We report on the effect of pressure on the dual segmental relaxation of an athermal poly(isoprene-b-vinylethylene) (PI-PVE) diblock copolymer melt using dielectric spectroscopy. The quantity is employed as a probe of the state of dynamic miscibility in the system. We find that pressure, unlike temperature, induces dynamic homogeneity.
REFERENCES
1.
J. B.
Miller
, K. J.
McGrath
, C. M.
Roland
, C. A.
Trask
, and A. N.
Garroway
, Macromolecules
23
, 4543
(1990
);X.
Quan
, G. E.
Johnson
, E. W.
Anderson
and H. S.
Lee
, Macromolecules
22
, 2451
(1991
);A. K.
Rizos
, G.
Fytas
, and J. E. L.
Roovers
, J. Chem. Phys.
97
, 6925
(1992
);K.
Schmidt-Rohr
, J.
Clauss
, and H. W.
Spiess
, Macromolecules
25
, 3273
(1992
);G.
Fytas
, S.
Anastasiadis
, K.
Karatasos
, and N.
Hadjichristidis
, Phys. Scr.
T49
, 237
(1993
).2.
(a)
J.
Kanetakis
, G.
Fytas
, F.
Kremer
, and T.
Pakula
, Macromolecules
25
, 3484
(1992
);(b)
J. A.
Zawada
, G. G.
Fuller
, R. H.
Colby
, L. J.
Fetters
, and J. E. L.
Roovers
, Macromolecules
27
, 6861
(1994
);(c)
G. C.
Chung
, J. A.
Kornfield
, and S. D.
Smith
, Macromolecules
27
, 964
(1994
);G. C.
Chung
, J. A.
Kornfield
, and S. D.
Smith
, Macromolecules
27
, 5729
(1994
);(d)
A.
Alegria
, J.
Colmenero
, K. L.
Ngai
, and C. M.
Roland
, Macromolecules
27
, 4486
(1994
);(e)
J. A.
Pathak
, R. H.
Colby
, G.
Floudas
, and R.
Jerome
, Macromolecules
32
, 2553
(1999
);(g) M. Doxastakis et al. (in preparation).
3.
A. R.
Khokhlov
and I. Ya.
Erukhimovich
, Macromolecules
26
, 7155
(1993
).4.
R. E.
Wetton
, W. J.
MacKnight
, J. R.
Fried
, and F. E.
Karasz
, Macromolecules
11
, 158
(1978
);5.
6.
S. K.
Kumar
, R. H.
Colby
, S.
Anastasiadis
, and G.
Fytas
, J. Chem. Phys.
105
, 3777
(1996
);S.
Kamath
, R. H.
Colby
, S. K.
Kumar
, K.
Karatasos
, G.
Floudas
, G.
Fytas
, and J. E. L.
Roovers
, J. Chem. Phys.
111
, 6121
(1999
).7.
8.
9.
(b) G. Floudas, T. Reisinger, and G. Wegner (in preparation);
(c) G. Floudas, C. Gravalides, T. Reisinger, and G. Wegner, J. Chem. Phys. (to be published).
10.
11.
G.
Williams
, Trans. Faraday Soc.
60
, 1548
(1964
), and references therein.
This content is only available via PDF.
© 1999 American Institute of Physics.
1999
American Institute of Physics
You do not currently have access to this content.