Outer- and inner-valence ionization spectra of group V hydrides, and were studied by the symmetry-adapted-cluster configuration-interaction (SAC-CI) general-R method. Fine details of the experimental spectra of these hydrides were reproduced and the quantitative assignments of the peaks were proposed. The inner-valence satellites were classified into those including the valence or Rydberg excitations. For we interpreted the spectrum using the relative intensity and proposed some unresolved bands. For bands 2 and 3, for which different assignments have been proposed, were attributed to the inner-valence satellites. A detailed inner-valence satellite spectrum of is theoretically proposed.
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