The recently developed technique of scattering and recoiling imaging spectrometry (SARIS) is used to probe the effect of hydrogen atoms on the trajectories of 5 keV scattering from a Pt(111) surface. Classical kinematic calculations and ion trajectory simulations, using the scattering and recoiling imaging code (SARIC), are carried out in order to probe the details of the interaction and the nature of the perturbation. It is demonstrated that adsorbed hydrogen atoms are capable of deflecting these low kilo-electron-volt Ne trajectories scattering from a Pt surface. These perturbations result in spatial shifts and broadenings of the anisotropic features of the SARIS images that are readily detectable. The scattered Ne atoms lose 0–18% of their initial kinetic energy as a result of the perturbation by the H atoms. The physics of the perturbation on the trajectories can be understood from straightforward classical kinematic calculations and SARIC ion trajectory simulations.
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22 December 1999
Research Article|
December 22 1999
How do hydrogen atoms on surfaces affect the trajectories of heavier scattered atoms? Available to Purchase
K. M. Lui;
K. M. Lui
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
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I. Bolotin;
I. Bolotin
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
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A. Kutana;
A. Kutana
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
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V. Bykov;
V. Bykov
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
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W. M. Lau;
W. M. Lau
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
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J. W. Rabalais
J. W. Rabalais
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
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K. M. Lui
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
I. Bolotin
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
A. Kutana
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
V. Bykov
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
W. M. Lau
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
J. W. Rabalais
Department of Chemistry, University of Houston, Houston, Texas 77204-5641
J. Chem. Phys. 111, 11095–11100 (1999)
Article history
Received:
August 04 1999
Accepted:
September 29 1999
Citation
K. M. Lui, I. Bolotin, A. Kutana, V. Bykov, W. M. Lau, J. W. Rabalais; How do hydrogen atoms on surfaces affect the trajectories of heavier scattered atoms?. J. Chem. Phys. 22 December 1999; 111 (24): 11095–11100. https://doi.org/10.1063/1.480468
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