The isotropic Compton profile of BeO has been measured using a γ-ray Compton spectrometer which employs a 5 Ci annular source. The measurement is compared with the theoretical HF-LCAO Compton profile published by Lichanot et al. The measurement has also been compared with our calculations based on the RFA model employing different ionic wavefunctions. It is seen that the experimental Compton profile is in very good agreement with the HF-LCAO calculations. To determine the nature of bonding, equal-valence-electron-density Compton profile of BeO has been compared with that of the isovalent compound MgO. It is observed that the bonding in BeO is partially covalent and less ionic than MgO in agreement with the conclusions of the HF-LCAO calculation.
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1 July 1999
Research Article|
July 01 1999
Compton profile study of bonding in BeO
K. B. Joshi;
K. B. Joshi
Department of Physics, College of Science Campus, M.L. Sukhadia University, Udaipur-313 001, India
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Rajesh Jain;
Rajesh Jain
Department of Physics, S.S.J. (Subodh) College, Jaipur 302 004, India
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R. K. Pandya;
R. K. Pandya
Department of Physics, L.B.S. College, Jaipur 302 004, India
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B. L. Ahuja;
B. L. Ahuja
Department of Physics, College of Science Campus, M.L. Sukhadia University, Udaipur-313 001, India
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B. K. Sharma
B. K. Sharma
Department of Physics, University of Rajasthan, Jaipur 302 004, India
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J. Chem. Phys. 111, 163–167 (1999)
Article history
Received:
June 08 1998
Accepted:
March 31 1999
Citation
K. B. Joshi, Rajesh Jain, R. K. Pandya, B. L. Ahuja, B. K. Sharma; Compton profile study of bonding in BeO. J. Chem. Phys. 1 July 1999; 111 (1): 163–167. https://doi.org/10.1063/1.479262
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