A simple model of harmonic vibrations in topologically disordered systems, such as glasses and supercooled liquids, is studied analytically by extending Euclidean random matrix theory to include vector vibrations. Rather generally, it is found that (i) the dynamic structure factor shows soundlike Brillouin peaks whose longitudinal/transverse character can only be distinguished for small transferred momentum, p; (ii) the model presents a mechanical instability transition at small densities, for which scaling laws are analytically predicted and confirmed numerically; (iii) the Brillouin peaks persist deep into the unstable phase, the phase transition being noticeable mostly in their linewidth; (iv) the Brillouin linewidth scales like in the stable phase, and like p in the unstable one. The analytical results are checked numerically for a simple potential. The main features of glassy vibrations previously deduced from scalar are not substantially altered by these new results.
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22 October 2003
Research Article|
October 22 2003
Brillouin and boson peaks in glasses from vector Euclidean random matrix theory
S. Ciliberti;
S. Ciliberti
Dipartimento di Fisica, Universitá di Roma “La Sapienza,” INFM unità di Roma I
Center for Statistical Mechanics and Complexity (SMC), P.le A. Moro 2, I-00185 Roma, Italy
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T. S. Grigera;
T. S. Grigera
Centro di Studi e Ricerche “Enrico Fermi,” via Panisperna 89/A, I-00184 Roma, Italy
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V. Martı́n-Mayor;
V. Martı́n-Mayor
Departamento de Fisica Teorica I, Universidad Complutense de Madrid, Madrid 28040, Spain
Instituto de Biocomputación y Fı́sica de Sistemas Complejos (BIFI). Universidad de Zaragoza, 50009 Zaragoza, Spain
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G. Parisi;
G. Parisi
Dipartimento di Fisica, Universitá di Roma “La Sapienza,” INFM unità di Roma I, and Center for Statistical Mechanics and Complexity (SMC), P.le A. Moro 2, I-00185 Roma, Italy
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P. Verrocchio
P. Verrocchio
Departamento de Fisica Teorica I, Universidad Complutense de Madrid, Madrid 28040, Spain
Instituto de Biocomputación y Fı́sica de Sistemas Complejos (BIFI). Universidad de Zaragoza, 50009 Zaragoza, Spain
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J. Chem. Phys. 119, 8577–8591 (2003)
Article history
Received:
May 27 2003
Accepted:
July 24 2003
Citation
S. Ciliberti, T. S. Grigera, V. Martı́n-Mayor, G. Parisi, P. Verrocchio; Brillouin and boson peaks in glasses from vector Euclidean random matrix theory. J. Chem. Phys. 22 October 2003; 119 (16): 8577–8591. https://doi.org/10.1063/1.1610439
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