Recently, C92− dianions have been observed as products in the collision of 48 keV [CsC9] ions with hydrogen or helium. Motivated by this observation we examined the structure of [CsC9] anions in a detailed theoretical study. The geometries of the finally detected C92− dianions should be closely related to the intermediately produced [CsC9] anions. We found stable isomers of [CsC9] which possess “lightly embracing” structures reflecting the geometrical characteristics of the theoretically prognosticated stable C92− dianions. The examination of the smaller [CsC7] anions confirmed these results: Lightly embracing isomers of [CsC7] have been found to form stable anions.

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