
, and
H. L.
Swinney
,
J. Phys. Chem.
96
,
1228
(
1992
).
31.
L.
Györgyi
,
S.
Rempe
, and
R. J.
Field
,
J. Phys. Chem.
95
,
3159
(
1991
).
32.
I. R.
Epstein
,
Nature (London)
346
,
16
(
1990
).
33.
I. R.
Epstein
,
Nature (London)
374
,
321
(
1995
).
34.
F. W.
Schneider
and
A. F.
Münster
,
J. Phys. Chem.
95
,
2130
(
1991
).
35.
L.
Györgyi
and
R. J.
Field
,
J. Phys. Chem.
92
,
7079
(
1988
).
36.
R. J.
Field
and
R. M.
Noyes
,
J. Chem. Phys.
60
,
1877
(
1974
).
37.
R. J.
Field
,
Scholarpedia J.
2
,
1386
(
2007
).
38.
L.
Györgyi
and
R. J.
Field
,
J. Phys. Chem.
95
,
6594
(
1991
).
39.
R. J.
Field
,
Scholarpedia J.
3
,
4051
(
2008
).
40.
T.
Tél
and
M.
Gruiz
,
Chaotic Dynamics: An Introduction Based on Classical Mechanics
(
Cambridge University Press
,
Cambridge
,
2006
).
41.
J. H. E.
Cartwright
,
Phys. Lett. A
264
,
298
(
1999
).
42.
You do not currently have access to this content.