The effect of delocalization on the exchange energy in meta- and para-linked Pt-containing carbazole polymers and monomers Available to Purchase

A series of novel platinum-containing carbazole monomers and polymers was synthesized and fully characterized by UV-VIS absorption, luminescence, and photoinduced absorption studies. In these compounds, a carbazole unit is incorporated into the main chain via either a para- or a meta-linkage. We discuss the effects of linkage and polymerization on the energy levels of $S1$⁠, $T1$⁠, and $Tn$⁠. The $S1-T1$ splitting observed for the meta-linked monomer $(0.4eV)$ is only half of that in the para-linked monomer $(0.8eV)$⁠. Upon polymerization, the exchange energy in the para-linked compound reduces, yet still remains larger than in the meta-linked polymer. We attribute the difference in exchange energy to the difference in wave function overlap between electron and hole in these compounds.