The curvature dependence of the surface tension of one-component droplets and bubbles is determined approximately. In the scope of the approximation used, it is found that for both droplets and bubbles of any size the surface tension diminishes monotonically with decreasing the radius of the surface of tension.
REFERENCES
1.
J. W. Gibbs, The Collected Works. Vol. 1. Thermodynamics (Yale University Press, New Haven, 1957).
2.
3.
S. Ono and S. Kondo, in Handbuch der Physik, Vol. 10, edited by S. Flügge (Springer, Berlin, 1960), p. 134.
4.
E. A. Guggenheim, Thermodynamics (North-Holland, Amsterdam, 1967).
5.
A. I. Rusanov, Fazovye Ravnovesiya i Poverkhnostnye Yavleniya (Khimiya, Leningrad, 1967).
6.
A. I. Rusanov, Phasengleichgewichte und Grenzflächenerscheidungen (Akademie-Verlag, Berlin, 1978).
7.
J. S. Rowlinson and B. Widom, Molecular Theory of Capillarity (Clarendon, Oxford, 1982).
8.
F. F. Abraham, Homogeneous Nucleation Theory (Academic, New York, 1974).
9.
D. Kashchiev, Nucleation: Basic Theory with Applications (Butterworth-Heinemann, Oxford, 2000).
10.
11.
J. W. P.
Schmelzer
, J.
Schmelzer
, Jr., and I.
Gutzow
, J. Chem. Phys.
112
, 3820
(2000
).12.
13.
14.
15.
16.
17.
18.
19.
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© 2003 American Institute of Physics.
2003
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