The Czochralski method was used to grow a -long crystal of the clathrate, which was cut into disks that were evaluated for thermoelectric performance. The Seebeck coefficient and electrical and thermal conductivities all showed evidence of a transition from extrinsic to intrinsic behavior in the range of . The corresponding figure of merit (ZT) was found to be a record high of 1.35 at and with an extrapolated maximum of 1.63 at . This makes the clathrate an exceptionally strong candidate for medium and high-temperature thermoelectric applications.
REFERENCES
1.
B. C.
Sales
, D.
Mandrus
, and R. K.
Williams
, Science
272
, 1325
(1996
).2.
G. S.
Nolas
, M.
Kaeser
, R. T.
Littleton
, and T. M.
Tritt
, Appl. Phys. Lett.
77
, 1855
(2000
).3.
T.
Caillat
, J. P.
Fleurial
, and A.
Borshchevsky
, J. Phys. Chem. Solids
58
, 1119
(1997
).4.
5.
J. W.
Sharp
, B. C.
Sales
, D. G.
Mandrus
, and B. C.
Chakoumakos
, Appl. Phys. Lett.
74
, 3794
(1999
).6.
B.
Wölfing
, C.
Kloc
, J.
Teubner
, and E.
Bucher
, Phys. Rev. Lett.
86
, 4350
(2001
).7.
T. M.
Tritt
and R. T.
Littleton
, Semicond. Semimetals
70
, 179
(2001
).8.
C. M.
Bhandari
, in CRC Handbook of Thermoelectric
, edited by D. M.
Rowe
(CRC
, Boca Raton
, 1995
), p. 30
.9.
K. F.
Hsu
et al., Science
303
, 818
(2004
).10.
R.
Venkatasubramanian
, E.
Siivola
, T.
Colpitts
, and B.
O’Quinn
, Nature (London)
413
, 597
(2001
).11.
T. C.
Harman
, P. J.
Taylor
, D. L.
Spears
, and M. P.
Walsh
, Proceedings of the 18th International Conference Thermoelectrics, Baltimore, MD, 1999
(IEEE
, New York
, 1999
), pp. 280
–284
.12.
G. K. H.
Madsen
, K.
Schwarz
, P.
Blaha
, and D. J.
Singh
, Phys. Rev. B
68
, 125212
(2003
).13.
C.
Gatti
, L.
Bartini
, N. P.
Blake
, and B. B.
Iversen
, Chem.-Eur. J.
9
, 4556
(2003
).14.
L.
Bertini
et al., Proceedings of the 22nd International Conference Thermoelectrics, La Grande Motte, France, 2003
(IEEE
, New York
, 2003
), pp. 127
–130
.15.
J. D.
Bryan
, Dissertation Thesis, University of California at Santa Barbara
, 2002
.16.
H.
Anno
, M.
Hokazono
, M.
Kawamura
, J.
Nagao
, and K.
Matsubara
, Proceedings of the 21st International Conference on Thermoelectrics, Long Beach, CA, 2002
(IEEE
, New York
, 2002
), pp. 77
–80
.17.
B. C.
Sales
, B. C.
Chakoumakos
, R.
Jin
, J. R.
Thompson
, and D.
Mandrus
, Phys. Rev. B
63
, 245113
(2001
).18.
S.
Paschen
, W.
Carrillo-Cabrera
, A.
Bentien
, V. H.
Tran
, M.
Baenitz
, Y.
Grin
, and F.
Steglich
, Phys. Rev. B
64
, 214404
(2001
).19.
N. P.
Blake
, J. D.
Bryan
, S.
Latturner
, L.
Møllnitz
, G. D.
Stucky
, and H.
Metiu
, J. Chem. Phys.
114
, 10063
(2001
).20.
N.
Blake
, S.
Latturner
, J. D.
Bryan
, G. D.
Stucky
, and H.
Metiu
, J. Chem. Phys.
115
, 8060
(2001
).21.
A. E. C.
Palmqvist
, B. B.
Iversen
, J. D.
Bryan
, S.
Latturner
, and G. D.
Stucky
, Proceedings of the 19th International Conference on Thermoelectrics, Cardiff, UK, 2000
(IEEE
, New York
, 2000
), pp. 113
–116
.22.
V.
Keppens
, B. C.
Sales
, D.
Mandrus
, B. C.
Chakoumakos
, and C.
Laermans
, Philos. Mag. Lett.
80
, 807
(2000
).23.
A.
Bentien
, A. E. C.
Palmqvist
, J. D.
Bryan
, S.
Latturner
, G. D.
Stucky
, L.
Furenlid
, and B. B.
Iversen
, Angew. Chem., Int. Ed.
112
, 3759
(2000
).24.
G. S.
Nolas
, G. A.
Slack
, J. L.
Cohn
, and S. B.
Schujman
, Proceedings of the 17th International Conference on Thermoelectrics, Nagoya, Japan, 1998
(IEEE
, New York
, 1998
), pp. 294
–297
.25.
G. S.
Nolas
, J. L.
Cohn
, G. A.
Slack
, and S. B.
Schujman
, Appl. Phys. Lett.
73
, 178
(1998
).26.
V. L.
Kuznetsov
, L. A.
Kuznetsova
, A. E.
Kaliazin
, and D. M.
Rowe
, J. Appl. Phys.
87
, 7871
(2000
).27.
G. A.
Slack
, in CRC Handbook of Thermoelectrics
, edited by D. M.
Rowe
(CRC
, Boca Raton
, 1995
), pp. 407
–440
.28.
B. C.
Chakoumakos
, B. C.
Sales
, D. G.
Mandrus
, and G. S.
Nolas
, J. Alloys Compd.
296
, 80
(2000
).29.
J. D.
Bryan
, N. P.
Blake
, H.
Metiu
, G. D.
Stucky
, B. B.
Iversen
, R. D.
Poulsen
, and A.
Bentien
, J. Appl. Phys.
92
, 7281
(2002
);J. D.
Bryan
, N. P.
Blake
, H.
Metiu
, G. D.
Stucky
, B. B.
Iversen
, R. D.
Poulsen
, and A.
Bentien
, J. Appl. Phys.
93
, 4343
(E) (2003
).30.
A. A.
Chernov
, Modern Crystallography III
(Springer-Verlag
, Berlin
, 1984
), Vol. 3
, pp. 424
–429
.31.
R. H.
Doremus
, B. W.
Roberts
, and D.
Turnbull
, Growth and Perfection of Crystals
(Wiley
, New York
, 1958
).32.
B.
Eisenmann
, H.
Schäfer
, and R.
Zagler
, J. Less-Common Met.
118
, 43
(1986
).33.
L.
Bertini
et al., Proceedings of the 22nd International Conference Thermoelectrics, La Grande Motte, France, 2003
(IEEE
, New York
, 2003
), pp. 532
–536
.34.
L.
Bertini
et al., J. Appl. Phys.
93
, 438
(2003
).35.
S. G. K.
Williams
, D. M.
Rowe
, V.
Kuznetsov
, and G.
Min
, Proceedings of the Sixth European Workshop, Freiburg, Germany, 2001
(IEEE
, New York
, 2001
), pp. 200
–208
.36.
R. B.
Marinenko
, in Standards for Electron Probe Microanalysis
(Plenum
, New York
1991
), pp. 251
–260
.37.
A.
Bentien
, M.
Christensen
, J. D.
Bryan
, A.
Sanchez
, S.
Paschen
, F.
Steglich
, G. D.
Stucky
, and B. B.
Iversen
, Phys. Rev. B
69
, 045107
(2004
).© 2006 American Institute of Physics.
2006
American Institute of Physics
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