We present an iterative path integral algorithm for computing multitime correlation functions of a quantum system coupled to a dissipative bath of harmonic oscillators. By splitting the Boltzmann operator into two parts and reordering the propagators in the expression for canonical correlation functions, we are able to transform the evolution time contour into a symmetric one so that a forward propagation and a backward one are specified. Because the memory induced by the bath through the Feynman–Vernon influence functional decays rapidly in the complex time plane, long-time correlations are negligible. Taking advantage of this fact, we show that the correlation function can be obtained via an iterative procedure. The method is used to calculate three-time correlation functions of a dissipative two-level system.
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8 January 2002
Research Article|
January 08 2002
Iterative path integral formulation of equilibrium correlation functions for quantum dissipative systems
Jiushu Shao;
Jiushu Shao
Department of Chemistry, University of Illinois, Urbana, Illinois 61801
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Nancy Makri
Nancy Makri
Departments of Chemistry and Physics, University of Illinois, Urbana, Illinois 61801
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J. Chem. Phys. 116, 507–514 (2002)
Article history
Received:
September 19 2001
Accepted:
October 10 2001
Citation
Jiushu Shao, Nancy Makri; Iterative path integral formulation of equilibrium correlation functions for quantum dissipative systems. J. Chem. Phys. 8 January 2002; 116 (2): 507–514. https://doi.org/10.1063/1.1423936
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