A quantum-classical bracket is proposed and is shown to satisfy the Jacobi identity, in contrast to previous definitions that obey this property only up to higher order terms in the Planck constant . The Jacobi identity is required of a true Lie bracket and ensures that the Lie bracket of constants of motion is also a constant of motion. An explicit calculation of the Jacobi identity highlights the difference between the proposed and traditional definitions. A further example illustrates that the proposed bracket generates a more consistent quantum-classical dynamics than the traditional bracket. The traditional quantum-classical dynamics in the Henon-Heiles system diverges due to higher order terms. The divergence is eliminated with the proposed bracket.
Skip Nav Destination
Article navigation
28 May 2006
Rapid Communication|
May 22 2006
A quantum-classical bracket that satisfies the Jacobi identity
Oleg V. Prezhdo
Oleg V. Prezhdo
Department of Chemistry,
University of Washington
, Seattle, Washington 98195-1700
Search for other works by this author on:
J. Chem. Phys. 124, 201104 (2006)
Article history
Received:
March 03 2006
Accepted:
April 05 2006
Connected Content
A related article has been published:
Comment on “A quantum-classical bracket that satisfies the Jacobi identity” [J. Chem. Phys. 124, 201104 (2006)]
Citation
Oleg V. Prezhdo; A quantum-classical bracket that satisfies the Jacobi identity. J. Chem. Phys. 28 May 2006; 124 (20): 201104. https://doi.org/10.1063/1.2200342
Download citation file:
Pay-Per-View Access
$40.00
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Citing articles via
DeePMD-kit v2: A software package for deep potential models
Jinzhe Zeng, Duo Zhang, et al.
CREST—A program for the exploration of low-energy molecular chemical space
Philipp Pracht, Stefan Grimme, et al.
Related Content
Short proof of Jacobi’s identity for Poisson brackets
American Journal of Physics (January 2000)
Classical Nambu brackets in higher dimensions
J. Math. Phys. (May 2023)
Gyrokinetic energy conservation and Poisson‐bracket formulation
Phys. Fluids B (July 1989)
Vlasov moment flows and geodesics on the Jacobi group
J. Math. Phys. (November 2012)