The structural stability and electrical properties of Sr2FeMoO6 under high pressure at room temperature have been studied using energy dispersive x-ray diffraction with synchrotron radiation and resistance and capacitance measurements. The x-ray diffraction results show that the structure of Sr2FeMoO6 remains stable up to 40 GPa. The equation of state of Sr2FeMoO6 is obtained from the V/V0–P relationship. The bulk modulus B0 and its first-order derivative B0 of Sr2FeMoO6 were calculated based on the Birch–Murnaghan equation. The electrical resistance undergoes a metallic transition at about 2.1 GPa. The metallic transition may be caused by a change in the electronic structure induced by high pressure.

1.
K.-I.
Kobayashi
,
T.
Kimura
,
H.
Sawada
,
K.
Terakura
, and
Y.
Tokura
,
Nature (London)
395
,
677
(
1998
).
2.
T.
Nakagawa
,
K.
Yoshikawa
, and
S.
Nomura
,
J. Phys. Soc. Jpn.
27
,
880
(
1969
).
3.
M.
Itoh
,
I.
Ohta
, and
Y.
Inaguma
,
Mater. Sci. Eng., B
41
,
55
(
1996
).
4.
Z.
Fang
,
K.
Terakura
, and
J.
Kanamori
,
Phys. Rev. B
63
,
180407
(
2001
).
5.
O.
Chmaissem
,
R.
Kruk
,
B.
Dabrowski
,
D. E.
Brown
,
X.
Xiong
,
S.
Kolesnik
,
J. S.
Jorgensen
, and
C. W.
Kimball
,
Phys. Rev. B
62
,
14197
(
2000
).
6.
P.
Zhao
,
Z. X.
Bao
,
C. X.
Liu
,
M. Z.
Jin
,
R. C.
Yu
, and
C. Q.
Jin
,
Chinese J. High Press. Phys.
16
(
2
),
137
(
2002
).
7.
J.
Liu
,
J.
Zhao
,
R. Z.
Che
, and
Y.
Yang
Chin. Sci. Bull.
45
,
1659
(
2000
).
8.
Z. X.
Bao
,
V. H.
Schmidt
, and
F. L.
Howell
,
J. Appl. Phys.
70
,
6804
(
1991
).
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