Optically active erbium ions in the silica and silicon sections of a Si-infiltrated silica colloidal photonic crystal can be separately addressed. A face-centered cubic colloidal crystal composed of 860 nm silica colloids was made by self-assembly under controlled drying conditions. It was then infiltrated with Si using chemical vapor deposition at 550 °C. Next, the photonic crystal was doped with erbium ions by 2 MeV ion implantation. The erbium ions were activated by thermal anneals at 400 and 750 °C, and showed clear photoluminescence at 1.5 μm in both the Si and silica parts of the photonic crystal. By varying measurement temperature and excitation wavelength the erbium ions were selectively excited in Si and/or silica. In this way the local optical density of states in these photonic crystals can be selectively probed. The emission linewidth for in crystalline Si is relatively narrow and fits well within the calculated photonic band gap. The long luminescence lifetime of Er in Si makes these photonic crystals an ideal geometry to measure effects of the optical density of states on spontaneous emission.
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1 March 2004
Research Article|
March 01 2004
Selective excitation of erbium in silicon-infiltrated silica colloidal photonic crystals Available to Purchase
J. Kalkman;
J. Kalkman
FOM Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands
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E. de Bres;
E. de Bres
FOM Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands
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A. Polman;
A. Polman
FOM Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands
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Y. Jun;
Y. Jun
Department of Chemical Engineering and Material Science (CEMS), University of Minnesota, Minneapolis, MN 55455-0132
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D. J. Norris;
D. J. Norris
Department of Chemical Engineering and Material Science (CEMS), University of Minnesota, Minneapolis, MN 55455-0132
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D. C. ’t Hart;
D. C. ’t Hart
Department of Soft Condensed Matter, Debye Institute, Utrecht University, Princeton Plein 5, 3584CC Utrecht, The Netherlands
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J. P. Hoogenboom;
J. P. Hoogenboom
Department of Soft Condensed Matter, Debye Institute, Utrecht University, Princeton Plein 5, 3584CC Utrecht, The Netherlands
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A. van Blaaderen
A. van Blaaderen
Department of Soft Condensed Matter, Debye Institute, Utrecht University, Princeton Plein 5, 3584CC Utrecht, The Netherlands
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J. Kalkman
FOM Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands
E. de Bres
FOM Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands
A. Polman
FOM Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands
Y. Jun
Department of Chemical Engineering and Material Science (CEMS), University of Minnesota, Minneapolis, MN 55455-0132
D. J. Norris
Department of Chemical Engineering and Material Science (CEMS), University of Minnesota, Minneapolis, MN 55455-0132
D. C. ’t Hart
Department of Soft Condensed Matter, Debye Institute, Utrecht University, Princeton Plein 5, 3584CC Utrecht, The Netherlands
J. P. Hoogenboom
Department of Soft Condensed Matter, Debye Institute, Utrecht University, Princeton Plein 5, 3584CC Utrecht, The Netherlands
A. van Blaaderen
Department of Soft Condensed Matter, Debye Institute, Utrecht University, Princeton Plein 5, 3584CC Utrecht, The Netherlands
J. Appl. Phys. 95, 2297–2302 (2004)
Article history
Received:
September 16 2003
Accepted:
November 18 2003
Citation
J. Kalkman, E. de Bres, A. Polman, Y. Jun, D. J. Norris, D. C. ’t Hart, J. P. Hoogenboom, A. van Blaaderen; Selective excitation of erbium in silicon-infiltrated silica colloidal photonic crystals. J. Appl. Phys. 1 March 2004; 95 (5): 2297–2302. https://doi.org/10.1063/1.1640459
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