Metal clusters embedded in ultracold helium nanodroplets are exposed to femtosecond laser pulses with intensities of 10131014Wcm2. The influence of the matrix on the ionization and fragmentation dynamics is studied by pump-probe time-of-flight mass spectrometry. Special attention is paid to the generation of helium snowballs around positive metal ions (Mez+HeN, z=1,2). Closings of the first and second helium shells are found for silver at N1=10,12 and N2=32,44, as well as for magnesium at N1=1920. The distinct abundance enhancement of helium snowballs in the presence of isolated atoms and small clusters in the droplets is used as a diagnostics to explore the cage effect. For silver, a reaggregation of the clusters is observed at 30ps after femtosecond laser excitation.

1.
T.
Döppner
,
Th.
Fennel
,
Th.
Diederich
,
J.
Tiggesbäumker
, and
K.-H.
Meiwes-Broer
,
Phys. Rev. Lett.
94
,
013401
(
2005
).
2.
Q.
Liu
,
J.-K.
Wang
, and
A.
Zewail
,
Nature (London)
364
,
427
(
1993
).
3.
B.
Greenblatt
,
M.
Zanni
, and
D.
Neumark
,
Science
276
,
1675
(
1997
).
4.
V.
Vorsa
,
S.
Nandi
,
P.
Campagnola
,
M.
Larsson
, and
W.
Lineberger
,
J. Chem. Phys.
106
,
1402
(
1997
).
5.
A.
Braun
and
M.
Drabbels
,
Phys. Rev. Lett.
93
,
253401
(
2004
).
6.
J. Chem. Phys.
115
(
2001
), special issue on He droplets.
7.
J. P.
Toennies
and
A. F.
Vilesov
,
Angew. Chem., Int. Ed.
43
,
2622
(
2004
).
8.
M.
Barranco
,
R.
Guardiola
,
S.
Hernandez
,
R.
Mayol
,
J.
Navarro
, and
M.
Pi
,
J. Low Temp. Phys.
142
,
1
(
2006
).
9.
J.
Tiggesbäumker
and
F.
Stienkemeier
,
Phys. Chem. Chem. Phys.
(accepted).
10.
M.
Hartmann
,
R.
Miller
,
J. P.
Toennies
, and
A. F.
Vilesov
,
Phys. Rev. Lett.
75
,
1566
(
1995
).
11.
S.
Goyal
,
D.
Schutt
, and
G.
Scoles
,
Phys. Rev. Lett.
69
,
933
(
1992
).
12.
M.
Lewerenz
,
B.
Schilling
, and
J. P.
Toennies
,
J. Chem. Phys.
102
,
8191
(
1995
).
13.
J.
Higgins
,
C.
Callegari
,
J.
Reho
,
F.
Stienkemeier
,
W. E.
Ernst
,
M.
Gutowski
, and
G.
Scoles
,
J. Phys. Chem. A
102
,
4952
(
1998
).
14.
A.
Przystawik
,
P.
Radcliffe
,
S.
Göde
,
K.-H.
Meiwes-Broer
, and
J.
Tiggesbäumker
,
J. Phys. B
39
,
S1183
(
2006
).
15.
K.
Nauta
and
R. E.
Miller
,
Science
283
,
1895
(
1999
).
16.
J.
Higgins
,
C.
Callegari
,
J.
Reho
,
F.
Stienkemeier
,
W. E.
Ernst
,
K. K.
Lehmann
,
M.
Gutowski
, and
G.
Scoles
,
Science
273
,
629
(
1996
).
17.
F.
Federmann
,
K.
Hoffmann
,
N.
Quaas
, and
J. P.
Toennies
,
Eur. Phys. J. D
9
,
11
(
1999
).
18.
Th.
Diederich
,
J.
Tiggesbäumker
, and
K.-H.
Meiwes-Broer
,
J. Chem. Phys.
116
,
3263
(
2002
).
19.
Th.
Diederich
,
T.
Döppner
,
Th.
Fennel
,
J.
Tiggesbäumker
, and
K.-H.
Meiwes-Broer
,
Phys. Rev. A
72
,
023203
(
2005
).
20.
P.
Radcliffe
,
A.
Przystawik
,
Th.
Diederich
,
T.
Döppner
,
J.
Tiggesbäumker
, and
K.-H.
Meiwes-Broer
,
Phys. Rev. Lett.
92
,
173403
(
2004
).
21.
J.
Jortner
,
N.
Kestner
,
S.
Rice
, and
M.
Cohen
,
J. Chem. Phys.
43
,
2614
(
1965
).
22.
23.
K. W.
Schwarz
,
Adv. Chem. Phys.
33
,
1
(
1975
).
24.
W.
Glaberson
and
W.
Johnson
,
J. Low Temp. Phys.
20
,
313
(
1975
).
25.
H.
Skullerud
,
M.
Elford
, and
I.
Røeggen
,
J. Phys. B
29
,
1925
(
1996
).
26.
M.
Foerste
,
H.
Guenther
,
O.
Riediger
,
J.
Wiebe
, and
G.
zu Putlitz
,
Z. Phys. B: Condens. Matter
104
,
317
(
1997
).
27.
S. A.
Chin
and
E.
Krotscheck
,
Phys. Rev. B
45
,
852
(
1992
).
28.
M.
Mella
,
M.
Colombo
, and
G.
Morosi
,
J. Chem. Phys.
117
,
9695
(
2002
).
29.
D.
Ceperley
,
Rev. Mod. Phys.
67
,
279
(
1995
).
30.
Y.
Kwon
and
K.
Whaley
,
Phys. Rev. Lett.
83
,
4108
(
1999
).
31.
A.
Nakayama
and
K.
Yamashita
,
J. Chem. Phys.
112
,
10966
(
2000
).
32.
M.
Rossi
,
M.
Verona
,
D.
Galli
, and
L.
Reatto
,
Phys. Rev. B
69
,
212510
(
2004
).
33.
F.
Dalfovo
,
Z. Phys. D: At., Mol. Clusters
29
,
61
(
1994
).
34.
S.
Gatica
,
E.
Hernandez
, and
M.
Barranco
,
J. Chem. Phys.
107
,
927
(
1997
).
35.
A. M.
Sapse
,
A.
Dumitra
, and
D. C.
Jain
,
J. Cluster Sci.
14
,
21
(
2003
).
36.
X.
Bu
and
C.
Zhong
,
J. Mol. Struct.: THEOCHEM
726
,
99
(
2005
).
37.
E.
Bodo
,
E.
Yurtsever
,
M.
Yurtsever
, and
F.
Gianturco
,
J. Chem. Phys.
124
,
074320
(
2006
).
38.
Th.
Diederich
,
T.
Döppner
,
J.
Braune
,
J.
Tiggesbäumker
, and
K.-H.
Meiwes-Broer
,
Phys. Rev. Lett.
86
,
4807
(
2001
).
39.
A.
Bartelt
,
J.
Close
,
F.
Federmann
,
N.
Quaas
, and
J. P.
Toennies
,
Phys. Rev. Lett.
77
,
3525
(
1996
).
40.
T.
Döppner
,
Th.
Diederich
,
J.
Tiggesbäumker
, and
K.-H.
Meiwes-Broer
,
Eur. Phys. J. D
16
,
13
(
2001
).
41.
T.
Döppner
,
Th.
Diederich
,
A.
Przystawik
,
Th.
Fennel
,
J.
Tiggesbäumker
, and
K.-H.
Meiwes-Broer
,
Phys. Chem. Chem. Phys.
(accepted).
42.
M.
Buzzacchi
,
D.
Galli
, and
L.
Reatto
,
Phys. Rev. B
64
,
094512
(
2001
).
43.
P.
Claas
,
C.
Schulz
, and
F.
Stienkemeier
(unpublished).
44.
X.
Bu
and
C.
Zhong
,
Chem. Phys. Lett.
392
,
181
(
2004
).
45.
S.
Augst
,
D.
Strickland
,
D. D.
Meyerhofer
,
S. L.
Chin
, and
J. H.
Eberly
,
Phys. Rev. Lett.
63
,
2212
(
1989
).
You do not currently have access to this content.