The inelastic neutron scattering from H2 in D2O ice at energy transfers that correspond to rotation-translation are presented. Both the first energy gain and the energy loss peaks are observed. The position of the peaks shows that the H2 molecules execute nearly free rotation. The translational (recoil) contribution to the band positions as well as their widths can be fit by free translation with the molecule having an effective mass of about 1.7M0 where M0 is the mass of H2. The experimental results are compared to the available computer simulations.

1.
D. Eisenberg and W. Kauzmann, The Structure and Properties of Water (Oxford, New York, 1969).
2.
J. I.
Lunine
and
D. J.
Stevenson
Astrophys. J., Suppl. Ser.
58
,
493
(
1985
).
3.
D.
Laufer
,
E.
Kochavi
and
A.
Bar-Nun
,
Phys. Rev. B
36
,
9219
(
1987
).
4.
W. L.
Vos
,
L. W.
Finger
,
R. J.
Hemley
, and
H.-K.
Mao
,
Phys. Rev. Lett.
71
,
3150
(
1993
).
5.
Landolt-Bornstein, Zahlewerte und Funktionen (Springer, Berlin, 1962), Vol. 2.2b, pp. 1–19.
6.
Yu. A.
Dyadin
,
E. Ya.
Aladko
,
K. A.
Vdachin
, and
M.
Tkacz
,
Pol. J. Chem.
68
,
343
(
1994
).
7.
D. W. Davidson, in Water, A Comprehensive Treatise, edited by F. Franks (Plenum, New York, 1973), Vol. 2, Chap. 3, p. 115.
8.
J. H.
Van der Waals
and
J. C.
Plattecuw
,
Adv. Chem. Phys.
2
,
1
(
1959
).
9.
H. L.
Strauss
,
Z.
Chen
, and
C.-K.
Loong
,
J. Chem. Phys.
101
,
7177
(
1994
).
10.
D. G.
Taylor
and
H. L.
Strauss
,
J. Chem. Phys.
90
,
768
(
1989
).
11.
D. G.
Taylor
and
H. L.
Strauss
,
J. Chem. Phys.
96
,
3367
(
1992
).
12.
Z. Chen and H. L. Strauss (unpublished).
13.
J. E.
Hunter
,
D. G.
Taylor
, and
H. L.
Strauss
,
J. Chem. Phys.
97
,
50
(
1992
).
14.
L.
Xiao
and
D. F.
Coker
,
J. Chem. Phys.
102
,
1107
(
1995
).
15.
H. S.
Mei
and
D. F.
Coker
,
J. Chem. Phys.
104
,
4755
(
1996
).
16.
H. S.
Mei
and
D. F.
Coker
,
J. Chem. Phys.
105
,
3938
(
1996
).
17.
C.-K.
Loong
,
S.
Ikeda
, and
J. M.
Carpenter
,
Nucl. Instrum. Methods Phys. Res. A
260
,
381
(
1987
).
18.
C.-K. Loong, L. I. Donely, G. E. Ostrowski, R. Kleb, J. P. Hammonds, L. Soderholm, and S. Takahashi, in Proceedings of the 12th Meeting of the International Collaboration on Advanced Neutron Sources (Rutherford Appleton Laboratory, Oxfordshire, UK, 1992).
19.
J. A.
Young
and
J. U.
Koppel
,
Phys. Rev. A
135
,
603
(
1964
).
20.
S. W. Lovesey, Theory of Neutrons of Condensed Matter (Oxford, New York, 1986), Sect. 6.5, p. 264.
21.
J.
Langel
,
D. L.
Price
,
R. O.
Simmons
, and
P. E.
Sokol
,
Phys. Rev. B
38
,
11275
(
1988
).
22.
G. J.
Kellogg
,
J. W.
White
,
K. W.
Herwig
, and
P. E.
Sokol
,
J. Chem. Phys.
93
,
7153
(
1990
).
23.
V. B.
Kazansky
,
F. C.
Jentoft
, and
H. G.
Karga
,
J. Chem. Soc., Faraday Trans.
94
,
1347
(
1998
).
This content is only available via PDF.
You do not currently have access to this content.