The quadrupolar and chemical shift tensors, as well as the relative orientation of the two principle axis systems, are accurately determined using a two‐dimensional nuclear magnetic resonance technique. Good agreement between experimental and simulated two‐dimensional spectra is obtained for a series of rubidium and sodium compounds at multiple magnetic field strengths. Extension of this technique to correlate the quadrupolar and dipolar interactions, as well as the incorporation of a purely isotropic dimension resulting in a three‐dimensional experiment is also discussed.
REFERENCES
1.
2.
3.
4.
I.
Farnan
, P. J.
Grandinetti
, J. H.
Baltisberger
, J. F.
Stebbins
, U.
Werner
, M. A.
Eastman
, and A.
Pines
, Nature
358
, 31
(1992
).5.
P. J.
Grandinetti
, J. H.
Baltisberger
, I.
Farnan
, J. F.
Stebbins
, U.
Werner
, and A.
Pines
, J. Phys. Chem.
99
, 12341
(1995
).6.
7.
8.
9.
10.
11.
F.
Lefebvre
, J. P.
Amoureux
, C.
Fernandez
, and E. G.
Derouane
, J. Chem. Phys.
86
, 6070
(1987
).12.
13.
14.
P. W.
France
, J. Magn. Reson.
92
, 30
(1991
).15.
C.
Fernandez
, J. P.
Amoureux
, and P.
Bodart
, J. Magn. Reson. Series a
113
, 205
(1995
).16.
J.
Hirschinger
, T.
Mongrelet
, C.
Marichal
, P.
Granger
, J. M.
Savariault
, E.
Deramond
, and J.
Galy
, J. Phys. Chem.
97
, 10301
(1993
).17.
W. P.
Power
, R. E.
Wasylishen
, S.
Mooibroek
, B. A.
Pettitt
, and W.
Danchura
, J. Phys. Chem.
94
, 591
(1990
).18.
C.
Fernandez
, P.
Bodart
, and J. P.
Amoureux
, Solid State Nucl. Magn. Reson.
3
, 79
(1994
).19.
J.
Skibsted
, N. C.
Nielsen
, H.
Bildsoe
, and H. J.
Jakobsen
, J. Am. Chem. Soc.
115
, 7351
(1993
).20.
H. J.
Jakobsen
, J.
Skibsted
, H.
Bildso/e
, and N. C.
Nielsen
, J. Magn. Reson.
85
, 173
(1989
).21.
R. K.
Hester
, J. L.
Ackermann
, B. L.
Neff
, and J. S.
Waugh
, Phys. Rev. Lett.
36
, 1081
(1976
).22.
E. F.
Rybaczewski
, B. L.
Neff
, J. S.
Waugh
, and J. S.
Sherfinski
, J. Chem. Phys.
67
, 1231
(1977
).23.
24.
M. A.
Eastman
, P. J.
Grandinetti
, Y. K.
Lee
, and A.
Pines
, J. Magn. Reson.
98
, 333
(1992
).25.
26.
G.
Drobny
, A.
Pines
, S.
Sinton
, D. P.
Weitekamp
, and D.
Wemmer
, Faraday Symp. Chem. Soc.
13
, 49
(1979
).27.
D. J.
States
, R. A.
Haberkorn
, and D. J.
Ruben
, J. Magn. Reson.
48
, 286
(1982
).28.
J. H. Baltisberger, Ph.D. thesis, University of California, 1993.
29.
U. Haeberlen, High Resolution NMR in Solids: Selective Averaging, Advances in Magnetic Resonance, Supplement 1 (Academic, New York, 1976).
30.
M. Mehring, High Resolution NMR in Solids (Springer, New York, 1983).
31.
A. R. Edmonds, Angular Momentum in Quantum Mechanics (Princeton University Press, Princeton, NJ, 1960).
32.
M. E. Rose, Elementary Theory of Angular Momentum (Wiley, New York, NY, 1957).
33.
34.
A.
Bax
, N. M.
Szeverenyi
, and G. E.
Maciel
, J. Magn. Reson.
55
, 494
(1983
).35.
36.
A. Medek, J. H. Sachleben, and L. Frydman, Presented at the 36th Experimental Nuclear Magnetic Resonance Conference, Boston, Massachusetts, March 1995, p. 377.
37.
A.
Medek
, J. H.
Sachleben
, P.
Beverwyk
, and L.
Frydman
, J. Chem. Phys.
104
, 5374
(1996
).38.
L.
Frydman
, G. C.
Chingas
, Y. K.
Lee
, P. J.
Grandinetti
, M. A.
Eastman
, G. A.
Barrall
, and A.
Pines
, J. Chem. Phys.
97
, 4800
(1992
).39.
40.
J. H.
Baltisberger
, S. L.
Gann
, E. W.
Wooten
, T. H.
Chang
, K. T.
Mueller
, and A.
Pines
, J. Am. Chem. Soc.
114
, 7489
(1992
).
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