New long path length, high resolution, Fourier transform spectrometer measurements for water are presented. These spectra cover the near infrared, visible, and near ultraviolet regions and contain water transitions belonging to all polyads from 3 to 8 Transitions in the range 13 100–21 400 cm−1 are analyzed using line lists computed using variational first-principles calculations. 2286 new transitions are assigned to These result in the observation of transitions in 15 new overtone and combination bands of water. Energy levels for these and other newly observed levels are presented. It is suggested that local mode rather than normal mode vibrational assignments are more appropriate for the vibrational states of water in polyads 4 and above.
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8 August 1999
Research Article|
August 08 1999
The near infrared, visible, and near ultraviolet overtone spectrum of water
M. Carleer;
M. Carleer
Université Libre de Bruxelles, Service de Chimie Physique Moléculaire, CP 160/09, Av. F.D. Roosevelt 50, B-1050 Brussels, Belgium
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A. Jenouvrier;
A. Jenouvrier
Spectrométrie Moléculaire et Atmosphérique, UFR Sciences, Moulin de la Housse, B.P. 1039, 51687 Reims Cedex 2, France
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A.-C. Vandaele;
A.-C. Vandaele
Institut d’Aeronomie Spatiale de Belgique, Av. Circulaire 3, B-1180 Brussels, Belgium
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P. F. Bernath;
P. F. Bernath
Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada
, and Department of Chemistry, University of Arizona, Tucson, Arizona 85721
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M. F. Mérienne;
M. F. Mérienne
Spectrométrie Moléculaire et Atmosphérique, UFR Sciences, Moulin de la Housse, B.P. 1039, 51687 Reims Cedex 2, France
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R. Colin;
R. Colin
Université Libre de Bruxelles, Service de Chimie Physique Moléculaire, CP 160/09, Av. F. D. Roosevelt 50, B-1050 Brussels, Belgium
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N. F. Zobov;
N. F. Zobov
Department of Physics and Astronomy, University College London, London WC1E 6BT, United Kingdom
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Oleg L. Polyansky;
Oleg L. Polyansky
Department of Physics and Astronomy, University College London, London WC1E 6BT, United Kingdom
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Jonathan Tennyson;
Jonathan Tennyson
Department of Physics and Astronomy, University College London, London WC1E 6BT, United Kingdom
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V. A. Savin
V. A. Savin
Department of Mathematics, Nizhny Novgorod State University, Nizhny Novgorod, Russia
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M. Carleer
A. Jenouvrier
A.-C. Vandaele
P. F. Bernath
,
M. F. Mérienne
R. Colin
N. F. Zobov
Oleg L. Polyansky
Jonathan Tennyson
V. A. Savin
Université Libre de Bruxelles, Service de Chimie Physique Moléculaire, CP 160/09, Av. F.D. Roosevelt 50, B-1050 Brussels, Belgium
J. Chem. Phys. 111, 2444–2450 (1999)
Article history
Received:
April 06 1999
Accepted:
May 13 1999
Connected Content
A related article has been published:
Comment on “The near infrared, visible, and near ultraviolet overtone spectrum of water” [J. Chem. Phys. 111, 2444 (1999)]
Citation
M. Carleer, A. Jenouvrier, A.-C. Vandaele, P. F. Bernath, M. F. Mérienne, R. Colin, N. F. Zobov, Oleg L. Polyansky, Jonathan Tennyson, V. A. Savin; The near infrared, visible, and near ultraviolet overtone spectrum of water. J. Chem. Phys. 8 August 1999; 111 (6): 2444–2450. https://doi.org/10.1063/1.479859
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