The curvature dependence of the surface tension of one-component droplets and bubbles is determined approximately. In the scope of the approximation used, it is found that for both droplets and bubbles of any size the surface tension diminishes monotonically with decreasing the radius of the surface of tension.

1.
J. W. Gibbs, The Collected Works. Vol. 1. Thermodynamics (Yale University Press, New Haven, 1957).
2.
R. C.
Tolman
,
J. Chem. Phys.
17
,
333
(
1949
).
3.
S. Ono and S. Kondo, in Handbuch der Physik, Vol. 10, edited by S. Flügge (Springer, Berlin, 1960), p. 134.
4.
E. A. Guggenheim, Thermodynamics (North-Holland, Amsterdam, 1967).
5.
A. I. Rusanov, Fazovye Ravnovesiya i Poverkhnostnye Yavleniya (Khimiya, Leningrad, 1967).
6.
A. I. Rusanov, Phasengleichgewichte und Grenzflächenerscheidungen (Akademie-Verlag, Berlin, 1978).
7.
J. S. Rowlinson and B. Widom, Molecular Theory of Capillarity (Clarendon, Oxford, 1982).
8.
F. F. Abraham, Homogeneous Nucleation Theory (Academic, New York, 1974).
9.
D. Kashchiev, Nucleation: Basic Theory with Applications (Butterworth-Heinemann, Oxford, 2000).
10.
D.
Kashchiev
,
J. Chem. Phys.
118
,
1837
(
2003
).
11.
J. W. P.
Schmelzer
,
J.
Schmelzer
, Jr.
, and
I.
Gutzow
,
J. Chem. Phys.
112
,
3820
(
2000
).
12.
S.
Kondo
,
J. Chem. Phys.
25
,
662
(
1956
).
13.
L. S.
Bartell
,
J. Phys. Chem. B
105
,
11615
(
2001
).
14.
V.
Talanquer
,
J. Chem. Phys.
106
,
9957
(
1997
).
15.
P. R.
ten Wolde
and
D.
Frenkel
,
J. Chem. Phys.
109
,
9901
(
1998
).
16.
A.
Laaksonen
and
R.
McGraw
,
Europhys. Lett.
35
,
367
(
1996
).
17.
K.
Nishioka
,
Metall. Trans. A
23A
,
1869
(
1992
).
18.
I.
Hadjiagapiou
,
J. Phys.: Condens. Matter
6
,
5303
(
1994
).
19.
I.
Kusaka
,
J. Chem. Phys.
118
,
5510
(
2003
).
This content is only available via PDF.
You do not currently have access to this content.