Photoelectron spectra of and of the anion produced by the dissociative adsorption of a water molecule by are interpreted with density-functional geometry optimizations and electron-propagator calculations of vertical electron detachment energies. For , , and , the observed signals may be attributed to the most stable isomer of each anion. For , the features in the photoelectron spectrum are due to three almost isoenergetic isomers.
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Research Article| December 18 2007
Electron binding energies and Dyson orbitals of and
Alfredo Guevara-García, Ana Martínez, J. V. Ortiz; Electron binding energies and Dyson orbitals of and . J. Chem. Phys. 21 December 2007; 127 (23): 234302. https://doi.org/10.1063/1.2806845
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