The present work is devoted to investigation of the temperature and frequency dependencies of the different relaxing values in highly-viscous glycerol-like liquids. The consideration is based on microinhomogeneous structure conception, allowing us to give the consecutive explanation to both the thermodynamic and kinetic properties. The main attention is paid to analysis of heat capacity, dielectrical permeability and longitudinal sound velocity. The influence of measuring time and preparation one of highly-viscous states on observed values are discussed.

1.
T. Litovitz and K. Davis, in Physical Acoustics, Principles and Methods, V. 2A: Properties of Gases, Liquids and Solutions, edited by Y. Mason (Academic, London, 1965), pp. 298–370.
2.
Y.-X.
Yan
,
L.-T.
Cheng
, and
K. A.
Nelson
,
J. Chem. Phys.
88
,
6477
(
1988
).
3.
W. Götze, in Liquids, Freezing and Glass Transition, edited by J. P. Hanssen, D. Levesque, and J. Zinn-Justin (North-Holland, Amsterdam, 1991), pp. 287–504.
4.
M. C.
Marchetti
,
Phys. Rev. A
33
,
3363
(
1986
).
5.
D.
Kivelson
and
S. A.
Kivelson
,
J. Chem. Phys.
90
,
4464
(
1989
).
6.
R. A.
McPhail
and
D.
Kivelson
,
J. Chem. Phys.
90
,
6555
(
1989
).
7.
V. S.
Dotzenko
,
Usp. Fiz. Nauk (Russia)
113
,
1
(
1993
).
8.
N. P.
Malomuzh
and
S. B.
Pelishenko
,
Ukr. Fiz. Zh. (USSR)
35
,
577
(
1990
).
9.
N. P.
Malomuzh
and
S. B.
Pelishenko
,
Phys. Lett. A
154
,
269
(
1991
).
10.
T. V.
Lokotosh
and
N. P.
Malomuzh
,
Zh. Fiz. Khim. (Russia)
68
,
983
(
1994
).
11.
S. V.
Kuzmin
and
N. P.
Malomuzh
,
J. Mol. Liquids
58
,
81
(
1993
).
12.
S. V.
Lishchuk
and
N. P.
Malomuzh
,
Zh. Fiz. Khim. (Russia)
69
,
110
(
1995
).
13.
S. V.
Lishchuk
and
N. P.
Malomuzh
,
J. Mol. Struct.
348
,
205
(
1995
).
14.
S. V.
Lishchuk
and
N. P.
Malomuzh
,
Zh. Fiz. Khim. (Russia)
69
,
1694
(
1995
).
15.
S. V.
Lishchuk
and
N. P.
Malomuzh
,
Zh. Fiz. Khim. (Russia)
70
,
410
(
1996
).
16.
M. A.
Isakovich
,
I. A.
Chaban
,
Zh. Eksp. Teor. Fiz. (USSR)
50
,
1343
(
1966
).
17.
G. I.
Salistra
,
Zh. Eksp. Teor. Fiz. (USSR)
53
,
258
(
1967
).
18.
D. N. Zubarev, Nonequilibrium Statistical Thermodynamics (Nauka, Moscow, 1971), p. 416.
19.
N. O.
Birge
and
S. R.
Nagel
,
Phys. Rev. Lett.
54
,
2674
(
1985
).
20.
L. D. Landau and E. M. Lifshits, Statistical Physics (Nauka, Moscow, 1976), p. 584.
21.
A. R. Ubbelode, Melting and Crystal Structure (Clarendon, Oxford, 1965), p. 420.
22.
Tables of Physical Values, edited by I. K. Kikoin (Atomizdat, Moscow, 1976), p. 1007.
23.
M.
Rajeswari
and
A. K.
Raychaudhuri
,
Phys. Rev. B
47
,
3036
(
1991
).
24.
H.
Jónsson
and
H. C.
Andersen
,
Phys. Rev. Lett.
60
,
2295
(
1988
).
25.
G. C.
Knolman
and
A. S.
Hamamoto
,
J. Chem. Phys.
47
,
5232
(
1967
).
26.
E. O.
Ryabichev
and
M. I.
Shakhparonov
,
Vestnik MGU (USSR)
4
,
487
(
1974
).
27.
Y. H.
Jeong
,
S. R.
Nagel
, and
S.
Bhattacharya
,
Phys. Rev. A
34
,
602
(
1986
).
28.
G. I.
Kolesnikov
,
Trudy FIAN (USSR)
118
,
108
(
1979
).
29.
D. A.
Pinnow
,
S. J.
Candau
,
J. T.
LaMacchia
, and
T. A.
Litowitz
,
J. Acoust. Soc. Am.
43
,
131
(
1968
).
30.
Y. H.
Jeong
,
Phys. Rev. A
36
,
766
(
1987
).
31.
L.-T.
Cheng
,
Y.-X.
Yan
, and
K. A.
Nelson
,
J. Chem. Phys.
91
,
6052
(
1989
).
32.
D. W.
Dawidson
and
R. H.
Cole
,
J. Chem. Phys.
19
,
1484
(
1951
).
This content is only available via PDF.
You do not currently have access to this content.